Ni2[LnCl6] (Ln = EuII, CeII, GdII): The first LnII compounds stabilized in a pure inorganic lattice

Bianca Baldo; Francisco Rubio; Erwin Flores; Andres Vega; Nathalie Audebrand; Diego Venegas-Yazigi; Verónica Paredes-García

doi:10.1039/c7cc09921e

Ni₂[LnCl₆] (Ln = Eu^II, Ce^II, Gd^II): The first Ln^II compounds stabilized in a pure inorganic lattice

Bianca Baldo, Francisco Rubio, Erwin Flores, Andres Vega, Nathalie Audebrand, Diego Venegas-Yazigi, Verónica Paredes-García

Facultad Ciencias Exactas

Producción científica: Contribución a una revista › Artículo › revisión exhaustiva

5 Citas (Scopus)

Resumen

Here we report the first examples of 3d-4f compounds based on Ln^II cations. We have obtained a series of Ni₂[LnCl₆] isostructural compounds where Ln^II = Ce 1, Eu 2 and Gd 3 which were characterized in a cubic crystalline system with a Fm3m space group. Magnetic and optical characterization was also performed on this new class of compounds.

Idioma original	Inglés
Páginas (desde-hasta)	7531-7534
Número de páginas	4
Publicación	Chemical Communications
Volumen	54
N.º	54
DOI	https://doi.org/10.1039/c7cc09921e
Estado	Publicada - 1 ene. 2018

Áreas temáticas de ASJC Scopus

Catálisis
Materiales electrónicos, ópticos y magnéticos
Cerámicos y compuestos
Química General
Superficies, recubrimientos y láminas
Metales y aleaciones
Química de los materiales

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10.1039/c7cc09921e

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title = "Ni2[LnCl6] (Ln = EuII, CeII, GdII): The first LnII compounds stabilized in a pure inorganic lattice",

abstract = "Here we report the first examples of 3d-4f compounds based on LnII cations. We have obtained a series of Ni2[LnCl6] isostructural compounds where LnII = Ce 1, Eu 2 and Gd 3 which were characterized in a cubic crystalline system with a Fm3m space group. Magnetic and optical characterization was also performed on this new class of compounds.",

author = "Bianca Baldo and Francisco Rubio and Erwin Flores and Andres Vega and Nathalie Audebrand and Diego Venegas-Yazigi and Ver{\'o}nica Paredes-Garc{\'i}a",

note = "Funding Information: The authors acknowledge FONDECYT 1170887, Proyecto Anillo CONICYT ACT 1404 grant, CONICYT-FONDEQUIP/PPMS/ EQM130086, Chilean-French International Associated Laboratory for Multifunctional Molecules and Materials-LIAM3-CNRS No. 1027 and ECOS/CONICYT C15E02. The authors acknowledge CEDENNA, Financiamiento Basal, FB0807. The authors also acknowledge the support from the Laboratory of Analyses of Solids (L.A.S-UNAB). B. B. thanks CONICYT scholarship No. 21140908.",

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T2 - The first LnII compounds stabilized in a pure inorganic lattice

AU - Baldo, Bianca

AU - Rubio, Francisco

AU - Flores, Erwin

AU - Vega, Andres

AU - Audebrand, Nathalie

AU - Venegas-Yazigi, Diego

AU - Paredes-García, Verónica

N1 - Funding Information: The authors acknowledge FONDECYT 1170887, Proyecto Anillo CONICYT ACT 1404 grant, CONICYT-FONDEQUIP/PPMS/ EQM130086, Chilean-French International Associated Laboratory for Multifunctional Molecules and Materials-LIAM3-CNRS No. 1027 and ECOS/CONICYT C15E02. The authors acknowledge CEDENNA, Financiamiento Basal, FB0807. The authors also acknowledge the support from the Laboratory of Analyses of Solids (L.A.S-UNAB). B. B. thanks CONICYT scholarship No. 21140908.

PY - 2018/1/1

Y1 - 2018/1/1

N2 - Here we report the first examples of 3d-4f compounds based on LnII cations. We have obtained a series of Ni2[LnCl6] isostructural compounds where LnII = Ce 1, Eu 2 and Gd 3 which were characterized in a cubic crystalline system with a Fm3m space group. Magnetic and optical characterization was also performed on this new class of compounds.

AB - Here we report the first examples of 3d-4f compounds based on LnII cations. We have obtained a series of Ni2[LnCl6] isostructural compounds where LnII = Ce 1, Eu 2 and Gd 3 which were characterized in a cubic crystalline system with a Fm3m space group. Magnetic and optical characterization was also performed on this new class of compounds.

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