Quantitative characterization of the global electrophilicity power of common diene/dienophile pairs in Diels-Alder reactions

Luis R. Domingo, M. José Aurell, Patricia Pérez, Renato Contreras

Resultado de la investigación: Article

527 Citas (Scopus)

Resumen

The global electrophilicity power, ω, of a series of dienes and dienophiles commonly used in Diels-Alder reactions may be conveniently classified within a unique relative scale. Useful information about the polarity of transition state structures expected for a given reaction may be obtained from the difference in the global electrophilicity power, Δω, of the diene/dienophile interacting pair. Thus the polarity of the process can be related with non-polar (Δω small, pericyclic processes) and polar (Δω big, ionic processes) mechanisms.

Idioma originalEnglish
Páginas (desde-hasta)4417-4423
Número de páginas7
PublicaciónTetrahedron
Volumen58
N.º22
DOI
EstadoPublished - 27 may 2002

Huella dactilar

Cycloaddition Reaction

ASJC Scopus subject areas

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

Citar esto

Domingo, Luis R. ; Aurell, M. José ; Pérez, Patricia ; Contreras, Renato. / Quantitative characterization of the global electrophilicity power of common diene/dienophile pairs in Diels-Alder reactions. En: Tetrahedron. 2002 ; Vol. 58, N.º 22. pp. 4417-4423.
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Quantitative characterization of the global electrophilicity power of common diene/dienophile pairs in Diels-Alder reactions. / Domingo, Luis R.; Aurell, M. José; Pérez, Patricia; Contreras, Renato.

En: Tetrahedron, Vol. 58, N.º 22, 27.05.2002, p. 4417-4423.

Resultado de la investigación: Article

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AU - Pérez, Patricia

AU - Contreras, Renato

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