Nucleophilicity scale for n- and π-nucleophiles

Paula Jaramillo, Patricio Fuentealba, Patricia Pérez

Resultado de la investigación: Article

32 Citas (Scopus)

Resumen

A recently introduced empirical nucleophilicity index for a series of n- and π-nucleophiles was evaluated. The index is based on the frontier molecular orbital information of the nucleophile and its electrophilic partner. The model is validated against kinetic data of alkenes, phosphanes, phosphites and amines interacting with the corresponding electrophilic partner. The predictive character of this index is tested for some nucleophiles.

Idioma originalEnglish
Páginas (desde-hasta)421-425
Número de páginas5
PublicaciónChemical Physics Letters
Volumen427
N.º4-6
DOI
EstadoPublished - 31 ago 2006

Huella dactilar

Nucleophiles
nucleophiles
phosphine
Phosphites
Alkenes
Molecular orbitals
alkenes
Amines
molecular orbitals
amines
Kinetics
kinetics

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

Citar esto

Jaramillo, Paula ; Fuentealba, Patricio ; Pérez, Patricia. / Nucleophilicity scale for n- and π-nucleophiles. En: Chemical Physics Letters. 2006 ; Vol. 427, N.º 4-6. pp. 421-425.
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Nucleophilicity scale for n- and π-nucleophiles. / Jaramillo, Paula; Fuentealba, Patricio; Pérez, Patricia.

En: Chemical Physics Letters, Vol. 427, N.º 4-6, 31.08.2006, p. 421-425.

Resultado de la investigación: Article

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AU - Fuentealba, Patricio

AU - Pérez, Patricia

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