Nonacarbonyl-μ2-hydrido-μ 2-(N-methylcarboxamido)-C:O-(N-trimethylamine)triosmium(3 Os - Os)

Andrés Vega; Evgenia Spodine; Alejandro Arce; Jorge Manzur; Ana María García; María Teresa Garland

doi:10.1107/S0108270198012839

Nonacarbonyl-μ₂-hydrido-μ ₂-(N-methylcarboxamido)-C:O-(N-trimethylamine)triosmium(3 Os - Os)

Andrés Vega, Evgenia Spodine, Alejandro Arce, Jorge Manzur, Ana María García, María Teresa Garland

Facultad Ciencias Exactas

Resultado de la investigación: Contribución a una revista › Artículo › revisión exhaustiva

4 Citas (Scopus)

Resumen

In the title compound, nonacarbonyl-1κ²C,2κ³C,3κ ⁴C-μ-hydrido-1:2κ ²H-μ-(N-methylcarboxamido)-1:2κ ²O:C-(N-trimethylamine-1κN)triosmium(3 Os-Os), [Os₃H-(C₂H₄NO)(C₃H ₉N)(CO)₉], the MeHNCO ligand forms a μ₂-C:O bridge between two metal centers, which are also linked by a μ-hydride ligand. These two groups are at opposite sides of the plane defined by the Os atoms. Bond lengths between Os atoms are 2.8149 (8), 2.8777 (8) and 2.9278 (8) Å. The structure shows two metal centers which are heptacoordinated and one which is hexacoordinated.

Idioma original	Inglés
Páginas (desde-hasta)	322-323
Número de páginas	2
Publicación	Acta Crystallographica Section C: Crystal Structure Communications
Volumen	55
N.º	3
DOI	https://doi.org/10.1107/S0108270198012839
Estado	Publicada - 15 mar 1999

Áreas temáticas de ASJC Scopus

Bioquímica, genética y biología molecular (todo)

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10.1107/S0108270198012839

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@article{6fded13053a14184a5f49ecfae03e603,

title = "Nonacarbonyl-μ2-hydrido-μ 2-(N-methylcarboxamido)-C:O-(N-trimethylamine)triosmium(3 Os - Os)",

abstract = "In the title compound, nonacarbonyl-1κ2C,2κ3C,3κ 4C-μ-hydrido-1:2κ 2H-μ-(N-methylcarboxamido)-1:2κ 2O:C-(N-trimethylamine-1κN)triosmium(3 Os-Os), [Os3H-(C2H4NO)(C3H 9N)(CO)9], the MeHNCO ligand forms a μ2-C:O bridge between two metal centers, which are also linked by a μ-hydride ligand. These two groups are at opposite sides of the plane defined by the Os atoms. Bond lengths between Os atoms are 2.8149 (8), 2.8777 (8) and 2.9278 (8) {\AA}. The structure shows two metal centers which are heptacoordinated and one which is hexacoordinated.",

author = "Andr{\'e}s Vega and Evgenia Spodine and Alejandro Arce and Jorge Manzur and Garc{\'i}a, {Ana Mar{\'i}a} and Garland, {Mar{\'i}a Teresa}",

year = "1999",

month = mar,

day = "15",

doi = "10.1107/S0108270198012839",

language = "English",

volume = "55",

pages = "322--323",

journal = "Acta Crystallographica Section C: Crystal Structure Communications",

issn = "0108-2701",

publisher = "International Union of Crystallography",

number = "3",

}

Nonacarbonyl-μ₂-hydrido-μ ₂-(N-methylcarboxamido)-C:O-(N-trimethylamine)triosmium(3 Os - Os). / Vega, Andrés; Spodine, Evgenia; Arce, Alejandro; Manzur, Jorge; García, Ana María; Garland, María Teresa.

En: Acta Crystallographica Section C: Crystal Structure Communications, Vol. 55, N.º 3, 15.03.1999, p. 322-323.

Resultado de la investigación: Contribución a una revista › Artículo › revisión exhaustiva

TY - JOUR

T1 - Nonacarbonyl-μ2-hydrido-μ 2-(N-methylcarboxamido)-C:O-(N-trimethylamine)triosmium(3 Os - Os)

AU - Vega, Andrés

AU - Spodine, Evgenia

AU - Arce, Alejandro

AU - Manzur, Jorge

AU - García, Ana María

AU - Garland, María Teresa

PY - 1999/3/15

Y1 - 1999/3/15

N2 - In the title compound, nonacarbonyl-1κ2C,2κ3C,3κ 4C-μ-hydrido-1:2κ 2H-μ-(N-methylcarboxamido)-1:2κ 2O:C-(N-trimethylamine-1κN)triosmium(3 Os-Os), [Os3H-(C2H4NO)(C3H 9N)(CO)9], the MeHNCO ligand forms a μ2-C:O bridge between two metal centers, which are also linked by a μ-hydride ligand. These two groups are at opposite sides of the plane defined by the Os atoms. Bond lengths between Os atoms are 2.8149 (8), 2.8777 (8) and 2.9278 (8) Å. The structure shows two metal centers which are heptacoordinated and one which is hexacoordinated.

AB - In the title compound, nonacarbonyl-1κ2C,2κ3C,3κ 4C-μ-hydrido-1:2κ 2H-μ-(N-methylcarboxamido)-1:2κ 2O:C-(N-trimethylamine-1κN)triosmium(3 Os-Os), [Os3H-(C2H4NO)(C3H 9N)(CO)9], the MeHNCO ligand forms a μ2-C:O bridge between two metal centers, which are also linked by a μ-hydride ligand. These two groups are at opposite sides of the plane defined by the Os atoms. Bond lengths between Os atoms are 2.8149 (8), 2.8777 (8) and 2.9278 (8) Å. The structure shows two metal centers which are heptacoordinated and one which is hexacoordinated.

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JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

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