Resumen
The reaction of 2 equiv of C9H6-1-SiMe 3-3-CH2CH2-NC5H10 (2) with the ytterbium(III) amide [(Me3Si)2N] 3Yb-(μ-Cl)Li(THF)3 produced a novel ytterbium(II) complex with an indenyl ligand bonded to the metal via the benzo ring with η4 hapticity, (η4: η2η1-(C5H10NCH 2CH2C9H5SiMe3)Li(μ-Cl) ]Yb-(η5:η1-C5H10NCH 2CH2C9H5SiMe3) (1), as verified by a solid-state structure determination and theoretical calculations.
Idioma original | English |
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Páginas (desde-hasta) | 2399-2401 |
Número de páginas | 3 |
Publicación | Organometallics |
Volumen | 25 |
N.º | 10 |
DOI | |
Estado | Published - 8 may 2006 |
Huella dactilar
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Organic Chemistry
- Inorganic Chemistry
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Experimental and theoretical evidence for the first example of an organolanthanide(II) compound having an indenyl ligand bonded to the metal through the benzo ring in η4 hapticity. / Wang, Shaowu; Tang, Xinliang; Vega, Andres; Saillard, Jean Yves; Sheng, Enhong; Yang, Gaosheng; Zhou, Shuangliu; Huang, Zixiang.
En: Organometallics, Vol. 25, N.º 10, 08.05.2006, p. 2399-2401.Resultado de la investigación: Article
TY - JOUR
T1 - Experimental and theoretical evidence for the first example of an organolanthanide(II) compound having an indenyl ligand bonded to the metal through the benzo ring in η4 hapticity
AU - Wang, Shaowu
AU - Tang, Xinliang
AU - Vega, Andres
AU - Saillard, Jean Yves
AU - Sheng, Enhong
AU - Yang, Gaosheng
AU - Zhou, Shuangliu
AU - Huang, Zixiang
PY - 2006/5/8
Y1 - 2006/5/8
N2 - The reaction of 2 equiv of C9H6-1-SiMe 3-3-CH2CH2-NC5H10 (2) with the ytterbium(III) amide [(Me3Si)2N] 3Yb-(μ-Cl)Li(THF)3 produced a novel ytterbium(II) complex with an indenyl ligand bonded to the metal via the benzo ring with η4 hapticity, (η4: η2η1-(C5H10NCH 2CH2C9H5SiMe3)Li(μ-Cl) ]Yb-(η5:η1-C5H10NCH 2CH2C9H5SiMe3) (1), as verified by a solid-state structure determination and theoretical calculations.
AB - The reaction of 2 equiv of C9H6-1-SiMe 3-3-CH2CH2-NC5H10 (2) with the ytterbium(III) amide [(Me3Si)2N] 3Yb-(μ-Cl)Li(THF)3 produced a novel ytterbium(II) complex with an indenyl ligand bonded to the metal via the benzo ring with η4 hapticity, (η4: η2η1-(C5H10NCH 2CH2C9H5SiMe3)Li(μ-Cl) ]Yb-(η5:η1-C5H10NCH 2CH2C9H5SiMe3) (1), as verified by a solid-state structure determination and theoretical calculations.
UR - http://www.scopus.com/inward/record.url?scp=33744479235&partnerID=8YFLogxK
U2 - 10.1021/om0601192
DO - 10.1021/om0601192
M3 - Article
AN - SCOPUS:33744479235
VL - 25
SP - 2399
EP - 2401
JO - Organometallics
JF - Organometallics
SN - 0276-7333
IS - 10
ER -