Planar tetracoordinate carbons in cyclic semisaturated hydrocarbons

Nancy Perez-Peralta, Mario Sanchez, Jesus Martin-Polo, Rafael Islas, Alberto Vela, Gabriel Merino

Resultado de la investigación: Article

27 Citas (Scopus)

Resumen

(Figure Presented) A series of planar tetracoordinate carbon molecules in cyclic semisaturated hydrocarbons resulting from the combination of the C 5 2- skeleton with saturated hydrocarbon fragments is reported. The electronic stabilization and the bonding situation are studied through the analyses of molecular orbitals and the electron localization function. The magnetic properties are also revised, giving particular attention to the induced magnetic field. These systems are the first semisaturated cycles containing a planar tetracoordinate carbon stabilized only by electronic factors.

Idioma originalEnglish
Páginas (desde-hasta)7037-7044
Número de páginas8
PublicaciónJournal of Organic Chemistry
Volumen73
N.º18
DOI
EstadoPublished - 19 sep 2008

Huella dactilar

Cyclic Hydrocarbons
Carbon
Molecular orbitals
Hydrocarbons
Magnetic properties
Stabilization
Magnetic fields
Molecules
Electrons

ASJC Scopus subject areas

  • Organic Chemistry

Citar esto

Perez-Peralta, N., Sanchez, M., Martin-Polo, J., Islas, R., Vela, A., & Merino, G. (2008). Planar tetracoordinate carbons in cyclic semisaturated hydrocarbons. Journal of Organic Chemistry, 73(18), 7037-7044. https://doi.org/10.1021/jo800885x
Perez-Peralta, Nancy ; Sanchez, Mario ; Martin-Polo, Jesus ; Islas, Rafael ; Vela, Alberto ; Merino, Gabriel. / Planar tetracoordinate carbons in cyclic semisaturated hydrocarbons. En: Journal of Organic Chemistry. 2008 ; Vol. 73, N.º 18. pp. 7037-7044.
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Perez-Peralta, N, Sanchez, M, Martin-Polo, J, Islas, R, Vela, A & Merino, G 2008, 'Planar tetracoordinate carbons in cyclic semisaturated hydrocarbons', Journal of Organic Chemistry, vol. 73, n.º 18, pp. 7037-7044. https://doi.org/10.1021/jo800885x

Planar tetracoordinate carbons in cyclic semisaturated hydrocarbons. / Perez-Peralta, Nancy; Sanchez, Mario; Martin-Polo, Jesus; Islas, Rafael; Vela, Alberto; Merino, Gabriel.

En: Journal of Organic Chemistry, Vol. 73, N.º 18, 19.09.2008, p. 7037-7044.

Resultado de la investigación: Article

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T1 - Planar tetracoordinate carbons in cyclic semisaturated hydrocarbons

AU - Perez-Peralta, Nancy

AU - Sanchez, Mario

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AU - Islas, Rafael

AU - Vela, Alberto

AU - Merino, Gabriel

PY - 2008/9/19

Y1 - 2008/9/19

N2 - (Figure Presented) A series of planar tetracoordinate carbon molecules in cyclic semisaturated hydrocarbons resulting from the combination of the C 5 2- skeleton with saturated hydrocarbon fragments is reported. The electronic stabilization and the bonding situation are studied through the analyses of molecular orbitals and the electron localization function. The magnetic properties are also revised, giving particular attention to the induced magnetic field. These systems are the first semisaturated cycles containing a planar tetracoordinate carbon stabilized only by electronic factors.

AB - (Figure Presented) A series of planar tetracoordinate carbon molecules in cyclic semisaturated hydrocarbons resulting from the combination of the C 5 2- skeleton with saturated hydrocarbon fragments is reported. The electronic stabilization and the bonding situation are studied through the analyses of molecular orbitals and the electron localization function. The magnetic properties are also revised, giving particular attention to the induced magnetic field. These systems are the first semisaturated cycles containing a planar tetracoordinate carbon stabilized only by electronic factors.

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Perez-Peralta N, Sanchez M, Martin-Polo J, Islas R, Vela A, Merino G. Planar tetracoordinate carbons in cyclic semisaturated hydrocarbons. Journal of Organic Chemistry. 2008 sep 19;73(18):7037-7044. https://doi.org/10.1021/jo800885x