Calculated optical and magnetic properties of hexafluorouranate (V) anion: UF6 -

Ramiro Arratia-Pérez, Lucia Hernandez-Acevedo, Gulzari L. Malli

Resultado de la investigación: Article

29 Citas (Scopus)

Resumen

The optical and magnetic properties of hexafluorouranate (V) anion U-F bound was discussed. The Dirac scattered wave calculation was also performed at the optimized U-F bond distances using the first order pertubational procedure. Orbital contributions from unquenched orbital angular contributes significantly to the Zee man effects as well as the 235U hyperfine interactions. It was observed that the close agreement between theory and experiments for the Zeeman splitting suggests that the use of four component Dirac molecular wave functions is necessary while a relativistic treatment taking into account double group.

Idioma originalEnglish
Páginas (desde-hasta)7743-7747
Número de páginas5
PublicaciónJournal of Chemical Physics
Volumen121
N.º16
DOI
EstadoPublished - 22 oct 2004

Huella dactilar

Wave functions
Anions
Magnetic properties
Optical properties
magnetic properties
anions
optical properties
orbitals
Experiments
wave functions
interactions

ASJC Scopus subject areas

  • Atomic and Molecular Physics, and Optics
  • Physical and Theoretical Chemistry
  • Physics and Astronomy(all)

Citar esto

Arratia-Pérez, Ramiro ; Hernandez-Acevedo, Lucia ; Malli, Gulzari L. / Calculated optical and magnetic properties of hexafluorouranate (V) anion : UF6 -. En: Journal of Chemical Physics. 2004 ; Vol. 121, N.º 16. pp. 7743-7747.
@article{03499fd759a24afd831b70eefa913f3b,
title = "Calculated optical and magnetic properties of hexafluorouranate (V) anion: UF6 -",
abstract = "The optical and magnetic properties of hexafluorouranate (V) anion U-F bound was discussed. The Dirac scattered wave calculation was also performed at the optimized U-F bond distances using the first order pertubational procedure. Orbital contributions from unquenched orbital angular contributes significantly to the Zee man effects as well as the 235U hyperfine interactions. It was observed that the close agreement between theory and experiments for the Zeeman splitting suggests that the use of four component Dirac molecular wave functions is necessary while a relativistic treatment taking into account double group.",
author = "Ramiro Arratia-P{\'e}rez and Lucia Hernandez-Acevedo and Malli, {Gulzari L.}",
year = "2004",
month = "10",
day = "22",
doi = "10.1063/1.1799891",
language = "English",
volume = "121",
pages = "7743--7747",
journal = "Journal of Chemical Physics",
issn = "0021-9606",
publisher = "American Institute of Physics",
number = "16",

}

Calculated optical and magnetic properties of hexafluorouranate (V) anion : UF6 -. / Arratia-Pérez, Ramiro; Hernandez-Acevedo, Lucia; Malli, Gulzari L.

En: Journal of Chemical Physics, Vol. 121, N.º 16, 22.10.2004, p. 7743-7747.

Resultado de la investigación: Article

TY - JOUR

T1 - Calculated optical and magnetic properties of hexafluorouranate (V) anion

T2 - UF6 -

AU - Arratia-Pérez, Ramiro

AU - Hernandez-Acevedo, Lucia

AU - Malli, Gulzari L.

PY - 2004/10/22

Y1 - 2004/10/22

N2 - The optical and magnetic properties of hexafluorouranate (V) anion U-F bound was discussed. The Dirac scattered wave calculation was also performed at the optimized U-F bond distances using the first order pertubational procedure. Orbital contributions from unquenched orbital angular contributes significantly to the Zee man effects as well as the 235U hyperfine interactions. It was observed that the close agreement between theory and experiments for the Zeeman splitting suggests that the use of four component Dirac molecular wave functions is necessary while a relativistic treatment taking into account double group.

AB - The optical and magnetic properties of hexafluorouranate (V) anion U-F bound was discussed. The Dirac scattered wave calculation was also performed at the optimized U-F bond distances using the first order pertubational procedure. Orbital contributions from unquenched orbital angular contributes significantly to the Zee man effects as well as the 235U hyperfine interactions. It was observed that the close agreement between theory and experiments for the Zeeman splitting suggests that the use of four component Dirac molecular wave functions is necessary while a relativistic treatment taking into account double group.

UR - http://www.scopus.com/inward/record.url?scp=8344244627&partnerID=8YFLogxK

U2 - 10.1063/1.1799891

DO - 10.1063/1.1799891

M3 - Article

C2 - 15485235

AN - SCOPUS:8344244627

VL - 121

SP - 7743

EP - 7747

JO - Journal of Chemical Physics

JF - Journal of Chemical Physics

SN - 0021-9606

IS - 16

ER -