Two polymorphic forms of a mixed zinc/copper biquinoline dihydrogenphosphate

Yanko Moreno, Patricio Hermosilla, María Teresa Garland, Octavio Pẽa, Ricardo Baggio

Resultado de la investigación: Contribución a una revistaArtículorevisión exhaustiva

1 Cita (Scopus)

Resumen

Two polymorphic forms of a mixed zinc/copper biquinoline dihydrogenphosphate are presented, showing almost identical monomeric units, viz. (2,2′-biquinoline-2 N,N′)bis-(di-hydrogen-phos- phato-O)copper(II)/zinc(II), formulated as [Zn x Cu1-x (H2PO4)2(C18H12N2)], with x = 0.88 (1) and 0.90 (2). The cation is tetra-hedrally coordinated to a chelating biquinoline system and two diprotonated phosphate anions. The structures differ mainly in their inter-molecular hydrogen-bonding inter-actions, leading to different packing schemes. No significant evidence of stress due to the Zn/Cu solid solution formation was detected.

Idioma originalInglés
Páginas (desde-hasta)m249-m252
PublicaciónActa Crystallographica Section C: Crystal Structure Communications
Volumen63
N.º6
DOI
EstadoPublicada - 11 may 2007

Áreas temáticas de ASJC Scopus

  • Bioquímica, genética y biología molecular (todo)

Huella

Profundice en los temas de investigación de 'Two polymorphic forms of a mixed zinc/copper biquinoline dihydrogenphosphate'. En conjunto forman una huella única.

Citar esto