Trans-Bis[1,2-bis(diphenylphosphanyl)ethane]chlorido(ethynyl)ruthenium(II)

Alexander Trujillo, Mauricio Fuentealba, Ramiro Arratia-Perez, Judith A K Howard

Resultado de la investigación: Contribución a una revistaArtículo

2 Citas (Scopus)

Resumen

The molecular structure of the title compound, trans-[Cu(C2H)Cl(C26H24P2)2] , consists of an RuII cation, located on an inversion centre, in an octahedral environment defined by two chelating phosphines, one acetylide and one chloride ligand. The -C CH and the chlorine ligands are disordered over two equivalent positions (0.5 occupancy each). The coordination geometry is distorted octahedral, with the -C CH fragment and the Cl ligand in trans positions. The four P atoms occupy the equatorial plane of the octahedron and the chloride and acetylide ligands the axial positions.

Idioma originalInglés
PublicaciónActa Crystallographica Section E: Structure Reports Online
Volumen68
N.º12
DOI
EstadoPublicada - dic 2012

Áreas temáticas de ASJC Scopus

  • Física de la materia condensada
  • Ciencia de los materiales (todo)
  • Química (todo)

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