Aquabis(benzonitrile)(o-benzoquinone diimine)(triphenylphosphine) ruthenium(II) bis(tetrafluoroborate) hydrate

Diego Venegas-Yazigi, A. B P Lever, Alan J. Lough, Andrés Vega, Verónica Paredes-García, Juan Costamagna, Ramoń Latorre

Resultado de la investigación: Article

4 Citas (Scopus)

Resumen

A family of ruthenium complexes containing o-benzoquinone diimine (BQDI) and other non-redox active ligands with different electron donor±acceptor behavior was synthesized in order to understand the bonding between ruthenium and redox-active (non-innocent) ligands and its implication for electrochemical behavior. The Ru atom in the title complex, shows an octahedral coordination. The benzonitrile ligands are in the same plane as the o-benzoquinone diimine ligand. Bond distances for the benzoquinone diimine ring establish a quinone arrangement showing that the highly acidic behavior of the benzonitrile ligands does not have an influence on its arrangement.

Idioma originalEnglish
PublicaciónActa Crystallographica Section C: Crystal Structure Communications
Volumen56
N.º8
DOI
EstadoPublished - ago 2000

Huella dactilar

Ruthenium
Hydrates
Ligands
Oxidation-Reduction
triphenylphosphine
2-benzoquinone
benzonitrile
Electrons
Atoms

ASJC Scopus subject areas

  • Biochemistry, Genetics and Molecular Biology(all)
  • Medicine(all)

Citar esto

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title = "Aquabis(benzonitrile)(o-benzoquinone diimine)(triphenylphosphine) ruthenium(II) bis(tetrafluoroborate) hydrate",
abstract = "A family of ruthenium complexes containing o-benzoquinone diimine (BQDI) and other non-redox active ligands with different electron donor±acceptor behavior was synthesized in order to understand the bonding between ruthenium and redox-active (non-innocent) ligands and its implication for electrochemical behavior. The Ru atom in the title complex, shows an octahedral coordination. The benzonitrile ligands are in the same plane as the o-benzoquinone diimine ligand. Bond distances for the benzoquinone diimine ring establish a quinone arrangement showing that the highly acidic behavior of the benzonitrile ligands does not have an influence on its arrangement.",
author = "Diego Venegas-Yazigi and Lever, {A. B P} and Lough, {Alan J.} and Andr{\'e}s Vega and Ver{\'o}nica Paredes-Garc{\'i}a and Juan Costamagna and Ramoń Latorre",
year = "2000",
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language = "English",
volume = "56",
journal = "Acta Crystallographica Section C: Crystal Structure Communications",
issn = "0108-2701",
publisher = "International Union of Crystallography",
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Aquabis(benzonitrile)(o-benzoquinone diimine)(triphenylphosphine) ruthenium(II) bis(tetrafluoroborate) hydrate. / Venegas-Yazigi, Diego; Lever, A. B P; Lough, Alan J.; Vega, Andrés; Paredes-García, Verónica; Costamagna, Juan; Latorre, Ramoń.

En: Acta Crystallographica Section C: Crystal Structure Communications, Vol. 56, N.º 8, 08.2000.

Resultado de la investigación: Article

TY - JOUR

T1 - Aquabis(benzonitrile)(o-benzoquinone diimine)(triphenylphosphine) ruthenium(II) bis(tetrafluoroborate) hydrate

AU - Venegas-Yazigi, Diego

AU - Lever, A. B P

AU - Lough, Alan J.

AU - Vega, Andrés

AU - Paredes-García, Verónica

AU - Costamagna, Juan

AU - Latorre, Ramoń

PY - 2000/8

Y1 - 2000/8

N2 - A family of ruthenium complexes containing o-benzoquinone diimine (BQDI) and other non-redox active ligands with different electron donor±acceptor behavior was synthesized in order to understand the bonding between ruthenium and redox-active (non-innocent) ligands and its implication for electrochemical behavior. The Ru atom in the title complex, shows an octahedral coordination. The benzonitrile ligands are in the same plane as the o-benzoquinone diimine ligand. Bond distances for the benzoquinone diimine ring establish a quinone arrangement showing that the highly acidic behavior of the benzonitrile ligands does not have an influence on its arrangement.

AB - A family of ruthenium complexes containing o-benzoquinone diimine (BQDI) and other non-redox active ligands with different electron donor±acceptor behavior was synthesized in order to understand the bonding between ruthenium and redox-active (non-innocent) ligands and its implication for electrochemical behavior. The Ru atom in the title complex, shows an octahedral coordination. The benzonitrile ligands are in the same plane as the o-benzoquinone diimine ligand. Bond distances for the benzoquinone diimine ring establish a quinone arrangement showing that the highly acidic behavior of the benzonitrile ligands does not have an influence on its arrangement.

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U2 - 10.1107/S0108270100009215

DO - 10.1107/S0108270100009215

M3 - Article

AN - SCOPUS:4243435482

VL - 56

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

SN - 0108-2701

IS - 8

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