Resumen
The title compound corresponds to a copper(II) dimer, [CU 2(OH)2(C2H3N)2(C 21H22N2)2](ClO4) 2, where the metal centres are μ2-bridged by hydroxo groups. The coordination of each copper(II) centre is a slightly distorted square-based pyramid, with two N atoms from dibenzyl(6-methyl-2-pyridylmethyl) amine (BiBzMePMA) and two hydroxo O atoms occupying the basal positions, and the acetonitrile N atom at the apical position. The dimer is centrosymmetric, with a crystallographic inversion centre midway between the two Cu atoms [Cu⋯Cu = 2.9522 (9) Å]
| Idioma original | English |
|---|---|
| Publicación | Acta Crystallographica Section C: Crystal Structure Communications |
| Volumen | 61 |
| N.º | 2 |
| DOI | |
| Estado | Published - feb 2005 |
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ASJC Scopus subject areas
- Condensed Matter Physics
- Structural Biology
- Biochemistry, Genetics and Molecular Biology(all)
- Medicine(all)
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Di-μ-hydroxo-bis{(acetonitrile)di-benzyl(6-methyl-2-pyridylmethyl) amine-κ2N,Ncopper(II)} bis(perchlorate). / Rojas, Dario; García, Ana María; Manzur, Jorge; Vega, Andrés.
En: Acta Crystallographica Section C: Crystal Structure Communications, Vol. 61, N.º 2, 02.2005.Resultado de la investigación: Article
TY - JOUR
T1 - Di-μ-hydroxo-bis{(acetonitrile)di-benzyl(6-methyl-2-pyridylmethyl) amine-κ2N,Ncopper(II)} bis(perchlorate)
AU - Rojas, Dario
AU - García, Ana María
AU - Manzur, Jorge
AU - Vega, Andrés
PY - 2005/2
Y1 - 2005/2
N2 - The title compound corresponds to a copper(II) dimer, [CU 2(OH)2(C2H3N)2(C 21H22N2)2](ClO4) 2, where the metal centres are μ2-bridged by hydroxo groups. The coordination of each copper(II) centre is a slightly distorted square-based pyramid, with two N atoms from dibenzyl(6-methyl-2-pyridylmethyl) amine (BiBzMePMA) and two hydroxo O atoms occupying the basal positions, and the acetonitrile N atom at the apical position. The dimer is centrosymmetric, with a crystallographic inversion centre midway between the two Cu atoms [Cu⋯Cu = 2.9522 (9) Å]
AB - The title compound corresponds to a copper(II) dimer, [CU 2(OH)2(C2H3N)2(C 21H22N2)2](ClO4) 2, where the metal centres are μ2-bridged by hydroxo groups. The coordination of each copper(II) centre is a slightly distorted square-based pyramid, with two N atoms from dibenzyl(6-methyl-2-pyridylmethyl) amine (BiBzMePMA) and two hydroxo O atoms occupying the basal positions, and the acetonitrile N atom at the apical position. The dimer is centrosymmetric, with a crystallographic inversion centre midway between the two Cu atoms [Cu⋯Cu = 2.9522 (9) Å]
UR - http://www.scopus.com/inward/record.url?scp=30944467566&partnerID=8YFLogxK
U2 - 10.1107/S010827010500034X
DO - 10.1107/S010827010500034X
M3 - Article
C2 - 15695890
AN - SCOPUS:30944467566
VL - 61
JO - Acta Crystallographica Section C: Crystal Structure Communications
JF - Acta Crystallographica Section C: Crystal Structure Communications
SN - 0108-2701
IS - 2
ER -