Copper(II) assisted hydrolysis of 2,4,6-tris(pyrazol-1-yl)-1,3,5-triazine. Crystal and molecular structure of catena-[CuL(H2O)Cl]n (L = 2,4-dione-1,3,5-(1H)-triazin-1-amido)

Jorge Manzur, Carolina Acuña, Andrés Vega, Ana María García

Resultado de la investigación: Article

13 Citas (Scopus)

Resumen

This article describes the partial hydrolysis of the multidentate ligand 2,4,6-tris(pyrazol-1-yl)-1,3,5-triazine in the presence of copper(II), to give the anionic ligand 2,4-dione-1,3,5-(1H)-triazin-1-amido, which was isolated as the cupric complex catena-[CuL(H2O)Cl]n, where L is the amido ligand. No other hydrolysis products were isolated or identified. The complex defines a zigzag 1D covalent chain, along the b cell axis, through apical copper-oxygen bonds (Cu-N-C-O⋯Cu bridges).

Idioma originalEnglish
Páginas (desde-hasta)637-642
Número de páginas6
PublicaciónInorganica Chimica Acta
Volumen374
N.º1
DOI
EstadoPublished - 1 ago 2011

Huella dactilar

Triazines
Dione
Molecular structure
hydrolysis
Copper
Hydrolysis
molecular structure
Crystal structure
Ligands
copper
ligands
crystal structure
Oxygen
oxygen
products
cells

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

Citar esto

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title = "Copper(II) assisted hydrolysis of 2,4,6-tris(pyrazol-1-yl)-1,3,5-triazine. Crystal and molecular structure of catena-[CuL(H2O)Cl]n (L = 2,4-dione-1,3,5-(1H)-triazin-1-amido)",
abstract = "This article describes the partial hydrolysis of the multidentate ligand 2,4,6-tris(pyrazol-1-yl)-1,3,5-triazine in the presence of copper(II), to give the anionic ligand 2,4-dione-1,3,5-(1H)-triazin-1-amido, which was isolated as the cupric complex catena-[CuL(H2O)Cl]n, where L is the amido ligand. No other hydrolysis products were isolated or identified. The complex defines a zigzag 1D covalent chain, along the b cell axis, through apical copper-oxygen bonds (Cu-N-C-O⋯Cu bridges).",
keywords = "1,3,5-Triazine, Copper complex, Hydrolysis, Molecular structure",
author = "Jorge Manzur and Carolina Acu{\~n}a and Andr{\'e}s Vega and Garc{\'i}a, {Ana Mar{\'i}a}",
year = "2011",
month = "8",
day = "1",
doi = "10.1016/j.ica.2011.03.031",
language = "English",
volume = "374",
pages = "637--642",
journal = "Inorganica Chimica Acta",
issn = "0020-1693",
publisher = "Elsevier BV",
number = "1",

}

Copper(II) assisted hydrolysis of 2,4,6-tris(pyrazol-1-yl)-1,3,5-triazine. Crystal and molecular structure of catena-[CuL(H2O)Cl]n (L = 2,4-dione-1,3,5-(1H)-triazin-1-amido). / Manzur, Jorge; Acuña, Carolina; Vega, Andrés; García, Ana María.

En: Inorganica Chimica Acta, Vol. 374, N.º 1, 01.08.2011, p. 637-642.

Resultado de la investigación: Article

TY - JOUR

T1 - Copper(II) assisted hydrolysis of 2,4,6-tris(pyrazol-1-yl)-1,3,5-triazine. Crystal and molecular structure of catena-[CuL(H2O)Cl]n (L = 2,4-dione-1,3,5-(1H)-triazin-1-amido)

AU - Manzur, Jorge

AU - Acuña, Carolina

AU - Vega, Andrés

AU - García, Ana María

PY - 2011/8/1

Y1 - 2011/8/1

N2 - This article describes the partial hydrolysis of the multidentate ligand 2,4,6-tris(pyrazol-1-yl)-1,3,5-triazine in the presence of copper(II), to give the anionic ligand 2,4-dione-1,3,5-(1H)-triazin-1-amido, which was isolated as the cupric complex catena-[CuL(H2O)Cl]n, where L is the amido ligand. No other hydrolysis products were isolated or identified. The complex defines a zigzag 1D covalent chain, along the b cell axis, through apical copper-oxygen bonds (Cu-N-C-O⋯Cu bridges).

AB - This article describes the partial hydrolysis of the multidentate ligand 2,4,6-tris(pyrazol-1-yl)-1,3,5-triazine in the presence of copper(II), to give the anionic ligand 2,4-dione-1,3,5-(1H)-triazin-1-amido, which was isolated as the cupric complex catena-[CuL(H2O)Cl]n, where L is the amido ligand. No other hydrolysis products were isolated or identified. The complex defines a zigzag 1D covalent chain, along the b cell axis, through apical copper-oxygen bonds (Cu-N-C-O⋯Cu bridges).

KW - 1,3,5-Triazine

KW - Copper complex

KW - Hydrolysis

KW - Molecular structure

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U2 - 10.1016/j.ica.2011.03.031

DO - 10.1016/j.ica.2011.03.031

M3 - Article

AN - SCOPUS:79960554377

VL - 374

SP - 637

EP - 642

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

SN - 0020-1693

IS - 1

ER -