Tuning the photophysical properties of a (P,N)Re^I complex by adding a -NH- fragment into a P,N-bidentate ligand: The case of [P,N-{(C₆H₅)₂(C₅H₄N)NHPRe(CO)₃Br]

Keyphrases

• Excited States 100%
• Non-radiative Decay 100%
• P,N-bidentate Ligands 100%
• Pyridylphosphines 100%
• Photophysical Properties 100%
• Spectroscopic Properties 50%
• Pyridine Ligands 50%
• UV-Vis Spectra 50%
• Photophysical 50%
• Reduction Method 50%
• New Complexes 50%
• Decay Lifetime 50%
• Decay Rate Constant 50%
• Ligand Reduction 50%
• Emission Band 50%
• Vibrational Modes 50%
• Electrochemical Properties 50%
• High Energy 50%
• Exponential Function 50%
• Absorption Maxima 50%
• Non-emissive 50%
• Absorption Bands 50%
• Dichloromethane 50%
• Cyclic Voltammetry 50%
• Intraligand 50%
• Bi-exponential 50%
• DFT Calculations 50%

Chemistry

• Excited State 100%
• Ground State 100%
• Density Functional Theory 50%
• Rate Constant 50%
• Luminiscence Type 50%
• Cyclic Voltammetry 50%
• Dichloromethane 50%
• UV/VIS Spectroscopy 50%
• Absorption Maxima 50%