Cyclodextrin-surfactant binding constant as driven force for uncomplexed cyclodextrin in equilibrium with micellar systems

M. Cepeda, R. Daviña, L. García-Río, M. Parajó

Resultado de la investigación: Contribución a una revistaArtículo

16 Citas (Scopus)

Resumen

Mixed systems formed by surfactants, sodium alkylsulfonates, and β-cyclodextrin have been studied by using the solvolysis of 4-methoxybenzenesulfonil chloride (MBSC) as a chemical probe. The kinetic analysis allows us to obtain the percentage of uncomplexed cyclodextrin in equilibrium with the micellar media and its variation with the alkyl chain length of the surfactant. Competition between surfactant complexation by the cyclodextrin and self-aggregation to form micelles is the driving force for the percentage of uncomplexed cyclodextrin in equilibrium with the micellar system and its variation with the surfactant chain length.

Idioma originalInglés
Páginas (desde-hasta)70-74
Número de páginas5
PublicaciónChemical Physics Letters
Volumen499
N.º1-3
DOI
EstadoPublicada - 20 oct 2010

Áreas temáticas de ASJC Scopus

  • Física y astronomía (todo)
  • Química física y teórica

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