The shielding cone in spherical aromatic structures: Insights from models for spherical 2(N + 1)2 aromatic fullerenes

Alvaro Muñoz-Castro

Resultado de la investigación: Contribución a una revistaArtículorevisión exhaustiva

27 Citas (Scopus)

Resumen

A direct correlation between π- and spherical aromaticity of the aromatic structures was established by showing that they shared a characteristic shielding cone, resulting from a specific orientation of the applied field. Herein, we revealed the presence of a related long-range shielding cone in spherical aromatic species that was demonstrated through C20, C32, C50, and C60 Hirsh aromatic fullerenes. It was found that while for planar aromatics, the cone is reserved only for a perpendicularly applied field, for spherical aromatic compounds, the three-dimensional cage allows the formation of a shielding cone according to the given orientation of the external field.

Idioma originalInglés
Páginas (desde-hasta)12633-12636
Número de páginas4
PublicaciónPhysical Chemistry Chemical Physics
Volumen19
N.º20
DOI
EstadoPublicada - 2017
Publicado de forma externa

Áreas temáticas de ASJC Scopus

  • Física y astronomía (todo)
  • Química física y teórica

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