The first ReI organometallic complex with an organoimido-polyoxometalate ligand

Patricio Hermosilla-Ibáñez, Kerry Wrighton-Araneda, Gaspar Prado, Verónica Paredes-García, Nancy Pizarro, Andrés Vega, Diego Venegas-Yazigi

Resultado de la investigación: Article

2 Citas (Scopus)

Resumen

The spectroscopic, electrochemical and photophysical properties of the first ReI organometallic organoimido-polyoxometalate complex [n-Bu4N][Mo6O18NC6H4-CH2-N3C2H2-Re-phen(CO)3] compared with all fragments are reported. The UV-Vis spectra are analysed using experimental and theoretical tools. In contrast to the reported studies in the literature, our results show that a new more intense band is present in the spectra of the hybrid ligand obscuring the intra-polyanion charge transfer. The electrochemical results show that the strong acceptor character of the polyoxometalate fragment is quenched by the condensation of the phenyl-triazole molecule.

Idioma originalEnglish
Páginas (desde-hasta)8611-8620
Número de páginas10
PublicaciónDalton Transactions
Volumen46
N.º26
DOI
EstadoPublished - 2017

Huella dactilar

Organometallics
Ligands
Triazoles
Carbon Monoxide
Charge transfer
Condensation
Molecules
polyoxometalate I
polyanions

ASJC Scopus subject areas

  • Inorganic Chemistry

Citar esto

Hermosilla-Ibáñez, Patricio ; Wrighton-Araneda, Kerry ; Prado, Gaspar ; Paredes-García, Verónica ; Pizarro, Nancy ; Vega, Andrés ; Venegas-Yazigi, Diego. / The first ReI organometallic complex with an organoimido-polyoxometalate ligand. En: Dalton Transactions. 2017 ; Vol. 46, N.º 26. pp. 8611-8620.
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abstract = "The spectroscopic, electrochemical and photophysical properties of the first ReI organometallic organoimido-polyoxometalate complex [n-Bu4N][Mo6O18NC6H4-CH2-N3C2H2-Re-phen(CO)3] compared with all fragments are reported. The UV-Vis spectra are analysed using experimental and theoretical tools. In contrast to the reported studies in the literature, our results show that a new more intense band is present in the spectra of the hybrid ligand obscuring the intra-polyanion charge transfer. The electrochemical results show that the strong acceptor character of the polyoxometalate fragment is quenched by the condensation of the phenyl-triazole molecule.",
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Hermosilla-Ibáñez, P, Wrighton-Araneda, K, Prado, G, Paredes-García, V, Pizarro, N, Vega, A & Venegas-Yazigi, D 2017, 'The first ReI organometallic complex with an organoimido-polyoxometalate ligand', Dalton Transactions, vol. 46, n.º 26, pp. 8611-8620. https://doi.org/10.1039/c7dt01633f

The first ReI organometallic complex with an organoimido-polyoxometalate ligand. / Hermosilla-Ibáñez, Patricio; Wrighton-Araneda, Kerry; Prado, Gaspar; Paredes-García, Verónica; Pizarro, Nancy; Vega, Andrés; Venegas-Yazigi, Diego.

En: Dalton Transactions, Vol. 46, N.º 26, 2017, p. 8611-8620.

Resultado de la investigación: Article

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T1 - The first ReI organometallic complex with an organoimido-polyoxometalate ligand

AU - Hermosilla-Ibáñez, Patricio

AU - Wrighton-Araneda, Kerry

AU - Prado, Gaspar

AU - Paredes-García, Verónica

AU - Pizarro, Nancy

AU - Vega, Andrés

AU - Venegas-Yazigi, Diego

PY - 2017

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