Synthesis, characterization of a new carbonylated zirconium metallocene using a dichloro-zirconocene derived from partially alkylated s-indacene

J. F. Araneda, S. Salinas, D. Mac-Leod-Carey, A. Muñoz-Castro, R. Arratia-Perez, C. Adams, I. Chávez, J. M. Manríquez

Resultado de la investigación: Article

3 Citas (Scopus)

Resumen

This work describes the synthesis and characterization of new organometallic species, an unprecedented mononuclear zirconium complex bearing a tetraalkylated s-indacene ligand, and secondly, its respective dicarbonyl complex obtained by reduction with Mg/HgCl2. Theoretical calculations of these two compounds were carried out to gain further understanding of these novel molecular systems.

Idioma originalEnglish
Páginas (desde-hasta)269-273
Número de páginas5
PublicaciónJournal of the Chilean Chemical Society
Volumen54
N.º3
DOI
EstadoPublished - 1 dic 2009

Huella dactilar

Bearings (structural)
Mercuric Chloride
Organometallics
Ligands
Zirconocene dichloride
metallocene

ASJC Scopus subject areas

  • Chemistry(all)

Citar esto

Araneda, J. F. ; Salinas, S. ; Mac-Leod-Carey, D. ; Muñoz-Castro, A. ; Arratia-Perez, R. ; Adams, C. ; Chávez, I. ; Manríquez, J. M. / Synthesis, characterization of a new carbonylated zirconium metallocene using a dichloro-zirconocene derived from partially alkylated s-indacene. En: Journal of the Chilean Chemical Society. 2009 ; Vol. 54, N.º 3. pp. 269-273.
@article{eb244b6e5d4147deb639ba6f13e4d4d4,
title = "Synthesis, characterization of a new carbonylated zirconium metallocene using a dichloro-zirconocene derived from partially alkylated s-indacene",
abstract = "This work describes the synthesis and characterization of new organometallic species, an unprecedented mononuclear zirconium complex bearing a tetraalkylated s-indacene ligand, and secondly, its respective dicarbonyl complex obtained by reduction with Mg/HgCl2. Theoretical calculations of these two compounds were carried out to gain further understanding of these novel molecular systems.",
keywords = "DFT, S-indaceno, Zirconium dicarbonyl, Zirconocene",
author = "Araneda, {J. F.} and S. Salinas and D. Mac-Leod-Carey and A. Mu{\~n}oz-Castro and R. Arratia-Perez and C. Adams and I. Ch{\'a}vez and Manr{\'i}quez, {J. M.}",
year = "2009",
month = "12",
day = "1",
doi = "10.4067/S0717-97072009000300014",
language = "English",
volume = "54",
pages = "269--273",
journal = "Journal of the Chilean Chemical Society",
issn = "0717-9324",
publisher = "Sociedad Chilena De Quimica",
number = "3",

}

Synthesis, characterization of a new carbonylated zirconium metallocene using a dichloro-zirconocene derived from partially alkylated s-indacene. / Araneda, J. F.; Salinas, S.; Mac-Leod-Carey, D.; Muñoz-Castro, A.; Arratia-Perez, R.; Adams, C.; Chávez, I.; Manríquez, J. M.

En: Journal of the Chilean Chemical Society, Vol. 54, N.º 3, 01.12.2009, p. 269-273.

Resultado de la investigación: Article

TY - JOUR

T1 - Synthesis, characterization of a new carbonylated zirconium metallocene using a dichloro-zirconocene derived from partially alkylated s-indacene

AU - Araneda, J. F.

AU - Salinas, S.

AU - Mac-Leod-Carey, D.

AU - Muñoz-Castro, A.

AU - Arratia-Perez, R.

AU - Adams, C.

AU - Chávez, I.

AU - Manríquez, J. M.

PY - 2009/12/1

Y1 - 2009/12/1

N2 - This work describes the synthesis and characterization of new organometallic species, an unprecedented mononuclear zirconium complex bearing a tetraalkylated s-indacene ligand, and secondly, its respective dicarbonyl complex obtained by reduction with Mg/HgCl2. Theoretical calculations of these two compounds were carried out to gain further understanding of these novel molecular systems.

AB - This work describes the synthesis and characterization of new organometallic species, an unprecedented mononuclear zirconium complex bearing a tetraalkylated s-indacene ligand, and secondly, its respective dicarbonyl complex obtained by reduction with Mg/HgCl2. Theoretical calculations of these two compounds were carried out to gain further understanding of these novel molecular systems.

KW - DFT

KW - S-indaceno

KW - Zirconium dicarbonyl

KW - Zirconocene

UR - http://www.scopus.com/inward/record.url?scp=77950635851&partnerID=8YFLogxK

U2 - 10.4067/S0717-97072009000300014

DO - 10.4067/S0717-97072009000300014

M3 - Article

AN - SCOPUS:77950635851

VL - 54

SP - 269

EP - 273

JO - Journal of the Chilean Chemical Society

JF - Journal of the Chilean Chemical Society

SN - 0717-9324

IS - 3

ER -