Spin-orbit effects in metal-metal multiple bonded M2X 8 halide complexes

Lucía Hernández-Acevedo, Ramiro Arratia-Pérez

Resultado de la investigación: Article

4 Citas (Scopus)

Resumen

Dirac molecular spinor calculations on the Re2Cl 8 2-, Re2Br8 2-, Os 2Cl8 2- (both staggered and eclipsed isomers), Os2Br8 2- and Os2I8 2- cluster ions are reported. Here we report the calculations of the spin-orbit splitting affecting the metal and ligand core-like states and also affecting the π and δ metal-metal bonds. We also compare the calculated molecular spin-orbit splitting against the calculated atomic spin-orbit splitting, and, against available experimental data.

Idioma originalEnglish
Páginas (desde-hasta)361-365
Número de páginas5
PublicaciónJournal of the Chilean Chemical Society
Volumen49
N.º4
EstadoPublished - dic 2004

Huella dactilar

Orbits
Metals
Isomers
Ions
Ligands

ASJC Scopus subject areas

  • Chemistry(all)

Citar esto

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abstract = "Dirac molecular spinor calculations on the Re2Cl 8 2-, Re2Br8 2-, Os 2Cl8 2- (both staggered and eclipsed isomers), Os2Br8 2- and Os2I8 2- cluster ions are reported. Here we report the calculations of the spin-orbit splitting affecting the metal and ligand core-like states and also affecting the π and δ metal-metal bonds. We also compare the calculated molecular spin-orbit splitting against the calculated atomic spin-orbit splitting, and, against available experimental data.",
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Spin-orbit effects in metal-metal multiple bonded M2X 8 halide complexes. / Hernández-Acevedo, Lucía; Arratia-Pérez, Ramiro.

En: Journal of the Chilean Chemical Society, Vol. 49, N.º 4, 12.2004, p. 361-365.

Resultado de la investigación: Article

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AU - Arratia-Pérez, Ramiro

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N2 - Dirac molecular spinor calculations on the Re2Cl 8 2-, Re2Br8 2-, Os 2Cl8 2- (both staggered and eclipsed isomers), Os2Br8 2- and Os2I8 2- cluster ions are reported. Here we report the calculations of the spin-orbit splitting affecting the metal and ligand core-like states and also affecting the π and δ metal-metal bonds. We also compare the calculated molecular spin-orbit splitting against the calculated atomic spin-orbit splitting, and, against available experimental data.

AB - Dirac molecular spinor calculations on the Re2Cl 8 2-, Re2Br8 2-, Os 2Cl8 2- (both staggered and eclipsed isomers), Os2Br8 2- and Os2I8 2- cluster ions are reported. Here we report the calculations of the spin-orbit splitting affecting the metal and ligand core-like states and also affecting the π and δ metal-metal bonds. We also compare the calculated molecular spin-orbit splitting against the calculated atomic spin-orbit splitting, and, against available experimental data.

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