Protonated diamines as linkers in the supramolecular assemblies based on the [V12B18O60H6] polyoxovanadoborate anion

P. Hermosilla-Ibáñez, J. Costamagna, A. Vega, V. Paredes-García, M. T. Garland, E. Le Fur, E. Spodine, D. Venegas-Yazigi

Resultado de la investigación: Article

3 Citas (Scopus)

Resumen

Two new polyoxovanadoborates based crystalline lattices are being reported: K5(H3O)2(1,3-diapH2)2[V12B18O60H6]·10.80H2O (1), and K2(H3O)7(enH2)[V12B18O60H6]·9H2O (2). These structures are characterized by presenting multiple hydrogen bonds between the diprotonated diamines (enH2 and 1,3-diapH2) and hydronium ions, and the oxygen atoms of the [V12B18O60H6] cluster. The crystalline packing and stability of these new polyoxovanadoborates is dominated by the different types of hydrogen interactions present in the lattices ranging from unidirectional to trifurcated ones. The crystallographic data, together with the BVS method, permit to assign a mixed valence ratios for the [V12B18O60H6] anionic cluster for (1) and (2) being 11/1 (VIV/VV) ratio.

Idioma originalEnglish
Páginas (desde-hasta)1453-1465
Número de páginas13
PublicaciónJournal of Structural Chemistry
Volumen55
N.º8
DOI
EstadoPublished - 1 ene 2014

Huella dactilar

Diamines
diamines
assemblies
Anions
Negative ions
hydronium ions
Crystalline materials
anions
Crystal lattices
Hydrogen
oxygen atoms
Hydrogen bonds
hydrogen bonds
Oxygen
valence
Atoms
Ions
hydrogen
interactions
hydronium ion

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

Citar esto

Hermosilla-Ibáñez, P. ; Costamagna, J. ; Vega, A. ; Paredes-García, V. ; Garland, M. T. ; Le Fur, E. ; Spodine, E. ; Venegas-Yazigi, D. / Protonated diamines as linkers in the supramolecular assemblies based on the [V12B18O60H6] polyoxovanadoborate anion. En: Journal of Structural Chemistry. 2014 ; Vol. 55, N.º 8. pp. 1453-1465.
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abstract = "Two new polyoxovanadoborates based crystalline lattices are being reported: K5(H3O)2(1,3-diapH2)2[V12B18O60H6]·10.80H2O (1), and K2(H3O)7(enH2)[V12B18O60H6]·9H2O (2). These structures are characterized by presenting multiple hydrogen bonds between the diprotonated diamines (enH2 and 1,3-diapH2) and hydronium ions, and the oxygen atoms of the [V12B18O60H6] cluster. The crystalline packing and stability of these new polyoxovanadoborates is dominated by the different types of hydrogen interactions present in the lattices ranging from unidirectional to trifurcated ones. The crystallographic data, together with the BVS method, permit to assign a mixed valence ratios for the [V12B18O60H6] anionic cluster for (1) and (2) being 11/1 (VIV/VV) ratio.",
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Protonated diamines as linkers in the supramolecular assemblies based on the [V12B18O60H6] polyoxovanadoborate anion. / Hermosilla-Ibáñez, P.; Costamagna, J.; Vega, A.; Paredes-García, V.; Garland, M. T.; Le Fur, E.; Spodine, E.; Venegas-Yazigi, D.

En: Journal of Structural Chemistry, Vol. 55, N.º 8, 01.01.2014, p. 1453-1465.

Resultado de la investigación: Article

TY - JOUR

T1 - Protonated diamines as linkers in the supramolecular assemblies based on the [V12B18O60H6] polyoxovanadoborate anion

AU - Hermosilla-Ibáñez, P.

AU - Costamagna, J.

AU - Vega, A.

AU - Paredes-García, V.

AU - Garland, M. T.

AU - Le Fur, E.

AU - Spodine, E.

AU - Venegas-Yazigi, D.

PY - 2014/1/1

Y1 - 2014/1/1

N2 - Two new polyoxovanadoborates based crystalline lattices are being reported: K5(H3O)2(1,3-diapH2)2[V12B18O60H6]·10.80H2O (1), and K2(H3O)7(enH2)[V12B18O60H6]·9H2O (2). These structures are characterized by presenting multiple hydrogen bonds between the diprotonated diamines (enH2 and 1,3-diapH2) and hydronium ions, and the oxygen atoms of the [V12B18O60H6] cluster. The crystalline packing and stability of these new polyoxovanadoborates is dominated by the different types of hydrogen interactions present in the lattices ranging from unidirectional to trifurcated ones. The crystallographic data, together with the BVS method, permit to assign a mixed valence ratios for the [V12B18O60H6] anionic cluster for (1) and (2) being 11/1 (VIV/VV) ratio.

AB - Two new polyoxovanadoborates based crystalline lattices are being reported: K5(H3O)2(1,3-diapH2)2[V12B18O60H6]·10.80H2O (1), and K2(H3O)7(enH2)[V12B18O60H6]·9H2O (2). These structures are characterized by presenting multiple hydrogen bonds between the diprotonated diamines (enH2 and 1,3-diapH2) and hydronium ions, and the oxygen atoms of the [V12B18O60H6] cluster. The crystalline packing and stability of these new polyoxovanadoborates is dominated by the different types of hydrogen interactions present in the lattices ranging from unidirectional to trifurcated ones. The crystallographic data, together with the BVS method, permit to assign a mixed valence ratios for the [V12B18O60H6] anionic cluster for (1) and (2) being 11/1 (VIV/VV) ratio.

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KW - polyoxometalate

KW - polyoxovanadate

KW - supramolecular

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