Metabolomic Analysis of the Lichen Everniopsis trulla Using Ultra High Performance Liquid Chromatography-Quadrupole-Orbitrap Mass Spectrometry (UHPLC-Q-OT-MS)

Olivio N. Castro, Julio Benites, Jesus Rodilla, Julio C. Santiago, Mario Simirgiotis, Beatriz Sepulveda, Carlos Areche

Resultado de la investigación: Article

8 Citas (Scopus)

Resumen

A new depside was identified in the methanolic extract from the lichen Everniopsis trulla based on the metabolomics UHPLC–DAD–MS analysis and HESI–MS–MS fragmentation patterns along with thirty-two known compounds for the first time. The compounds were structurally characterized by UV and high resolution quadrupole orbitrap mass spectra and by comparison with literature. According to the characteristic fragmentation patterns, the presence of two simple aromatic compounds, six lipid derivatives, eight depsidones, thirteen depsides, a chromone, two diphenylethers, and a dibenzofuran were identified. To our knowledge, this is the first study of the lichen E. trulla by liquid chromatography hyphenated with tandem mass spectrometry.

Idioma originalEnglish
Páginas (desde-hasta)967-973
Número de páginas7
PublicaciónChromatographia
Volumen80
N.º6
DOI
EstadoPublished - 1 jun 2017
Publicado de forma externa

Huella dactilar

Depsides
Lichens
Metabolomics
High performance liquid chromatography
Mass spectrometry
Mass Spectrometry
High Pressure Liquid Chromatography
Chromones
Aromatic compounds
Liquid chromatography
Tandem Mass Spectrometry
Liquid Chromatography
Derivatives
Lipids

ASJC Scopus subject areas

  • Analytical Chemistry
  • Biochemistry
  • Clinical Biochemistry
  • Organic Chemistry

Citar esto

Castro, Olivio N. ; Benites, Julio ; Rodilla, Jesus ; Santiago, Julio C. ; Simirgiotis, Mario ; Sepulveda, Beatriz ; Areche, Carlos. / Metabolomic Analysis of the Lichen Everniopsis trulla Using Ultra High Performance Liquid Chromatography-Quadrupole-Orbitrap Mass Spectrometry (UHPLC-Q-OT-MS). En: Chromatographia. 2017 ; Vol. 80, N.º 6. pp. 967-973.
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abstract = "A new depside was identified in the methanolic extract from the lichen Everniopsis trulla based on the metabolomics UHPLC–DAD–MS analysis and HESI–MS–MS fragmentation patterns along with thirty-two known compounds for the first time. The compounds were structurally characterized by UV and high resolution quadrupole orbitrap mass spectra and by comparison with literature. According to the characteristic fragmentation patterns, the presence of two simple aromatic compounds, six lipid derivatives, eight depsidones, thirteen depsides, a chromone, two diphenylethers, and a dibenzofuran were identified. To our knowledge, this is the first study of the lichen E. trulla by liquid chromatography hyphenated with tandem mass spectrometry.",
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Metabolomic Analysis of the Lichen Everniopsis trulla Using Ultra High Performance Liquid Chromatography-Quadrupole-Orbitrap Mass Spectrometry (UHPLC-Q-OT-MS). / Castro, Olivio N.; Benites, Julio; Rodilla, Jesus; Santiago, Julio C.; Simirgiotis, Mario; Sepulveda, Beatriz; Areche, Carlos.

En: Chromatographia, Vol. 80, N.º 6, 01.06.2017, p. 967-973.

Resultado de la investigación: Article

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AU - Castro, Olivio N.

AU - Benites, Julio

AU - Rodilla, Jesus

AU - Santiago, Julio C.

AU - Simirgiotis, Mario

AU - Sepulveda, Beatriz

AU - Areche, Carlos

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AB - A new depside was identified in the methanolic extract from the lichen Everniopsis trulla based on the metabolomics UHPLC–DAD–MS analysis and HESI–MS–MS fragmentation patterns along with thirty-two known compounds for the first time. The compounds were structurally characterized by UV and high resolution quadrupole orbitrap mass spectra and by comparison with literature. According to the characteristic fragmentation patterns, the presence of two simple aromatic compounds, six lipid derivatives, eight depsidones, thirteen depsides, a chromone, two diphenylethers, and a dibenzofuran were identified. To our knowledge, this is the first study of the lichen E. trulla by liquid chromatography hyphenated with tandem mass spectrometry.

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