Di-μ-hydroxo-bis{(acetonitrile)di-benzyl(6-methyl-2-pyridylmethyl) amine-κ2N,Ncopper(II)} bis(perchlorate)

Dario Rojas, Ana María García, Jorge Manzur, Andrés Vega

Resultado de la investigación: Article

2 Citas (Scopus)

Resumen

The title compound corresponds to a copper(II) dimer, [CU 2(OH)2(C2H3N)2(C 21H22N2)2](ClO4) 2, where the metal centres are μ2-bridged by hydroxo groups. The coordination of each copper(II) centre is a slightly distorted square-based pyramid, with two N atoms from dibenzyl(6-methyl-2-pyridylmethyl) amine (BiBzMePMA) and two hydroxo O atoms occupying the basal positions, and the acetonitrile N atom at the apical position. The dimer is centrosymmetric, with a crystallographic inversion centre midway between the two Cu atoms [Cu⋯Cu = 2.9522 (9) Å]

Idioma originalEnglish
PublicaciónActa Crystallographica Section C: Crystal Structure Communications
Volumen61
N.º2
DOI
EstadoPublished - feb 2005

Huella dactilar

perchlorates
acetonitrile
Amines
Copper
amines
Atoms
Dimers
atoms
Metals
dimers
copper
pyramids
inversions
perchlorate
metals

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Structural Biology
  • Biochemistry, Genetics and Molecular Biology(all)
  • Medicine(all)

Citar esto

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title = "Di-μ-hydroxo-bis{(acetonitrile)di-benzyl(6-methyl-2-pyridylmethyl) amine-κ2N,Ncopper(II)} bis(perchlorate)",
abstract = "The title compound corresponds to a copper(II) dimer, [CU 2(OH)2(C2H3N)2(C 21H22N2)2](ClO4) 2, where the metal centres are μ2-bridged by hydroxo groups. The coordination of each copper(II) centre is a slightly distorted square-based pyramid, with two N atoms from dibenzyl(6-methyl-2-pyridylmethyl) amine (BiBzMePMA) and two hydroxo O atoms occupying the basal positions, and the acetonitrile N atom at the apical position. The dimer is centrosymmetric, with a crystallographic inversion centre midway between the two Cu atoms [Cu⋯Cu = 2.9522 (9) {\AA}]",
author = "Dario Rojas and Garc{\'i}a, {Ana Mar{\'i}a} and Jorge Manzur and Andr{\'e}s Vega",
year = "2005",
month = "2",
doi = "10.1107/S010827010500034X",
language = "English",
volume = "61",
journal = "Acta Crystallographica Section C: Crystal Structure Communications",
issn = "0108-2701",
publisher = "International Union of Crystallography",
number = "2",

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TY - JOUR

T1 - Di-μ-hydroxo-bis{(acetonitrile)di-benzyl(6-methyl-2-pyridylmethyl) amine-κ2N,Ncopper(II)} bis(perchlorate)

AU - Rojas, Dario

AU - García, Ana María

AU - Manzur, Jorge

AU - Vega, Andrés

PY - 2005/2

Y1 - 2005/2

N2 - The title compound corresponds to a copper(II) dimer, [CU 2(OH)2(C2H3N)2(C 21H22N2)2](ClO4) 2, where the metal centres are μ2-bridged by hydroxo groups. The coordination of each copper(II) centre is a slightly distorted square-based pyramid, with two N atoms from dibenzyl(6-methyl-2-pyridylmethyl) amine (BiBzMePMA) and two hydroxo O atoms occupying the basal positions, and the acetonitrile N atom at the apical position. The dimer is centrosymmetric, with a crystallographic inversion centre midway between the two Cu atoms [Cu⋯Cu = 2.9522 (9) Å]

AB - The title compound corresponds to a copper(II) dimer, [CU 2(OH)2(C2H3N)2(C 21H22N2)2](ClO4) 2, where the metal centres are μ2-bridged by hydroxo groups. The coordination of each copper(II) centre is a slightly distorted square-based pyramid, with two N atoms from dibenzyl(6-methyl-2-pyridylmethyl) amine (BiBzMePMA) and two hydroxo O atoms occupying the basal positions, and the acetonitrile N atom at the apical position. The dimer is centrosymmetric, with a crystallographic inversion centre midway between the two Cu atoms [Cu⋯Cu = 2.9522 (9) Å]

UR - http://www.scopus.com/inward/record.url?scp=30944467566&partnerID=8YFLogxK

U2 - 10.1107/S010827010500034X

DO - 10.1107/S010827010500034X

M3 - Article

C2 - 15695890

AN - SCOPUS:30944467566

VL - 61

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

SN - 0108-2701

IS - 2

ER -