Di-μ-hydroxo-bis{(acetonitrile)di-benzyl(6-methyl-2-pyridylmethyl) amine-κ2N,Ncopper(II)} bis(perchlorate)

Dario Rojas; Ana María García; Jorge Manzur; Andrés Vega

doi:10.1107/S010827010500034X

Di-μ-hydroxo-bis{(acetonitrile)di-benzyl(6-methyl-2-pyridylmethyl) amine-κ²N,Ncopper(II)} bis(perchlorate)

Dario Rojas, Ana María García, Jorge Manzur, Andrés Vega

Facultad Ciencias Exactas

Resultado de la investigación: Contribución a una revista › Artículo

2 Citas (Scopus)

Resumen

The title compound corresponds to a copper(II) dimer, [CU ₂(OH)₂(C₂H₃N)₂(C ₂₁H₂₂N₂)₂](ClO₄) ₂, where the metal centres are μ₂-bridged by hydroxo groups. The coordination of each copper(II) centre is a slightly distorted square-based pyramid, with two N atoms from dibenzyl(6-methyl-2-pyridylmethyl) amine (BiBzMePMA) and two hydroxo O atoms occupying the basal positions, and the acetonitrile N atom at the apical position. The dimer is centrosymmetric, with a crystallographic inversion centre midway between the two Cu atoms [Cu⋯Cu = 2.9522 (9) Å]

Idioma original	Inglés
Publicación	Acta Crystallographica Section C: Crystal Structure Communications
Volumen	61
N.º	2
DOI	https://doi.org/10.1107/S010827010500034X
Estado	Publicada - feb 2005

Áreas temáticas de ASJC Scopus

Física de la materia condensada
Biología estructural
Bioquímica, genética y biología molecular (todo)
Medicina (todo)

Acceder al documento

10.1107/S010827010500034X

Link to publication in Scopus

Huella Profundice en los temas de investigación de 'Di-μ-hydroxo-bis{(acetonitrile)di-benzyl(6-methyl-2-pyridylmethyl) amine-κ<sup>2</sup>N,Ncopper(II)} bis(perchlorate)'. En conjunto forman una huella única.

Citar esto

Rojas, D., García, A. M., Manzur, J., & Vega, A. (2005). Di-μ-hydroxo-bis{(acetonitrile)di-benzyl(6-methyl-2-pyridylmethyl) amine-κ²N,Ncopper(II)} bis(perchlorate). Acta Crystallographica Section C: Crystal Structure Communications, 61(2). https://doi.org/10.1107/S010827010500034X

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title = "Di-μ-hydroxo-bis{(acetonitrile)di-benzyl(6-methyl-2-pyridylmethyl) amine-κ2N,Ncopper(II)} bis(perchlorate)",

abstract = "The title compound corresponds to a copper(II) dimer, [CU 2(OH)2(C2H3N)2(C 21H22N2)2](ClO4) 2, where the metal centres are μ2-bridged by hydroxo groups. The coordination of each copper(II) centre is a slightly distorted square-based pyramid, with two N atoms from dibenzyl(6-methyl-2-pyridylmethyl) amine (BiBzMePMA) and two hydroxo O atoms occupying the basal positions, and the acetonitrile N atom at the apical position. The dimer is centrosymmetric, with a crystallographic inversion centre midway between the two Cu atoms [Cu⋯Cu = 2.9522 (9) {\AA}]",

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T1 - Di-μ-hydroxo-bis{(acetonitrile)di-benzyl(6-methyl-2-pyridylmethyl) amine-κ2N,Ncopper(II)} bis(perchlorate)

AU - Rojas, Dario

AU - García, Ana María

AU - Manzur, Jorge

AU - Vega, Andrés

PY - 2005/2

Y1 - 2005/2

N2 - The title compound corresponds to a copper(II) dimer, [CU 2(OH)2(C2H3N)2(C 21H22N2)2](ClO4) 2, where the metal centres are μ2-bridged by hydroxo groups. The coordination of each copper(II) centre is a slightly distorted square-based pyramid, with two N atoms from dibenzyl(6-methyl-2-pyridylmethyl) amine (BiBzMePMA) and two hydroxo O atoms occupying the basal positions, and the acetonitrile N atom at the apical position. The dimer is centrosymmetric, with a crystallographic inversion centre midway between the two Cu atoms [Cu⋯Cu = 2.9522 (9) Å]

AB - The title compound corresponds to a copper(II) dimer, [CU 2(OH)2(C2H3N)2(C 21H22N2)2](ClO4) 2, where the metal centres are μ2-bridged by hydroxo groups. The coordination of each copper(II) centre is a slightly distorted square-based pyramid, with two N atoms from dibenzyl(6-methyl-2-pyridylmethyl) amine (BiBzMePMA) and two hydroxo O atoms occupying the basal positions, and the acetonitrile N atom at the apical position. The dimer is centrosymmetric, with a crystallographic inversion centre midway between the two Cu atoms [Cu⋯Cu = 2.9522 (9) Å]

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