Molecular and Crystalline Structure of the Ruthenium(II) Complex [{trans-(dppe)2(Cl) Ru–C≡C–H} · 0.5CDCl3]: An Additional Determination

C. A. Escobar, F. Madrid-Moliné, M. Fuentealba, J. C. Santos, P. Jara-Ulloa, A. Trujillo

Resultado de la investigación: Article

Resumen

Abstract: The synthesis and X-ray diffraction study of the ruthenium(II) complex, [{trans-(dppe)2(Cl) Ru–C≡C–H} · 0.5CDCl3] (trans-Ru · 0.5CDCl3), are presented. The molecule of trans-Ru · 0.5CDCl3 crystallizes in the triclinic sp. gr. P\1 with two chemically equivalent but crystallographic independent molecules. The intramolecular C–H···Cl–C hydrogen bonds build with the deuterated chloroform. In addition, the intermolecular C–H···Cl–Ru hydrogen bonds have been also found.

Idioma originalEnglish
Páginas (desde-hasta)1133-1137
Número de páginas5
PublicaciónCrystallography Reports
Volumen63
N.º7
DOI
EstadoPublished - 1 dic 2018

Huella dactilar

Ruthenium
ruthenium
Hydrogen bonds
molecular structure
hydrogen bonds
Crystalline materials
Molecules
Chloroform
Chlorine compounds
chloroform
molecules
X ray diffraction
synthesis
diffraction
x rays
dichlorotetrakis(dimethyl sulfoxide)ruthenium II

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

Citar esto

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title = "Molecular and Crystalline Structure of the Ruthenium(II) Complex [{trans-(dppe)2(Cl) Ru–C≡C–H} · 0.5CDCl3]: An Additional Determination",
abstract = "Abstract: The synthesis and X-ray diffraction study of the ruthenium(II) complex, [{trans-(dppe)2(Cl) Ru–C≡C–H} · 0.5CDCl3] (trans-Ru · 0.5CDCl3), are presented. The molecule of trans-Ru · 0.5CDCl3 crystallizes in the triclinic sp. gr. P\1 with two chemically equivalent but crystallographic independent molecules. The intramolecular C–H···Cl–C hydrogen bonds build with the deuterated chloroform. In addition, the intermolecular C–H···Cl–Ru hydrogen bonds have been also found.",
author = "Escobar, {C. A.} and F. Madrid-Molin{\'e} and M. Fuentealba and Santos, {J. C.} and P. Jara-Ulloa and A. Trujillo",
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TY - JOUR

T1 - Molecular and Crystalline Structure of the Ruthenium(II) Complex [{trans-(dppe)2(Cl) Ru–C≡C–H} · 0.5CDCl3]

T2 - An Additional Determination

AU - Escobar, C. A.

AU - Madrid-Moliné, F.

AU - Fuentealba, M.

AU - Santos, J. C.

AU - Jara-Ulloa, P.

AU - Trujillo, A.

PY - 2018/12/1

Y1 - 2018/12/1

N2 - Abstract: The synthesis and X-ray diffraction study of the ruthenium(II) complex, [{trans-(dppe)2(Cl) Ru–C≡C–H} · 0.5CDCl3] (trans-Ru · 0.5CDCl3), are presented. The molecule of trans-Ru · 0.5CDCl3 crystallizes in the triclinic sp. gr. P\1 with two chemically equivalent but crystallographic independent molecules. The intramolecular C–H···Cl–C hydrogen bonds build with the deuterated chloroform. In addition, the intermolecular C–H···Cl–Ru hydrogen bonds have been also found.

AB - Abstract: The synthesis and X-ray diffraction study of the ruthenium(II) complex, [{trans-(dppe)2(Cl) Ru–C≡C–H} · 0.5CDCl3] (trans-Ru · 0.5CDCl3), are presented. The molecule of trans-Ru · 0.5CDCl3 crystallizes in the triclinic sp. gr. P\1 with two chemically equivalent but crystallographic independent molecules. The intramolecular C–H···Cl–C hydrogen bonds build with the deuterated chloroform. In addition, the intermolecular C–H···Cl–Ru hydrogen bonds have been also found.

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DO - 10.1134/S106377451807009X

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JO - Crystallography Reports

JF - Crystallography Reports

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