Aquabis(benzonitrile)(o-benzoquinone diimine)(triphenylphosphine) ruthenium(II) bis(tetrafluoroborate) hydrate

Diego Venegas-Yazigi, A. B P Lever, Alan J. Lough, Andrés Vega, Verónica Paredes-García, Juan Costamagna, Ramoń Latorre

Resultado de la investigación: Contribución a una revistaArtículo

4 Citas (Scopus)

Resumen

A family of ruthenium complexes containing o-benzoquinone diimine (BQDI) and other non-redox active ligands with different electron donor±acceptor behavior was synthesized in order to understand the bonding between ruthenium and redox-active (non-innocent) ligands and its implication for electrochemical behavior. The Ru atom in the title complex, shows an octahedral coordination. The benzonitrile ligands are in the same plane as the o-benzoquinone diimine ligand. Bond distances for the benzoquinone diimine ring establish a quinone arrangement showing that the highly acidic behavior of the benzonitrile ligands does not have an influence on its arrangement.

Idioma originalInglés
PublicaciónActa Crystallographica Section C: Crystal Structure Communications
Volumen56
N.º8
DOI
EstadoPublicada - ago 2000

Áreas temáticas de ASJC Scopus

  • Bioquímica, genética y biología molecular (todo)
  • Medicina (todo)

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