Funcionalizacion del anion bis-(o-mercaptobenzoato)-cis- dioxomolibdato(VI), [MoO2(o-SC6H4COO)2]2-, con arilhidracinas p-sustituidas, R-p-C6H4NHNH2, R=H, Me, MeO, Cl, No2

Julia Li Kao; David Carrillo; Andres Vega; Maria Teresa Garland

Funcionalizacion del anion bis-(o-mercaptobenzoato)-cis- dioxomolibdato(VI), [MoO₂(o-SC₆H₄COO)₂]^2-, con arilhidracinas p-sustituidas, R-p-C₆H₄NHNH₂, R=H, Me, MeO, Cl, No₂

Julia Li Kao, David Carrillo, Andres Vega, Maria Teresa Garland

Facultad Ciencias Exactas

Resultado de la investigación: Contribución a una revista › Artículo › revisión exhaustiva

1 Cita (Scopus)

Resumen

In acetonitrile, the cis-[MoO₂]²⁺ group present in the anionic complex [MoO₂(o-SC₆H₄COO)₂]^2-, can be functionalized under mild conditions by reaction with arylhydrazines, p-R-C₆H₄NHNH₂. The resulting ionic complexes have been formulated as [Et₃NH]₂[Mo(NNC₆H₄-p-R) ₂(o-SC₆H₄COO)₂], R=H, [Et₃NH]₂[I]; Me, [Et₃NH]₂[II]; MeO, [Et₃NH]₂[III]; Cl, [Et₃NH]₂[IV]; NO₂, [Et₃NH]₂[V], characterized by spectroscopic methods and, additionally, in the case of complex [Et₃NH]₂[IV], by single crystal X-ray diffraction. The aryldiazenido ligands, occupying mutually cis positions, adopt the "singly bent" geometry.

Título traducido de la contribución	Functionalization of the bis-(o-mercaptobenzoato)-cis-dioxomolibdato(VI) anion, [MoO₂(o-SC₆H₄COO)₂]^2-, with p-substituted arylhydrazines, R-p-C₆H₄NHNH₂, R=H, Me, MeO, Cl, No₂
Idioma original	Español
Páginas (desde-hasta)	5-12
Número de páginas	8
Publicación	Boletin de la Sociedad Chilena de Quimica
Volumen	47
N.º	1
Estado	Publicada - mar. 2002

Palabras clave

Aryldiazenido
Diazenido
Molecular structure
Molybdenum complexes
Organodiazenido
o-mercaptobenzoate

Áreas temáticas de ASJC Scopus

Química (todo)

Otros archivos y enlaces

Enlace a la publicación en Scopus

Citar esto

@article{7a9737d0d8c944e7a4fe0f54c7d98b3c,

title = "Funcionalizacion del anion bis-(o-mercaptobenzoato)-cis- dioxomolibdato(VI), [MoO2(o-SC6H4COO)2]2-, con arilhidracinas p-sustituidas, R-p-C6H4NHNH2, R=H, Me, MeO, Cl, No2",

abstract = "In acetonitrile, the cis-[MoO2]2+ group present in the anionic complex [MoO2(o-SC6H4COO)2]2-, can be functionalized under mild conditions by reaction with arylhydrazines, p-R-C6H4NHNH2. The resulting ionic complexes have been formulated as [Et3NH]2[Mo(NNC6H4-p-R) 2(o-SC6H4COO)2], R=H, [Et3NH]2[I]; Me, [Et3NH]2[II]; MeO, [Et3NH]2[III]; Cl, [Et3NH]2[IV]; NO2, [Et3NH]2[V], characterized by spectroscopic methods and, additionally, in the case of complex [Et3NH]2[IV], by single crystal X-ray diffraction. The aryldiazenido ligands, occupying mutually cis positions, adopt the {"}singly bent{"} geometry.",

keywords = "Aryldiazenido, Diazenido, Molecular structure, Molybdenum complexes, Organodiazenido, o-mercaptobenzoate",

author = "{Li Kao}, Julia and David Carrillo and Andres Vega and Garland, {Maria Teresa}",

year = "2002",

month = mar,

language = "Espa{\~n}ol",

volume = "47",

pages = "5--12",

journal = "Journal of the Chilean Chemical Society",

issn = "0717-9324",

publisher = "Sociedad Chilena De Quimica",

number = "1",

}

Funcionalizacion del anion bis-(o-mercaptobenzoato)-cis- dioxomolibdato(VI), [MoO₂(o-SC₆H₄COO)₂]^2-, con arilhidracinas p-sustituidas, R-p-C₆H₄NHNH₂, R=H, Me, MeO, Cl, No₂. / Li Kao, Julia; Carrillo, David; Vega, Andres et al.

En: Boletin de la Sociedad Chilena de Quimica, Vol. 47, N.º 1, 03.2002, p. 5-12.

Resultado de la investigación: Contribución a una revista › Artículo › revisión exhaustiva

TY - JOUR

T1 - Funcionalizacion del anion bis-(o-mercaptobenzoato)-cis- dioxomolibdato(VI), [MoO2(o-SC6H4COO)2]2-, con arilhidracinas p-sustituidas, R-p-C6H4NHNH2, R=H, Me, MeO, Cl, No2

AU - Li Kao, Julia

AU - Carrillo, David

AU - Vega, Andres

AU - Garland, Maria Teresa

PY - 2002/3

Y1 - 2002/3

N2 - In acetonitrile, the cis-[MoO2]2+ group present in the anionic complex [MoO2(o-SC6H4COO)2]2-, can be functionalized under mild conditions by reaction with arylhydrazines, p-R-C6H4NHNH2. The resulting ionic complexes have been formulated as [Et3NH]2[Mo(NNC6H4-p-R) 2(o-SC6H4COO)2], R=H, [Et3NH]2[I]; Me, [Et3NH]2[II]; MeO, [Et3NH]2[III]; Cl, [Et3NH]2[IV]; NO2, [Et3NH]2[V], characterized by spectroscopic methods and, additionally, in the case of complex [Et3NH]2[IV], by single crystal X-ray diffraction. The aryldiazenido ligands, occupying mutually cis positions, adopt the "singly bent" geometry.

AB - In acetonitrile, the cis-[MoO2]2+ group present in the anionic complex [MoO2(o-SC6H4COO)2]2-, can be functionalized under mild conditions by reaction with arylhydrazines, p-R-C6H4NHNH2. The resulting ionic complexes have been formulated as [Et3NH]2[Mo(NNC6H4-p-R) 2(o-SC6H4COO)2], R=H, [Et3NH]2[I]; Me, [Et3NH]2[II]; MeO, [Et3NH]2[III]; Cl, [Et3NH]2[IV]; NO2, [Et3NH]2[V], characterized by spectroscopic methods and, additionally, in the case of complex [Et3NH]2[IV], by single crystal X-ray diffraction. The aryldiazenido ligands, occupying mutually cis positions, adopt the "singly bent" geometry.

KW - Aryldiazenido

KW - Diazenido

KW - Molecular structure

KW - Molybdenum complexes

KW - Organodiazenido

KW - o-mercaptobenzoate

UR - http://www.scopus.com/inward/record.url?scp=0036525479&partnerID=8YFLogxK

M3 - Artículo

AN - SCOPUS:0036525479

VL - 47

SP - 5

EP - 12

JO - Journal of the Chilean Chemical Society

JF - Journal of the Chilean Chemical Society

SN - 0717-9324

IS - 1

ER -