Synthesis and optimization of experimental variables of a hybrid organic-inorganic compound

D. Contreras, Y. Moreno, Y. Salgado, G. Cárdenas, R. Baggio, O. Peña, J. Y. Pivan

Resultado de la investigación: Article

9 Citas (Scopus)

Resumen

A multivariate study of the experimental parameters used in hydrothermal techniques (temperature, time, pH, relationship among reagents) was performed, and applied to the synthesis of a copper hybrid compound, [Cu(biqui)(H 2PO4)2]. In this way it was possible to rationalize the crystal yield and to find the best conditions to obtain the highest crystal production. The optimization was carried out through the Response Surface Method (RSM). The optimal values were determined over the response surface by the SIMPLEX method. These values were pH = 2.5, temperature = 123°C, time = 3.32 days and Cu(NO3)2 mass = 0.354 g. With these values the predicted crystal mass is 0.0376 ± 0.0082 g, considering the 95% of confidence interval.

Idioma originalEnglish
Páginas (desde-hasta)1751-1754
Número de páginas4
PublicaciónNew Journal of Chemistry
Volumen31
N.º10
DOI
EstadoPublished - 2007

Huella dactilar

Inorganic compounds
Crystals
Copper
Temperature

ASJC Scopus subject areas

  • Chemistry(all)
  • Catalysis
  • Materials Chemistry

Citar esto

Contreras, D., Moreno, Y., Salgado, Y., Cárdenas, G., Baggio, R., Peña, O., & Pivan, J. Y. (2007). Synthesis and optimization of experimental variables of a hybrid organic-inorganic compound. New Journal of Chemistry, 31(10), 1751-1754. https://doi.org/10.1039/b703592f
Contreras, D. ; Moreno, Y. ; Salgado, Y. ; Cárdenas, G. ; Baggio, R. ; Peña, O. ; Pivan, J. Y. / Synthesis and optimization of experimental variables of a hybrid organic-inorganic compound. En: New Journal of Chemistry. 2007 ; Vol. 31, N.º 10. pp. 1751-1754.
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abstract = "A multivariate study of the experimental parameters used in hydrothermal techniques (temperature, time, pH, relationship among reagents) was performed, and applied to the synthesis of a copper hybrid compound, [Cu(biqui)(H 2PO4)2]. In this way it was possible to rationalize the crystal yield and to find the best conditions to obtain the highest crystal production. The optimization was carried out through the Response Surface Method (RSM). The optimal values were determined over the response surface by the SIMPLEX method. These values were pH = 2.5, temperature = 123°C, time = 3.32 days and Cu(NO3)2 mass = 0.354 g. With these values the predicted crystal mass is 0.0376 ± 0.0082 g, considering the 95{\%} of confidence interval.",
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Contreras, D, Moreno, Y, Salgado, Y, Cárdenas, G, Baggio, R, Peña, O & Pivan, JY 2007, 'Synthesis and optimization of experimental variables of a hybrid organic-inorganic compound', New Journal of Chemistry, vol. 31, n.º 10, pp. 1751-1754. https://doi.org/10.1039/b703592f

Synthesis and optimization of experimental variables of a hybrid organic-inorganic compound. / Contreras, D.; Moreno, Y.; Salgado, Y.; Cárdenas, G.; Baggio, R.; Peña, O.; Pivan, J. Y.

En: New Journal of Chemistry, Vol. 31, N.º 10, 2007, p. 1751-1754.

Resultado de la investigación: Article

TY - JOUR

T1 - Synthesis and optimization of experimental variables of a hybrid organic-inorganic compound

AU - Contreras, D.

AU - Moreno, Y.

AU - Salgado, Y.

AU - Cárdenas, G.

AU - Baggio, R.

AU - Peña, O.

AU - Pivan, J. Y.

PY - 2007

Y1 - 2007

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AB - A multivariate study of the experimental parameters used in hydrothermal techniques (temperature, time, pH, relationship among reagents) was performed, and applied to the synthesis of a copper hybrid compound, [Cu(biqui)(H 2PO4)2]. In this way it was possible to rationalize the crystal yield and to find the best conditions to obtain the highest crystal production. The optimization was carried out through the Response Surface Method (RSM). The optimal values were determined over the response surface by the SIMPLEX method. These values were pH = 2.5, temperature = 123°C, time = 3.32 days and Cu(NO3)2 mass = 0.354 g. With these values the predicted crystal mass is 0.0376 ± 0.0082 g, considering the 95% of confidence interval.

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Contreras D, Moreno Y, Salgado Y, Cárdenas G, Baggio R, Peña O y otros. Synthesis and optimization of experimental variables of a hybrid organic-inorganic compound. New Journal of Chemistry. 2007;31(10):1751-1754. https://doi.org/10.1039/b703592f