Experimental and theoretical evidence for the first example of an organolanthanide(II) compound having an indenyl ligand bonded to the metal through the benzo ring in η4 hapticity

Shaowu Wang, Xinliang Tang, Andres Vega, Jean Yves Saillard, Enhong Sheng, Gaosheng Yang, Shuangliu Zhou, Zixiang Huang

Resultado de la investigación: Article

24 Citas (Scopus)

Resumen

The reaction of 2 equiv of C9H6-1-SiMe 3-3-CH2CH2-NC5H10 (2) with the ytterbium(III) amide [(Me3Si)2N] 3Yb-(μ-Cl)Li(THF)3 produced a novel ytterbium(II) complex with an indenyl ligand bonded to the metal via the benzo ring with η4 hapticity, (η4: η2η1-(C5H10NCH 2CH2C9H5SiMe3)Li(μ-Cl) ]Yb-(η51-C5H10NCH 2CH2C9H5SiMe3) (1), as verified by a solid-state structure determination and theoretical calculations.

Idioma originalEnglish
Páginas (desde-hasta)2399-2401
Número de páginas3
PublicaciónOrganometallics
Volumen25
N.º10
DOI
EstadoPublished - 8 may 2006

Huella dactilar

Ytterbium
ytterbium
Metals
Ligands
ligands
rings
Amides
metals
amides
solid state

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

Citar esto

Wang, Shaowu ; Tang, Xinliang ; Vega, Andres ; Saillard, Jean Yves ; Sheng, Enhong ; Yang, Gaosheng ; Zhou, Shuangliu ; Huang, Zixiang. / Experimental and theoretical evidence for the first example of an organolanthanide(II) compound having an indenyl ligand bonded to the metal through the benzo ring in η4 hapticity. En: Organometallics. 2006 ; Vol. 25, N.º 10. pp. 2399-2401.
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title = "Experimental and theoretical evidence for the first example of an organolanthanide(II) compound having an indenyl ligand bonded to the metal through the benzo ring in η4 hapticity",
abstract = "The reaction of 2 equiv of C9H6-1-SiMe 3-3-CH2CH2-NC5H10 (2) with the ytterbium(III) amide [(Me3Si)2N] 3Yb-(μ-Cl)Li(THF)3 produced a novel ytterbium(II) complex with an indenyl ligand bonded to the metal via the benzo ring with η4 hapticity, (η4: η2η1-(C5H10NCH 2CH2C9H5SiMe3)Li(μ-Cl) ]Yb-(η5:η1-C5H10NCH 2CH2C9H5SiMe3) (1), as verified by a solid-state structure determination and theoretical calculations.",
author = "Shaowu Wang and Xinliang Tang and Andres Vega and Saillard, {Jean Yves} and Enhong Sheng and Gaosheng Yang and Shuangliu Zhou and Zixiang Huang",
year = "2006",
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Experimental and theoretical evidence for the first example of an organolanthanide(II) compound having an indenyl ligand bonded to the metal through the benzo ring in η4 hapticity. / Wang, Shaowu; Tang, Xinliang; Vega, Andres; Saillard, Jean Yves; Sheng, Enhong; Yang, Gaosheng; Zhou, Shuangliu; Huang, Zixiang.

En: Organometallics, Vol. 25, N.º 10, 08.05.2006, p. 2399-2401.

Resultado de la investigación: Article

TY - JOUR

T1 - Experimental and theoretical evidence for the first example of an organolanthanide(II) compound having an indenyl ligand bonded to the metal through the benzo ring in η4 hapticity

AU - Wang, Shaowu

AU - Tang, Xinliang

AU - Vega, Andres

AU - Saillard, Jean Yves

AU - Sheng, Enhong

AU - Yang, Gaosheng

AU - Zhou, Shuangliu

AU - Huang, Zixiang

PY - 2006/5/8

Y1 - 2006/5/8

N2 - The reaction of 2 equiv of C9H6-1-SiMe 3-3-CH2CH2-NC5H10 (2) with the ytterbium(III) amide [(Me3Si)2N] 3Yb-(μ-Cl)Li(THF)3 produced a novel ytterbium(II) complex with an indenyl ligand bonded to the metal via the benzo ring with η4 hapticity, (η4: η2η1-(C5H10NCH 2CH2C9H5SiMe3)Li(μ-Cl) ]Yb-(η5:η1-C5H10NCH 2CH2C9H5SiMe3) (1), as verified by a solid-state structure determination and theoretical calculations.

AB - The reaction of 2 equiv of C9H6-1-SiMe 3-3-CH2CH2-NC5H10 (2) with the ytterbium(III) amide [(Me3Si)2N] 3Yb-(μ-Cl)Li(THF)3 produced a novel ytterbium(II) complex with an indenyl ligand bonded to the metal via the benzo ring with η4 hapticity, (η4: η2η1-(C5H10NCH 2CH2C9H5SiMe3)Li(μ-Cl) ]Yb-(η5:η1-C5H10NCH 2CH2C9H5SiMe3) (1), as verified by a solid-state structure determination and theoretical calculations.

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U2 - 10.1021/om0601192

DO - 10.1021/om0601192

M3 - Article

AN - SCOPUS:33744479235

VL - 25

SP - 2399

EP - 2401

JO - Organometallics

JF - Organometallics

SN - 0276-7333

IS - 10

ER -