Electronic properties of mixed valence iron(II,III) dinuclear complexes with carboxylate bridges

V. Paredes-García, D. Venegas-Yazigi, R. O. Latorre, E. Spodine

Resultado de la investigación: Contribución a una revistaArtículo

15 Citas (Scopus)

Resumen

Mixed valence dinuclear iron(II,III) complexes of the type [Fe2L2(H2O)4](NO3 )(H2O)3, where L is the dianion of a Schiff base ligand derived from α-amino acids (glycine and l-isoleucine) and 5-bromosalicylaldehyde, have been prepared and characterised using different spectroscopic methods, magnetic susceptibility, conductivity, and electrochemical measurements. The mixed valence iron complexes can be described as hexacoordinated species, in which the metal ion is surrounded by water molecules, the salicylidenimine ligand and two bridging carboxylate groups. The presence of bromine as a substituent in the salicylaldehyde ring stabilises the mixed valence species.

Idioma originalInglés
Páginas (desde-hasta)2026-2032
Número de páginas7
PublicaciónPolyhedron
Volumen25
N.º9
DOI
EstadoPublicada - 19 jun 2006

Áreas temáticas de ASJC Scopus

  • Química física y teórica
  • Química inorgánica
  • Química de los materiales

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