TY - JOUR
T1 - Structural and photophysical properties of a mononuclear Re(I) complex
T2 - [P,N-{(C6H5)2(C5H 5N)P}Re(CO)3Br]
AU - Venegas, Felipe
AU - Pizarro, Nancy
AU - Vega, Andres
PY - 2011
Y1 - 2011
N2 - We have prepared a new monometallic rhenium(I) carbonyl, the complex [P,N-{(C6H5)2 (C5H 5N)P}Re(CO) 3Br] by direct reaction of (Re(CO) 3Br(THF)) 2 and the ligand (C6H 5)2 (C5H5N)P The structure in the complex shows the pyridinic-phosphine ligand in a chelating mode, occupying cis positions around the rhenium octahedral environment. The molecule displays an absorption band centered at 315 nm which has been assigned to a MLCT transition, and a luminescence quantum yield of 0.001.
AB - We have prepared a new monometallic rhenium(I) carbonyl, the complex [P,N-{(C6H5)2 (C5H 5N)P}Re(CO) 3Br] by direct reaction of (Re(CO) 3Br(THF)) 2 and the ligand (C6H 5)2 (C5H5N)P The structure in the complex shows the pyridinic-phosphine ligand in a chelating mode, occupying cis positions around the rhenium octahedral environment. The molecule displays an absorption band centered at 315 nm which has been assigned to a MLCT transition, and a luminescence quantum yield of 0.001.
UR - http://www.scopus.com/inward/record.url?scp=84856120979&partnerID=8YFLogxK
U2 - 10.4067/S0717-97072011000300023
DO - 10.4067/S0717-97072011000300023
M3 - Article
AN - SCOPUS:84856120979
SN - 0717-9324
VL - 56
SP - 823
EP - 826
JO - Journal of the Chilean Chemical Society
JF - Journal of the Chilean Chemical Society
IS - 3
ER -