The first ReI organometallic complex with an organoimido-polyoxometalate ligand

Patricio Hermosilla-Ibáñez, Kerry Wrighton-Araneda, Gaspar Prado, Verónica Paredes-García, Nancy Pizarro, Andrés Vega, Diego Venegas-Yazigi

Resultado de la investigación: Contribución a una revistaArtículo

3 Citas (Scopus)

Resumen

The spectroscopic, electrochemical and photophysical properties of the first ReI organometallic organoimido-polyoxometalate complex [n-Bu4N][Mo6O18NC6H4-CH2-N3C2H2-Re-phen(CO)3] compared with all fragments are reported. The UV-Vis spectra are analysed using experimental and theoretical tools. In contrast to the reported studies in the literature, our results show that a new more intense band is present in the spectra of the hybrid ligand obscuring the intra-polyanion charge transfer. The electrochemical results show that the strong acceptor character of the polyoxometalate fragment is quenched by the condensation of the phenyl-triazole molecule.

Idioma originalInglés
Páginas (desde-hasta)8611-8620
Número de páginas10
PublicaciónDalton Transactions
Volumen46
N.º26
DOI
EstadoPublicada - 2017

Áreas temáticas de ASJC Scopus

  • Química inorgánica

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