Calcium-Poison-Resistant Cu/YCeO₂-TiO₂ Catalyst for the Selective Catalytic Reduction of NO with CO and Naphthalene in the Presence of Oxygen

The pollution from industrial processes based on biomass combustion is still an ongoing problem. In the present contribution, the selective catalytic reduction of NO with CO and naphthalene is carried out in the presence of 10% oxygen. The accumulation of alkaline and alkaline earth metals during biomass combustion is here simulated by the addition of calcium to a Cu-impregnated YCeO₂-TiO₂ support. The results show that a high dispersion of copper is obtained, which is resistant to the accumulation of calcium. Full conversion of CO and naphthalene is achieved above 200 °C, whereas NO conversions of 80, 90, and 87% are obtained for the catalysts with Ca loadings of 2.6, 5.2, and 13%, respectively, at 350 °C. It is proposed that the high activity of the catalysts is ascribed to the formation of Cu-O_x-Ce species and that the accumulation of Ca acts as a barrier to avoid copper sintering. It was found that different forms of carbonate and nitrite/nitrate species form during reaction, coexisting as adsorbed species during the SCR reaction. The selectivity to N₂ was almost 100% in all cases, due to the small presence of NO₂ in the reactor outlet (no N₂O was detected in any conditions).