Oxidative perhydroxylation of [closo-B12H12\ 2 to the stable inorganic cluster redox system [B12(OH) 12]2-/.-: Experiment and theory

Nguyen Van, Ioannis Tiritiris, Rainer F. Winter, Biprajit Sarkar, Priti Singh, Carole Duboc, Alvaro Muñoz-Castro, Ramiro Arratia-Pérez, Wolfgang Kaim, Thomas Schleid

Resultado de la investigación: Article

28 Citas (Scopus)

Resumen

It's radical: A surprisingly simple reaction converts the normally inert prototypical hydridoborate cluster [closo-B12H12] 2? not only to [closo-B12 (OH) 12] 2?but also at less-elevated temperatures to the new [hypocloso-B 12 (OH) 12].? radical anion (see figure). Both approximately icosahedral closo and hypocloso cluster ions were structurally characterized as the cesium salts and their properties were assessed experimentally and theoretically.

Idioma originalEnglish
Páginas (desde-hasta)11242-11245
Número de páginas4
PublicaciónChemistry - A European Journal
Volumen16
N.º37
DOI
EstadoPublished - 4 oct 2010

Huella dactilar

Cesium
Anions
Negative ions
Salts
Ions
Experiments
Temperature
Oxidation-Reduction

ASJC Scopus subject areas

  • Chemistry(all)

Citar esto

Van, Nguyen ; Tiritiris, Ioannis ; Winter, Rainer F. ; Sarkar, Biprajit ; Singh, Priti ; Duboc, Carole ; Muñoz-Castro, Alvaro ; Arratia-Pérez, Ramiro ; Kaim, Wolfgang ; Schleid, Thomas. / Oxidative perhydroxylation of [closo-B12H12\ 2 to the stable inorganic cluster redox system [B12(OH) 12]2-/.- : Experiment and theory. En: Chemistry - A European Journal. 2010 ; Vol. 16, N.º 37. pp. 11242-11245.
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abstract = "It's radical: A surprisingly simple reaction converts the normally inert prototypical hydridoborate cluster [closo-B12H12] 2? not only to [closo-B12 (OH) 12] 2?but also at less-elevated temperatures to the new [hypocloso-B 12 (OH) 12].? radical anion (see figure). Both approximately icosahedral closo and hypocloso cluster ions were structurally characterized as the cesium salts and their properties were assessed experimentally and theoretically.",
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Van, N, Tiritiris, I, Winter, RF, Sarkar, B, Singh, P, Duboc, C, Muñoz-Castro, A, Arratia-Pérez, R, Kaim, W & Schleid, T 2010, 'Oxidative perhydroxylation of [closo-B12H12\ 2 to the stable inorganic cluster redox system [B12(OH) 12]2-/.-: Experiment and theory', Chemistry - A European Journal, vol. 16, n.º 37, pp. 11242-11245. https://doi.org/10.1002/chem.201001374

Oxidative perhydroxylation of [closo-B12H12\ 2 to the stable inorganic cluster redox system [B12(OH) 12]2-/.- : Experiment and theory. / Van, Nguyen; Tiritiris, Ioannis; Winter, Rainer F.; Sarkar, Biprajit; Singh, Priti; Duboc, Carole; Muñoz-Castro, Alvaro; Arratia-Pérez, Ramiro; Kaim, Wolfgang; Schleid, Thomas.

En: Chemistry - A European Journal, Vol. 16, N.º 37, 04.10.2010, p. 11242-11245.

Resultado de la investigación: Article

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T2 - Experiment and theory

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AU - Winter, Rainer F.

AU - Sarkar, Biprajit

AU - Singh, Priti

AU - Duboc, Carole

AU - Muñoz-Castro, Alvaro

AU - Arratia-Pérez, Ramiro

AU - Kaim, Wolfgang

AU - Schleid, Thomas

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KW - Borates

KW - Cage compounds

KW - Closomers

KW - Electron-deficient compounds

KW - Hydroxylation

KW - Radicals

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