TY - JOUR
T1 - Fe-doped Al2O3 nanoplatforms as efficient and recyclable photocatalyst for the dyes remediation
AU - Lerici, Laura C.
AU - Leal Marchena, Candelaria
AU - Torres, Cecilia C.
AU - Campos, Cristian H.
AU - Pierella, Liliana B.
N1 - Publisher Copyright:
© 2021 Elsevier B.V.
PY - 2022/4/1
Y1 - 2022/4/1
N2 - γ-Al2O3 nanowires (NW) were synthetized and impregnated with different amounts of iron (2, 6 and 10 wt%). Catalysts were further characterized by powder X-ray, Fourier transform infrared spectroscopy, nitrogen adsorption–desorption isotherms, UV–visible diffuse reflectance, temperature-programmed reduction, thermogravimetric analysis, transmission electron microscopy, X-ray photoelectron spectrometry and atomic absorption. The obtained materials were evaluated as heterogeneous photocatalysts in the degradation of azo dye methyl orange as model compound employing a 125 W high-pressure mercury lamp. After 240 min under irradiation the complete decoloration and 69% of mineralization was obtained when Fe6NW was employed. When commercial γ-Al2O3 was employed as support of 6 wt%. of iron and evaluated in photodegradation the final decoloration reached up to only 46%. Reaction parameters such as iron amount, catalyst amount, pH, effect of support and reuses, were evaluated. The photocatalyst was employed for five consecutive reaction cycles with only a 10% of diminish of activity, resulting in an attractive low-cost and benefit in heterogeneous catalysis.
AB - γ-Al2O3 nanowires (NW) were synthetized and impregnated with different amounts of iron (2, 6 and 10 wt%). Catalysts were further characterized by powder X-ray, Fourier transform infrared spectroscopy, nitrogen adsorption–desorption isotherms, UV–visible diffuse reflectance, temperature-programmed reduction, thermogravimetric analysis, transmission electron microscopy, X-ray photoelectron spectrometry and atomic absorption. The obtained materials were evaluated as heterogeneous photocatalysts in the degradation of azo dye methyl orange as model compound employing a 125 W high-pressure mercury lamp. After 240 min under irradiation the complete decoloration and 69% of mineralization was obtained when Fe6NW was employed. When commercial γ-Al2O3 was employed as support of 6 wt%. of iron and evaluated in photodegradation the final decoloration reached up to only 46%. Reaction parameters such as iron amount, catalyst amount, pH, effect of support and reuses, were evaluated. The photocatalyst was employed for five consecutive reaction cycles with only a 10% of diminish of activity, resulting in an attractive low-cost and benefit in heterogeneous catalysis.
KW - Azo-dye
KW - Iron
KW - Photocatalysis
KW - γ-AlO nanowires
UR - http://www.scopus.com/inward/record.url?scp=85121797926&partnerID=8YFLogxK
U2 - 10.1016/j.jphotochem.2021.113733
DO - 10.1016/j.jphotochem.2021.113733
M3 - Article
AN - SCOPUS:85121797926
SN - 1010-6030
VL - 426
JO - Journal of Photochemistry and Photobiology A: Chemistry
JF - Journal of Photochemistry and Photobiology A: Chemistry
M1 - 113733
ER -