Stop rotating! One substitution halts the B19 - motor

Francisco Cervantes-Navarro, Gerardo Martínez-Guajardo, Edison Osorio, Diego Moreno, William Tiznado, Rafael Islas, Kelling J. Donald, Gabriel Merino

Resultado de la investigación: Article

24 Citas (Scopus)

Resumen

The B19 - anion and other boron species have been dubbed 'Wankel motors' for the almost barrierless rotation of inner and outer concentric rings relative to each other in these compounds. A single substitution in B19 - is shown to shut down the well-established fluxionality in the anion. A carbon atom substituted in the structure to give a neutral CB18 species is shown computationally to enforce bond localization. This journal is

Idioma originalEnglish
Páginas (desde-hasta)10680-10682
Número de páginas3
PublicaciónChemical Communications
Volumen50
N.º73
DOI
EstadoPublished - 21 sep 2014

Huella dactilar

Anions
Substitution reactions
Negative ions
Boron
Carbon
Atoms

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

Citar esto

Cervantes-Navarro, F., Martínez-Guajardo, G., Osorio, E., Moreno, D., Tiznado, W., Islas, R., ... Merino, G. (2014). Stop rotating! One substitution halts the B19 - motor. Chemical Communications, 50(73), 10680-10682. https://doi.org/10.1039/c4cc03698k
Cervantes-Navarro, Francisco ; Martínez-Guajardo, Gerardo ; Osorio, Edison ; Moreno, Diego ; Tiznado, William ; Islas, Rafael ; Donald, Kelling J. ; Merino, Gabriel. / Stop rotating! One substitution halts the B19 - motor. En: Chemical Communications. 2014 ; Vol. 50, N.º 73. pp. 10680-10682.
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Cervantes-Navarro, F, Martínez-Guajardo, G, Osorio, E, Moreno, D, Tiznado, W, Islas, R, Donald, KJ & Merino, G 2014, 'Stop rotating! One substitution halts the B19 - motor', Chemical Communications, vol. 50, n.º 73, pp. 10680-10682. https://doi.org/10.1039/c4cc03698k

Stop rotating! One substitution halts the B19 - motor. / Cervantes-Navarro, Francisco; Martínez-Guajardo, Gerardo; Osorio, Edison; Moreno, Diego; Tiznado, William; Islas, Rafael; Donald, Kelling J.; Merino, Gabriel.

En: Chemical Communications, Vol. 50, N.º 73, 21.09.2014, p. 10680-10682.

Resultado de la investigación: Article

TY - JOUR

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AU - Martínez-Guajardo, Gerardo

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AU - Tiznado, William

AU - Islas, Rafael

AU - Donald, Kelling J.

AU - Merino, Gabriel

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Cervantes-Navarro F, Martínez-Guajardo G, Osorio E, Moreno D, Tiznado W, Islas R y otros. Stop rotating! One substitution halts the B19 - motor. Chemical Communications. 2014 sep 21;50(73):10680-10682. https://doi.org/10.1039/c4cc03698k