Oxidative perhydroxylation of [closo-B12H12\ 2 to the stable inorganic cluster redox system [B12(OH) 12]2-/.-: Experiment and theory

Nguyen Van, Ioannis Tiritiris, Rainer F. Winter, Biprajit Sarkar, Priti Singh, Carole Duboc, Alvaro Muñoz-Castro, Ramiro Arratia-Pérez, Wolfgang Kaim, Thomas Schleid

Producción científica: Contribución a una revistaArtículorevisión exhaustiva

36 Citas (Scopus)

Resumen

It's radical: A surprisingly simple reaction converts the normally inert prototypical hydridoborate cluster [closo-B12H12] 2? not only to [closo-B12 (OH) 12] 2?but also at less-elevated temperatures to the new [hypocloso-B 12 (OH) 12].? radical anion (see figure). Both approximately icosahedral closo and hypocloso cluster ions were structurally characterized as the cesium salts and their properties were assessed experimentally and theoretically.

Idioma originalInglés
Páginas (desde-hasta)11242-11245
Número de páginas4
PublicaciónChemistry - A European Journal
Volumen16
N.º37
DOI
EstadoPublicada - 4 oct. 2010

Áreas temáticas de ASJC Scopus

  • Catálisis
  • Química orgánica

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