Sorption of apolar pesticides by units of benzoic acid propyl ester in cyclic phosphazene

Jorge Rivas, María Luisa Valenzuela

Resultado de la investigación: Article

Resumen

The effects of temperature, pH and agitation time (equilibrium) on the adsorption process of different pesticides on N3P3(OC6H4COOCH2CH2CH3)6 was studied. With optimal conditions experimental, the adsorption isotherms have been realized with through Langmuir and Freundlich models. Pesticides are compounds used mainly in agriculture to control various species (plants, insects, worms, fungi). Due to their physicochemical properties, they can remain for a long time in the application sites, bioaccumulating and moving between environmental compartments which generate various environmental problems. The results obtained showed a physisorption mechanism for the fve pesticides studied, with higher sorption for: azinphos methyl (93,5 mg kg-1), carbaryl (290.5 mg kg-1) and carbofuran (580.5 mg kg-1) at 20 ° C, according to the models used.

Idioma originalEnglish
Páginas (desde-hasta)3783-3787
Número de páginas5
PublicaciónJournal of the Chilean Chemical Society
Volumen62
N.º4
EstadoPublished - 1 ene 2017
Publicado de forma externa

Huella dactilar

Benzoic Acid
Pesticides
Sorption
Esters
Azinphosmethyl
Carbofuran
Carbaryl
Physisorption
Fungi
Adsorption isotherms
Agriculture
Adsorption
Temperature

ASJC Scopus subject areas

  • Chemistry(all)

Citar esto

Rivas, Jorge ; Valenzuela, María Luisa. / Sorption of apolar pesticides by units of benzoic acid propyl ester in cyclic phosphazene. En: Journal of the Chilean Chemical Society. 2017 ; Vol. 62, N.º 4. pp. 3783-3787.
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Sorption of apolar pesticides by units of benzoic acid propyl ester in cyclic phosphazene. / Rivas, Jorge; Valenzuela, María Luisa.

En: Journal of the Chilean Chemical Society, Vol. 62, N.º 4, 01.01.2017, p. 3783-3787.

Resultado de la investigación: Article

TY - JOUR

T1 - Sorption of apolar pesticides by units of benzoic acid propyl ester in cyclic phosphazene

AU - Rivas, Jorge

AU - Valenzuela, María Luisa

PY - 2017/1/1

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N2 - The effects of temperature, pH and agitation time (equilibrium) on the adsorption process of different pesticides on N3P3(OC6H4COOCH2CH2CH3)6 was studied. With optimal conditions experimental, the adsorption isotherms have been realized with through Langmuir and Freundlich models. Pesticides are compounds used mainly in agriculture to control various species (plants, insects, worms, fungi). Due to their physicochemical properties, they can remain for a long time in the application sites, bioaccumulating and moving between environmental compartments which generate various environmental problems. The results obtained showed a physisorption mechanism for the fve pesticides studied, with higher sorption for: azinphos methyl (93,5 mg kg-1), carbaryl (290.5 mg kg-1) and carbofuran (580.5 mg kg-1) at 20 ° C, according to the models used.

AB - The effects of temperature, pH and agitation time (equilibrium) on the adsorption process of different pesticides on N3P3(OC6H4COOCH2CH2CH3)6 was studied. With optimal conditions experimental, the adsorption isotherms have been realized with through Langmuir and Freundlich models. Pesticides are compounds used mainly in agriculture to control various species (plants, insects, worms, fungi). Due to their physicochemical properties, they can remain for a long time in the application sites, bioaccumulating and moving between environmental compartments which generate various environmental problems. The results obtained showed a physisorption mechanism for the fve pesticides studied, with higher sorption for: azinphos methyl (93,5 mg kg-1), carbaryl (290.5 mg kg-1) and carbofuran (580.5 mg kg-1) at 20 ° C, according to the models used.

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