[Cu(H2btec)(bipy)]: Reusable metal organic polymer catalyst for epoxidation reactions

Pedro Aguirre, Kareen Brown, Diego Venegas-Yazigi, Verónica Paredes-García, Evgenia Spodine

Resultado de la investigación: Contribución a una revistaArtículorevisión exhaustiva

7 Citas (Scopus)

Resumen

The search of new inorganic materials with better catalytic properties is an important field of research. Reusability, efficiency and atom economy correspond to the main parameters to characterize a catalyst. In this work, we inform the effectiveness of [Cu(H2btec)(bipy)] (H4btec = 1,2,4,5-benzenetetracarboxylic acid) as an heterogeneous coordination polymer catalyst for the oxidation of olefins. The catalyst exhibits good atom economy, high turnover numbers and good selectivity for a ratio of 4000/1 substrate/catalyst for cyclohexene and styrene oxidation. Furthermore, the catalyst was recycled and reused for seven consecutive cycles, retaining the structural integrity and effectiveness as catalyst in all the performed experiments.

Idioma originalInglés
Páginas (desde-hasta)65-71
Número de páginas7
PublicaciónMacromolecular Symposia
Volumen304
N.º1
DOI
EstadoPublicada - jun 2011

Áreas temáticas de ASJC Scopus

  • Química orgánica
  • Química de los materiales
  • Polímeros y plásticos
  • Física de la materia condensada

Huella

Profundice en los temas de investigación de '[Cu(H<sub>2</sub>btec)(bipy)]<sub>∞</sub>: Reusable metal organic polymer catalyst for epoxidation reactions'. En conjunto forman una huella única.

Citar esto