Testing the effectiveness of the isoelectronic substitution principle through the transformation of aromatic osmathiophene derivatives into their inorganic analogues

Alejandro Vásquez-Espinal, Jordi Poater, Miquel Solà, William Tiznado, Rafael Islas

Resultado de la investigación: Contribución a una revistaArtículo

2 Citas (Scopus)

Resumen

The objective of the current work is to evaluate the effectiveness of the isoelectronic substitution (IS) principle on a series of complexes with the general formula OsCl2(SX3H3)(PH3)2, where X3 represents the moieties CCC, CCB, CCN, CBN, CNB or NCB, formed by substitution of the carbon atoms in CCC by either the isoelectronic B- or N+ separately, or by both. The SX3H3 moiety forms, together with Os, an aromatic five-membered ring (5-MR) called osmathiophene. The preservation of stability and aromaticity in the resulting systems is used to indicate the effectiveness of the IS principle. The aromaticity of the proposed molecules is analyzed according to the magnetic (induced magnetic field (Bind)) and electronic (through the multicenter index (MCI)) criteria. In addition a chemical bonding analysis on selected species is performed by the adaptive natural density partitioning (AdNDP) method.

Idioma originalInglés
Páginas (desde-hasta)1168-1178
Número de páginas11
PublicaciónNew Journal of Chemistry
Volumen41
N.º3
DOI
EstadoPublicada - 2017

Áreas temáticas de ASJC Scopus

  • Catálisis
  • Química (todo)
  • Química de los materiales

Huella Profundice en los temas de investigación de 'Testing the effectiveness of the isoelectronic substitution principle through the transformation of aromatic osmathiophene derivatives into their inorganic analogues'. En conjunto forman una huella única.

  • Citar esto