TY - JOUR
T1 - Nonacarbonyl-μ2-hydrido-μ 2-(N-methylcarboxamido)-C:O-(N-trimethylamine)triosmium(3 Os - Os)
AU - Vega, Andrés
AU - Spodine, Evgenia
AU - Arce, Alejandro
AU - Manzur, Jorge
AU - García, Ana María
AU - Garland, María Teresa
N1 - Copyright:
Copyright 2018 Elsevier B.V., All rights reserved.
PY - 1999/3/15
Y1 - 1999/3/15
N2 - In the title compound, nonacarbonyl-1κ2C,2κ3C,3κ 4C-μ-hydrido-1:2κ 2H-μ-(N-methylcarboxamido)-1:2κ 2O:C-(N-trimethylamine-1κN)triosmium(3 Os-Os), [Os3H-(C2H4NO)(C3H 9N)(CO)9], the MeHNCO ligand forms a μ2-C:O bridge between two metal centers, which are also linked by a μ-hydride ligand. These two groups are at opposite sides of the plane defined by the Os atoms. Bond lengths between Os atoms are 2.8149 (8), 2.8777 (8) and 2.9278 (8) Å. The structure shows two metal centers which are heptacoordinated and one which is hexacoordinated.
AB - In the title compound, nonacarbonyl-1κ2C,2κ3C,3κ 4C-μ-hydrido-1:2κ 2H-μ-(N-methylcarboxamido)-1:2κ 2O:C-(N-trimethylamine-1κN)triosmium(3 Os-Os), [Os3H-(C2H4NO)(C3H 9N)(CO)9], the MeHNCO ligand forms a μ2-C:O bridge between two metal centers, which are also linked by a μ-hydride ligand. These two groups are at opposite sides of the plane defined by the Os atoms. Bond lengths between Os atoms are 2.8149 (8), 2.8777 (8) and 2.9278 (8) Å. The structure shows two metal centers which are heptacoordinated and one which is hexacoordinated.
UR - http://www.scopus.com/inward/record.url?scp=0008700686&partnerID=8YFLogxK
U2 - 10.1107/S0108270198012839
DO - 10.1107/S0108270198012839
M3 - Article
AN - SCOPUS:0008700686
VL - 55
SP - 322
EP - 323
JO - Acta Crystallographica Section C: Crystal Structure Communications
JF - Acta Crystallographica Section C: Crystal Structure Communications
SN - 0108-2701
IS - 3
ER -