Trans-Bis[1,2-bis(diphenylphosphanyl)ethane]chlorido(ethynyl)ruthenium(II)

Alexander Trujillo, Mauricio Fuentealba, Ramiro Arratia-Perez, Judith A K Howard

Resultado de la investigación: Article

2 Citas (Scopus)

Resumen

The molecular structure of the title compound, trans-[Cu(C2H)Cl(C26H24P2)2] , consists of an RuII cation, located on an inversion centre, in an octahedral environment defined by two chelating phosphines, one acetylide and one chloride ligand. The -C CH and the chlorine ligands are disordered over two equivalent positions (0.5 occupancy each). The coordination geometry is distorted octahedral, with the -C CH fragment and the Cl ligand in trans positions. The four P atoms occupy the equatorial plane of the octahedron and the chloride and acetylide ligands the axial positions.

Idioma originalEnglish
PublicaciónActa Crystallographica Section E: Structure Reports Online
Volumen68
N.º12
DOI
EstadoPublished - dic 2012

Huella dactilar

Ethane
Ruthenium
ethane
ruthenium
Ligands
ligands
Chlorides
chlorides
methylidyne
Phosphines
Chlorine
Chelation
phosphines
Molecular structure
chlorine
Cations
molecular structure
Positive ions
fragments
inversions

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Materials Science(all)
  • Chemistry(all)

Citar esto

@article{32c8ba00b65440be8004b2eea6fb1f8a,
title = "Trans-Bis[1,2-bis(diphenylphosphanyl)ethane]chlorido(ethynyl)ruthenium(II)",
abstract = "The molecular structure of the title compound, trans-[Cu(C2H)Cl(C26H24P2)2] , consists of an RuII cation, located on an inversion centre, in an octahedral environment defined by two chelating phosphines, one acetylide and one chloride ligand. The -C CH and the chlorine ligands are disordered over two equivalent positions (0.5 occupancy each). The coordination geometry is distorted octahedral, with the -C CH fragment and the Cl ligand in trans positions. The four P atoms occupy the equatorial plane of the octahedron and the chloride and acetylide ligands the axial positions.",
keywords = "data-to-parameter ratio = 22.1, disorder in main residue, mean ω(C-C) = 0.003 {\AA}, R factor = 0.030, single-crystal X-ray study, T = 120 K, wR factor = 0.072",
author = "Alexander Trujillo and Mauricio Fuentealba and Ramiro Arratia-Perez and Howard, {Judith A K}",
year = "2012",
month = "12",
doi = "10.1107/S1600536812044558",
language = "English",
volume = "68",
journal = "Acta Crystallographica Section E: Structure Reports Online",
issn = "1600-5368",
publisher = "International Union of Crystallography",
number = "12",

}

Trans-Bis[1,2-bis(diphenylphosphanyl)ethane]chlorido(ethynyl)ruthenium(II). / Trujillo, Alexander; Fuentealba, Mauricio; Arratia-Perez, Ramiro; Howard, Judith A K.

En: Acta Crystallographica Section E: Structure Reports Online, Vol. 68, N.º 12, 12.2012.

Resultado de la investigación: Article

TY - JOUR

T1 - Trans-Bis[1,2-bis(diphenylphosphanyl)ethane]chlorido(ethynyl)ruthenium(II)

AU - Trujillo, Alexander

AU - Fuentealba, Mauricio

AU - Arratia-Perez, Ramiro

AU - Howard, Judith A K

PY - 2012/12

Y1 - 2012/12

N2 - The molecular structure of the title compound, trans-[Cu(C2H)Cl(C26H24P2)2] , consists of an RuII cation, located on an inversion centre, in an octahedral environment defined by two chelating phosphines, one acetylide and one chloride ligand. The -C CH and the chlorine ligands are disordered over two equivalent positions (0.5 occupancy each). The coordination geometry is distorted octahedral, with the -C CH fragment and the Cl ligand in trans positions. The four P atoms occupy the equatorial plane of the octahedron and the chloride and acetylide ligands the axial positions.

AB - The molecular structure of the title compound, trans-[Cu(C2H)Cl(C26H24P2)2] , consists of an RuII cation, located on an inversion centre, in an octahedral environment defined by two chelating phosphines, one acetylide and one chloride ligand. The -C CH and the chlorine ligands are disordered over two equivalent positions (0.5 occupancy each). The coordination geometry is distorted octahedral, with the -C CH fragment and the Cl ligand in trans positions. The four P atoms occupy the equatorial plane of the octahedron and the chloride and acetylide ligands the axial positions.

KW - data-to-parameter ratio = 22.1

KW - disorder in main residue

KW - mean ω(C-C) = 0.003 Å

KW - R factor = 0.030

KW - single-crystal X-ray study

KW - T = 120 K

KW - wR factor = 0.072

UR - http://www.scopus.com/inward/record.url?scp=84870880846&partnerID=8YFLogxK

U2 - 10.1107/S1600536812044558

DO - 10.1107/S1600536812044558

M3 - Article

C2 - 23468677

AN - SCOPUS:84870880846

VL - 68

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

SN - 1600-5368

IS - 12

ER -