{[Cu3Lu2(ODA)6(H2O)6]·10H2O}: N: The first heterometallic framework based on copper(II)/lutetium(III) for the catalytic oxidation of olefins and aromatic benzylic substrates

P. Cancino, V. Paredes-García, J. Torres, S. Martínez, C. Kremer, E. Spodine

Resultado de la investigación: Contribución a la publicaciónArticle

  • 2 Citas

Resumen

The catalytic performance of the novel framework {[Cu3Lu2(ODA)6(H2O)6]·10H2O}n was tested in the oxidation of alkenes and benzylic hydrocarbons, using tert-butyl hydroperoxide (TBHP) and molecular oxygen (O2) as oxidants. Excellent conversions were obtained with O2 under solvent-free conditions, in the absence of a co-catalyst, for cyclohexene (95%) and for cumene (91%).

IdiomaEnglish
Páginas4929-4933
Número de páginas5
PublicaciónCatalysis Science and Technology
Volumen7
Número de edición21
DOI
EstadoPublished - 1 ene 2017

Huella dactilar

Lutetium
tert-Butylhydroperoxide
Molecular oxygen
Catalytic oxidation
Alkenes
Hydrocarbons
Oxidants
Olefins
Copper
Oxidation
Catalysts
Substrates
cyclohexene
cumene

ASJC Scopus subject areas

  • Catalysis

Citar esto

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title = "{[Cu3Lu2(ODA)6(H2O)6]·10H2O}: N: The first heterometallic framework based on copper(II)/lutetium(III) for the catalytic oxidation of olefins and aromatic benzylic substrates",
abstract = "The catalytic performance of the novel framework {[Cu3Lu2(ODA)6(H2O)6]·10H2O}n was tested in the oxidation of alkenes and benzylic hydrocarbons, using tert-butyl hydroperoxide (TBHP) and molecular oxygen (O2) as oxidants. Excellent conversions were obtained with O2 under solvent-free conditions, in the absence of a co-catalyst, for cyclohexene (95{\%}) and for cumene (91{\%}).",
author = "P. Cancino and V. Paredes-Garc{\'i}a and J. Torres and S. Mart{\'i}nez and C. Kremer and E. Spodine",
year = "2017",
month = "1",
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doi = "10.1039/c7cy01385j",
language = "English",
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pages = "4929--4933",
journal = "Catalysis Science and Technology",
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publisher = "Royal Society of Chemistry",
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{[Cu3Lu2(ODA)6(H2O)6]·10H2O}: N: The first heterometallic framework based on copper(II)/lutetium(III) for the catalytic oxidation of olefins and aromatic benzylic substrates. / Cancino, P.; Paredes-García, V.; Torres, J.; Martínez, S.; Kremer, C.; Spodine, E.

En: Catalysis Science and Technology, Vol. 7, N.º 21, 01.01.2017, p. 4929-4933.

Resultado de la investigación: Contribución a la publicaciónArticle

TY - JOUR

T1 - {[Cu3Lu2(ODA)6(H2O)6]·10H2O}: N: The first heterometallic framework based on copper(II)/lutetium(III) for the catalytic oxidation of olefins and aromatic benzylic substrates

AU - Cancino,P.

AU - Paredes-García,V.

AU - Torres,J.

AU - Martínez,S.

AU - Kremer,C.

AU - Spodine,E.

PY - 2017/1/1

Y1 - 2017/1/1

N2 - The catalytic performance of the novel framework {[Cu3Lu2(ODA)6(H2O)6]·10H2O}n was tested in the oxidation of alkenes and benzylic hydrocarbons, using tert-butyl hydroperoxide (TBHP) and molecular oxygen (O2) as oxidants. Excellent conversions were obtained with O2 under solvent-free conditions, in the absence of a co-catalyst, for cyclohexene (95%) and for cumene (91%).

AB - The catalytic performance of the novel framework {[Cu3Lu2(ODA)6(H2O)6]·10H2O}n was tested in the oxidation of alkenes and benzylic hydrocarbons, using tert-butyl hydroperoxide (TBHP) and molecular oxygen (O2) as oxidants. Excellent conversions were obtained with O2 under solvent-free conditions, in the absence of a co-catalyst, for cyclohexene (95%) and for cumene (91%).

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U2 - 10.1039/c7cy01385j

DO - 10.1039/c7cy01385j

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JO - Catalysis Science and Technology

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