Experimental and theoretical evidence for the first example of an organolanthanide(II) compound having an indenyl ligand bonded to the metal through the benzo ring in η4 hapticity

Shaowu Wang; Xinliang Tang; Andres Vega; Jean Yves Saillard; Enhong Sheng; Gaosheng Yang; Shuangliu Zhou; Zixiang Huang

doi:10.1021/om0601192

Experimental and theoretical evidence for the first example of an organolanthanide(II) compound having an indenyl ligand bonded to the metal through the benzo ring in η⁴ hapticity

Shaowu Wang, Xinliang Tang, Andres Vega, Jean Yves Saillard, Enhong Sheng, Gaosheng Yang, Shuangliu Zhou, Zixiang Huang

Facultad Ciencias Exactas

Resultado de la investigación: Contribución a una revista › Artículo

24 Citas (Scopus)

Resumen

The reaction of 2 equiv of C₉H₆-1-SiMe ₃-3-CH₂CH₂-NC₅H₁₀ (2) with the ytterbium(III) amide [(Me₃Si)₂N] ₃Yb-(μ-Cl)Li(THF)₃ produced a novel ytterbium(II) complex with an indenyl ligand bonded to the metal via the benzo ring with η⁴ hapticity, (η⁴: η²η¹-(C₅H₁₀NCH ₂CH₂C₉H₅SiMe₃)Li(μ-Cl) ]Yb-(η⁵:η¹-C₅H₁₀NCH ₂CH₂C₉H₅SiMe₃) (1), as verified by a solid-state structure determination and theoretical calculations.

Idioma original	Inglés
Páginas (desde-hasta)	2399-2401
Número de páginas	3
Publicación	Organometallics
Volumen	25
N.º	10
DOI	https://doi.org/10.1021/om0601192
Estado	Publicada - 8 may 2006

Áreas temáticas de ASJC Scopus

Química física y teórica
Química orgánica
Química inorgánica

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10.1021/om0601192

Link to publication in Scopus

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Wang, S., Tang, X., Vega, A., Saillard, J. Y., Sheng, E., Yang, G., Zhou, S., & Huang, Z. (2006). Experimental and theoretical evidence for the first example of an organolanthanide(II) compound having an indenyl ligand bonded to the metal through the benzo ring in η⁴ hapticity. Organometallics, 25(10), 2399-2401. https://doi.org/10.1021/om0601192

Wang, Shaowu ; Tang, Xinliang ; Vega, Andres ; Saillard, Jean Yves ; Sheng, Enhong ; Yang, Gaosheng ; Zhou, Shuangliu ; Huang, Zixiang. / Experimental and theoretical evidence for the first example of an organolanthanide(II) compound having an indenyl ligand bonded to the metal through the benzo ring in η⁴ hapticity. En: Organometallics. 2006 ; Vol. 25, N.º 10. pp. 2399-2401.

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title = "Experimental and theoretical evidence for the first example of an organolanthanide(II) compound having an indenyl ligand bonded to the metal through the benzo ring in η4 hapticity",

abstract = "The reaction of 2 equiv of C9H6-1-SiMe 3-3-CH2CH2-NC5H10 (2) with the ytterbium(III) amide [(Me3Si)2N] 3Yb-(μ-Cl)Li(THF)3 produced a novel ytterbium(II) complex with an indenyl ligand bonded to the metal via the benzo ring with η4 hapticity, (η4: η2η1-(C5H10NCH 2CH2C9H5SiMe3)Li(μ-Cl) ]Yb-(η5:η1-C5H10NCH 2CH2C9H5SiMe3) (1), as verified by a solid-state structure determination and theoretical calculations.",

author = "Shaowu Wang and Xinliang Tang and Andres Vega and Saillard, {Jean Yves} and Enhong Sheng and Gaosheng Yang and Shuangliu Zhou and Zixiang Huang",

year = "2006",

month = may,

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doi = "10.1021/om0601192",

language = "English",

volume = "25",

pages = "2399--2401",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

number = "10",

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Experimental and theoretical evidence for the first example of an organolanthanide(II) compound having an indenyl ligand bonded to the metal through the benzo ring in η⁴ hapticity. / Wang, Shaowu; Tang, Xinliang; Vega, Andres; Saillard, Jean Yves; Sheng, Enhong; Yang, Gaosheng; Zhou, Shuangliu; Huang, Zixiang.

En: Organometallics, Vol. 25, N.º 10, 08.05.2006, p. 2399-2401.

Resultado de la investigación: Contribución a una revista › Artículo

TY - JOUR

T1 - Experimental and theoretical evidence for the first example of an organolanthanide(II) compound having an indenyl ligand bonded to the metal through the benzo ring in η4 hapticity

AU - Wang, Shaowu

AU - Tang, Xinliang

AU - Vega, Andres

AU - Saillard, Jean Yves

AU - Sheng, Enhong

AU - Yang, Gaosheng

AU - Zhou, Shuangliu

AU - Huang, Zixiang

PY - 2006/5/8

Y1 - 2006/5/8

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AB - The reaction of 2 equiv of C9H6-1-SiMe 3-3-CH2CH2-NC5H10 (2) with the ytterbium(III) amide [(Me3Si)2N] 3Yb-(μ-Cl)Li(THF)3 produced a novel ytterbium(II) complex with an indenyl ligand bonded to the metal via the benzo ring with η4 hapticity, (η4: η2η1-(C5H10NCH 2CH2C9H5SiMe3)Li(μ-Cl) ]Yb-(η5:η1-C5H10NCH 2CH2C9H5SiMe3) (1), as verified by a solid-state structure determination and theoretical calculations.

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