Control of magnetic anisotropy by macrocyclic ligand distortion in a family of DyIIIand ErIIIsingle molecule magnets

Yolimar Gil, Pablo Fuentealba, Andrés Vega, Evgenia Spodine, Daniel Aravena

Resultado de la investigación: Contribución a una revistaArtículorevisión exhaustiva

2 Citas (Scopus)

Resumen

A family of hexaazamacrocyclic lanthanide complexes, [Ln(Ln)(NCS)3] (LnIII = Dy, Er; n = 1-3) has been synthesized and characterized by single-crystal X-ray diffraction, magnetic measurements and ab initio calculations. Macrocyclic ligands (Ln) differ in the lateral spacers, which are aliphatic chains with two and three carbons (for Ln, n = 1 and 2, respectively), and an aromatic ring for Ln = 3. Modification of the macrocycle spacer tunes planarity and rigidity of the equatorial coordination for both oblate (Dy) and prolate (Er) lanthanide ions. Ac-susceptibility studies showed that four of the six complexes are field induced single molecule magnets (SMMs). Trends in magnetic relaxation properties are rationalized with the aid of ab initio multireference calculations, highlighting the combined influence of macrocycle planarity, lanthanide electronic density distribution and intermolecular interactions for the achievement of slow demagnetization. This journal is

Idioma originalInglés
Páginas (desde-hasta)17709-17718
Número de páginas10
PublicaciónDalton Transactions
Volumen49
N.º48
DOI
EstadoPublicada - 28 dic 2020

Áreas temáticas de ASJC Scopus

  • Química inorgánica

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