Study of Na/Cu/TiO 2 catalysts for the storage and reduction of NO

Sichem Guerrero, Igor Guzmán, Gonzalo Aguila, Boris Chornik, Paulo Araya

Resultado de la investigación: Article

13 Citas (Scopus)

Resumen

A Pt-free system based on Na/Cu/TiO 2 catalysts was used to study the adsorption of NO under lean conditions. The results show that the NO adsorption activity dramatically increased when both sodium and copper are in intimate contact. Although copper is the active phase in the oxidation of NO to NO 2, it was found that the addition of sodium species is of vital importance on the subsequent adsorption of NO 2, which mainly occurs on the surface of the alkali in the form of nitrates and nitrites. It was found that a loading increase of the alkali led to an increase in the reduction temperature of the copper phase, which is ascribed to a close interaction between the copper and the sodium phases. Among the Na loadings that were studied, the addition of 5% Na gave the optimum adsorption of NO. After successive cycles of adsorption, the catalysts were fully regenerated at temperatures higher than 250°C using either CO or H 2 as a reducing agent.

Idioma originalEnglish
Páginas (desde-hasta)282-295
Número de páginas14
PublicaciónApplied Catalysis B: Environmental
Volumen123-124
DOI
EstadoPublished - 23 jul 2012

Huella dactilar

catalyst
Copper
adsorption
Adsorption
Catalysts
copper
Sodium
sodium
Alkalies
Reducing Agents
Reducing agents
Carbon Monoxide
Nitrites
Nitrates
nitrite
nitrate
oxidation
Oxidation
Temperature
temperature

ASJC Scopus subject areas

  • Catalysis
  • Environmental Science(all)
  • Process Chemistry and Technology

Citar esto

Guerrero, Sichem ; Guzmán, Igor ; Aguila, Gonzalo ; Chornik, Boris ; Araya, Paulo. / Study of Na/Cu/TiO 2 catalysts for the storage and reduction of NO. En: Applied Catalysis B: Environmental. 2012 ; Vol. 123-124. pp. 282-295.
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abstract = "A Pt-free system based on Na/Cu/TiO 2 catalysts was used to study the adsorption of NO under lean conditions. The results show that the NO adsorption activity dramatically increased when both sodium and copper are in intimate contact. Although copper is the active phase in the oxidation of NO to NO 2, it was found that the addition of sodium species is of vital importance on the subsequent adsorption of NO 2, which mainly occurs on the surface of the alkali in the form of nitrates and nitrites. It was found that a loading increase of the alkali led to an increase in the reduction temperature of the copper phase, which is ascribed to a close interaction between the copper and the sodium phases. Among the Na loadings that were studied, the addition of 5{\%} Na gave the optimum adsorption of NO. After successive cycles of adsorption, the catalysts were fully regenerated at temperatures higher than 250°C using either CO or H 2 as a reducing agent.",
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Study of Na/Cu/TiO 2 catalysts for the storage and reduction of NO. / Guerrero, Sichem; Guzmán, Igor; Aguila, Gonzalo; Chornik, Boris; Araya, Paulo.

En: Applied Catalysis B: Environmental, Vol. 123-124, 23.07.2012, p. 282-295.

Resultado de la investigación: Article

TY - JOUR

T1 - Study of Na/Cu/TiO 2 catalysts for the storage and reduction of NO

AU - Guerrero, Sichem

AU - Guzmán, Igor

AU - Aguila, Gonzalo

AU - Chornik, Boris

AU - Araya, Paulo

PY - 2012/7/23

Y1 - 2012/7/23

N2 - A Pt-free system based on Na/Cu/TiO 2 catalysts was used to study the adsorption of NO under lean conditions. The results show that the NO adsorption activity dramatically increased when both sodium and copper are in intimate contact. Although copper is the active phase in the oxidation of NO to NO 2, it was found that the addition of sodium species is of vital importance on the subsequent adsorption of NO 2, which mainly occurs on the surface of the alkali in the form of nitrates and nitrites. It was found that a loading increase of the alkali led to an increase in the reduction temperature of the copper phase, which is ascribed to a close interaction between the copper and the sodium phases. Among the Na loadings that were studied, the addition of 5% Na gave the optimum adsorption of NO. After successive cycles of adsorption, the catalysts were fully regenerated at temperatures higher than 250°C using either CO or H 2 as a reducing agent.

AB - A Pt-free system based on Na/Cu/TiO 2 catalysts was used to study the adsorption of NO under lean conditions. The results show that the NO adsorption activity dramatically increased when both sodium and copper are in intimate contact. Although copper is the active phase in the oxidation of NO to NO 2, it was found that the addition of sodium species is of vital importance on the subsequent adsorption of NO 2, which mainly occurs on the surface of the alkali in the form of nitrates and nitrites. It was found that a loading increase of the alkali led to an increase in the reduction temperature of the copper phase, which is ascribed to a close interaction between the copper and the sodium phases. Among the Na loadings that were studied, the addition of 5% Na gave the optimum adsorption of NO. After successive cycles of adsorption, the catalysts were fully regenerated at temperatures higher than 250°C using either CO or H 2 as a reducing agent.

KW - Cu H -TPR

KW - Cu/TiO

KW - Na/Cu/TiO

KW - NO oxidation

KW - NO reduction

KW - NO storage

KW - NSR

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JO - Applied Catalysis B: Environmental

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