Structural and electronic properties of Polyoxovanadoborates containing the [V 12 B 18 O 60 ] core in different mixed valence states

Patricio Hermosilla-Ibáñez, Karina Muñoz-Becerra, Verónica Paredes-García, Eric Le Fur, Evgenia Spodine, Diego Venegas-Yazigi

Resultado de la investigación: Review article

4 Citas (Scopus)

Resumen

This review summarizes all published data until April 2015 related to crystalline lattices formed by the [V 12 B 18 O 60 ] core, which generates polyanionic clusters with different degrees of protonation and mixed-valence ratios. The negative charge of this cluster is counterbalanced by different cations such as protonated amines, hydronium, and alkaline, and transition metal ions. The cluster is shown to form extended 1D, 2D, or 3D frameworks by forming covalent bonds or presenting hydrogen bond interactions with the present secondary cations. These cations have little influence on the solid state reflectance UV-visible spectra of the polyanionic cluster, but are shown to modify the FT-IR spectra and the magnetic behavior of the different reported species.

Idioma originalEnglish
Páginas (desde-hasta)309-331
Número de páginas23
PublicaciónInorganics
Volumen3
N.º3
DOI
EstadoPublished - 1 sep 2015

Huella dactilar

Electronic properties
Cations
Structural properties
Covalent bonds
Protonation
Crystal lattices
Amines
Transition metals
Metal ions
Hydrogen bonds
Crystalline materials

ASJC Scopus subject areas

  • Inorganic Chemistry

Citar esto

Hermosilla-Ibáñez, Patricio ; Muñoz-Becerra, Karina ; Paredes-García, Verónica ; Fur, Eric Le ; Spodine, Evgenia ; Venegas-Yazigi, Diego. / Structural and electronic properties of Polyoxovanadoborates containing the [V 12 B 18 O 60 ] core in different mixed valence states. En: Inorganics. 2015 ; Vol. 3, N.º 3. pp. 309-331.
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abstract = "This review summarizes all published data until April 2015 related to crystalline lattices formed by the [V 12 B 18 O 60 ] core, which generates polyanionic clusters with different degrees of protonation and mixed-valence ratios. The negative charge of this cluster is counterbalanced by different cations such as protonated amines, hydronium, and alkaline, and transition metal ions. The cluster is shown to form extended 1D, 2D, or 3D frameworks by forming covalent bonds or presenting hydrogen bond interactions with the present secondary cations. These cations have little influence on the solid state reflectance UV-visible spectra of the polyanionic cluster, but are shown to modify the FT-IR spectra and the magnetic behavior of the different reported species.",
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Structural and electronic properties of Polyoxovanadoborates containing the [V 12 B 18 O 60 ] core in different mixed valence states. / Hermosilla-Ibáñez, Patricio; Muñoz-Becerra, Karina; Paredes-García, Verónica; Fur, Eric Le; Spodine, Evgenia; Venegas-Yazigi, Diego.

En: Inorganics, Vol. 3, N.º 3, 01.09.2015, p. 309-331.

Resultado de la investigación: Review article

TY - JOUR

T1 - Structural and electronic properties of Polyoxovanadoborates containing the [V 12 B 18 O 60 ] core in different mixed valence states

AU - Hermosilla-Ibáñez, Patricio

AU - Muñoz-Becerra, Karina

AU - Paredes-García, Verónica

AU - Fur, Eric Le

AU - Spodine, Evgenia

AU - Venegas-Yazigi, Diego

PY - 2015/9/1

Y1 - 2015/9/1

N2 - This review summarizes all published data until April 2015 related to crystalline lattices formed by the [V 12 B 18 O 60 ] core, which generates polyanionic clusters with different degrees of protonation and mixed-valence ratios. The negative charge of this cluster is counterbalanced by different cations such as protonated amines, hydronium, and alkaline, and transition metal ions. The cluster is shown to form extended 1D, 2D, or 3D frameworks by forming covalent bonds or presenting hydrogen bond interactions with the present secondary cations. These cations have little influence on the solid state reflectance UV-visible spectra of the polyanionic cluster, but are shown to modify the FT-IR spectra and the magnetic behavior of the different reported species.

AB - This review summarizes all published data until April 2015 related to crystalline lattices formed by the [V 12 B 18 O 60 ] core, which generates polyanionic clusters with different degrees of protonation and mixed-valence ratios. The negative charge of this cluster is counterbalanced by different cations such as protonated amines, hydronium, and alkaline, and transition metal ions. The cluster is shown to form extended 1D, 2D, or 3D frameworks by forming covalent bonds or presenting hydrogen bond interactions with the present secondary cations. These cations have little influence on the solid state reflectance UV-visible spectra of the polyanionic cluster, but are shown to modify the FT-IR spectra and the magnetic behavior of the different reported species.

KW - Electronic properties

KW - FT-IR

KW - Magnetic behavior

KW - Polyoxovanadoborate

KW - Reflectance UV-vis

KW - VBO

KW - [V B O ]

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U2 - 10.3390/inorganics3030309

DO - 10.3390/inorganics3030309

M3 - Review article

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SP - 309

EP - 331

JO - Inorganics

JF - Inorganics

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