Magnetic and catalytic properties of the 2D copper(II) functionalized VPO hybrid system [{Cu(bpy)}2(VO)3(PO4) 2(HPO4)2]·2H2O

D. Venegas-Yazigi, K. Muñoz-Becerra, E. Spodine, K. Brown, C. Aliaga, V. Paredes-García, P. Aguirre, A. Vega, R. Cardoso-Gil, W. Schnelle, R. Kniep

Resultado de la investigación: Article

11 Citas (Scopus)

Resumen

The hybrid 2D compound [{Cu(bpy)}2(VO)3(PO 4)2(HPO4)2]·2H2O (1), has been investigated due to its interesting magnetic and catalytic properties. Compound (1) acts as an efficient catalyst in the epoxidation of cyclohexene and styrene. The chemoselectivity towards the epoxidation of cyclohexene is notoriously higher than the one observed towards styrene. The bulk antiferromagnetic behaviour of [{Cu(bpy)}2(VO) 3(PO4)2(HPO4)2] ·2H2O (1) can be well described with a pentanuclear model, using five J values. Both antiferromagnetic and ferromagnetic interactions mediated by phosphate bridges are found to be present in this hybrid copper(II)?vanadium(IV) material.

Idioma originalEnglish
Páginas (desde-hasta)2426-2434
Número de páginas9
PublicaciónPolyhedron
Volumen29
N.º12
DOI
EstadoPublished - 11 ago 2010

Huella dactilar

Styrene
epoxidation
Epoxidation
Hybrid systems
styrenes
Copper
magnetic properties
copper
Vanadium
vanadium
phosphates
Phosphates
catalysts
Catalysts
interactions
cyclohexene

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

Citar esto

Venegas-Yazigi, D. ; Muñoz-Becerra, K. ; Spodine, E. ; Brown, K. ; Aliaga, C. ; Paredes-García, V. ; Aguirre, P. ; Vega, A. ; Cardoso-Gil, R. ; Schnelle, W. ; Kniep, R. / Magnetic and catalytic properties of the 2D copper(II) functionalized VPO hybrid system [{Cu(bpy)}2(VO)3(PO4) 2(HPO4)2]·2H2O. En: Polyhedron. 2010 ; Vol. 29, N.º 12. pp. 2426-2434.
@article{da529cd684a7455092c5e933f774ca2c,
title = "Magnetic and catalytic properties of the 2D copper(II) functionalized VPO hybrid system [{Cu(bpy)}2(VO)3(PO4) 2(HPO4)2]·2H2O",
abstract = "The hybrid 2D compound [{Cu(bpy)}2(VO)3(PO 4)2(HPO4)2]·2H2O (1), has been investigated due to its interesting magnetic and catalytic properties. Compound (1) acts as an efficient catalyst in the epoxidation of cyclohexene and styrene. The chemoselectivity towards the epoxidation of cyclohexene is notoriously higher than the one observed towards styrene. The bulk antiferromagnetic behaviour of [{Cu(bpy)}2(VO) 3(PO4)2(HPO4)2] ·2H2O (1) can be well described with a pentanuclear model, using five J values. Both antiferromagnetic and ferromagnetic interactions mediated by phosphate bridges are found to be present in this hybrid copper(II)?vanadium(IV) material.",
keywords = "Epoxidation of olefins, Heterogeneous catalyst, Hybrid organo-inorganic, Molecular magnetism, Vanadium phosphate, VPO",
author = "D. Venegas-Yazigi and K. Mu{\~n}oz-Becerra and E. Spodine and K. Brown and C. Aliaga and V. Paredes-Garc{\'i}a and P. Aguirre and A. Vega and R. Cardoso-Gil and W. Schnelle and R. Kniep",
year = "2010",
month = "8",
day = "11",
doi = "10.1016/j.poly.2010.05.005",
language = "English",
volume = "29",
pages = "2426--2434",
journal = "Polyhedron",
issn = "0277-5387",
publisher = "Elsevier Limited",
number = "12",

}

Venegas-Yazigi, D, Muñoz-Becerra, K, Spodine, E, Brown, K, Aliaga, C, Paredes-García, V, Aguirre, P, Vega, A, Cardoso-Gil, R, Schnelle, W & Kniep, R 2010, 'Magnetic and catalytic properties of the 2D copper(II) functionalized VPO hybrid system [{Cu(bpy)}2(VO)3(PO4) 2(HPO4)2]·2H2O', Polyhedron, vol. 29, n.º 12, pp. 2426-2434. https://doi.org/10.1016/j.poly.2010.05.005

Magnetic and catalytic properties of the 2D copper(II) functionalized VPO hybrid system [{Cu(bpy)}2(VO)3(PO4) 2(HPO4)2]·2H2O. / Venegas-Yazigi, D.; Muñoz-Becerra, K.; Spodine, E.; Brown, K.; Aliaga, C.; Paredes-García, V.; Aguirre, P.; Vega, A.; Cardoso-Gil, R.; Schnelle, W.; Kniep, R.

En: Polyhedron, Vol. 29, N.º 12, 11.08.2010, p. 2426-2434.

Resultado de la investigación: Article

TY - JOUR

T1 - Magnetic and catalytic properties of the 2D copper(II) functionalized VPO hybrid system [{Cu(bpy)}2(VO)3(PO4) 2(HPO4)2]·2H2O

AU - Venegas-Yazigi, D.

AU - Muñoz-Becerra, K.

AU - Spodine, E.

AU - Brown, K.

AU - Aliaga, C.

AU - Paredes-García, V.

AU - Aguirre, P.

AU - Vega, A.

AU - Cardoso-Gil, R.

AU - Schnelle, W.

AU - Kniep, R.

PY - 2010/8/11

Y1 - 2010/8/11

N2 - The hybrid 2D compound [{Cu(bpy)}2(VO)3(PO 4)2(HPO4)2]·2H2O (1), has been investigated due to its interesting magnetic and catalytic properties. Compound (1) acts as an efficient catalyst in the epoxidation of cyclohexene and styrene. The chemoselectivity towards the epoxidation of cyclohexene is notoriously higher than the one observed towards styrene. The bulk antiferromagnetic behaviour of [{Cu(bpy)}2(VO) 3(PO4)2(HPO4)2] ·2H2O (1) can be well described with a pentanuclear model, using five J values. Both antiferromagnetic and ferromagnetic interactions mediated by phosphate bridges are found to be present in this hybrid copper(II)?vanadium(IV) material.

AB - The hybrid 2D compound [{Cu(bpy)}2(VO)3(PO 4)2(HPO4)2]·2H2O (1), has been investigated due to its interesting magnetic and catalytic properties. Compound (1) acts as an efficient catalyst in the epoxidation of cyclohexene and styrene. The chemoselectivity towards the epoxidation of cyclohexene is notoriously higher than the one observed towards styrene. The bulk antiferromagnetic behaviour of [{Cu(bpy)}2(VO) 3(PO4)2(HPO4)2] ·2H2O (1) can be well described with a pentanuclear model, using five J values. Both antiferromagnetic and ferromagnetic interactions mediated by phosphate bridges are found to be present in this hybrid copper(II)?vanadium(IV) material.

KW - Epoxidation of olefins

KW - Heterogeneous catalyst

KW - Hybrid organo-inorganic

KW - Molecular magnetism

KW - Vanadium phosphate

KW - VPO

UR - http://www.scopus.com/inward/record.url?scp=77955426829&partnerID=8YFLogxK

U2 - 10.1016/j.poly.2010.05.005

DO - 10.1016/j.poly.2010.05.005

M3 - Article

AN - SCOPUS:77955426829

VL - 29

SP - 2426

EP - 2434

JO - Polyhedron

JF - Polyhedron

SN - 0277-5387

IS - 12

ER -