Adsorption essays of palladium in modified silica gel with thiouronium groups: Experimental and theorical studies

Carreño G. Alexander, Schott V. Eduardo, Zárate B. Ximena, Ramiro Arratia-Perez, Carlos Vega De K. Juan, Mardones L. Miguel, M. Manríquez M. Juan, Chávez M. Ivonne

Resultado de la investigación: Article

3 Citas (Scopus)

Resumen

The silylant 3-cloropropyltriethoxysilyl was anchored over silica gel in anhydrous conditions in order to react with thiourea to obtain modified silica gel with thiouronium. The aim to obtain an inorganic support that is able to hijack metals from the VIII group such as palladium. The product was characterized by SBET and FTIR infrared spectroscopy. For the determination of the structure in the modified silica gel NMR spectra of silicon and carbon were preformed in solid state. The coordination form of the modified silica gel to the metal was studied computationally in the context of the DFT theory, using the ADF code. This was a collaborative work with "Fundación Chile" for the recuperation of precious metals from the mining industry.

Idioma originalEnglish
Páginas (desde-hasta)692-696
Número de páginas5
PublicaciónJournal of the Chilean Chemical Society
Volumen56
N.º2
EstadoPublished - 14 sep 2011

Huella dactilar

Silica Gel
Palladium
Adsorption
Metals
Thiourea
Mineral industry
Silicon
Precious metals
Discrete Fourier transforms
Infrared spectroscopy
Carbon
Nuclear magnetic resonance

ASJC Scopus subject areas

  • Chemistry(all)

Citar esto

Alexander, C. G., Eduardo, S. V., Ximena, Z. B., Arratia-Perez, R., Juan, C. V. D. K., Miguel, M. L., ... Ivonne, C. M. (2011). Adsorption essays of palladium in modified silica gel with thiouronium groups: Experimental and theorical studies. Journal of the Chilean Chemical Society, 56(2), 692-696.
Alexander, Carreño G. ; Eduardo, Schott V. ; Ximena, Zárate B. ; Arratia-Perez, Ramiro ; Juan, Carlos Vega De K. ; Miguel, Mardones L. ; Juan, M. Manríquez M. ; Ivonne, Chávez M. / Adsorption essays of palladium in modified silica gel with thiouronium groups : Experimental and theorical studies. En: Journal of the Chilean Chemical Society. 2011 ; Vol. 56, N.º 2. pp. 692-696.
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abstract = "The silylant 3-cloropropyltriethoxysilyl was anchored over silica gel in anhydrous conditions in order to react with thiourea to obtain modified silica gel with thiouronium. The aim to obtain an inorganic support that is able to hijack metals from the VIII group such as palladium. The product was characterized by SBET and FTIR infrared spectroscopy. For the determination of the structure in the modified silica gel NMR spectra of silicon and carbon were preformed in solid state. The coordination form of the modified silica gel to the metal was studied computationally in the context of the DFT theory, using the ADF code. This was a collaborative work with {"}Fundaci{\'o}n Chile{"} for the recuperation of precious metals from the mining industry.",
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Alexander, CG, Eduardo, SV, Ximena, ZB, Arratia-Perez, R, Juan, CVDK, Miguel, ML, Juan, MMM & Ivonne, CM 2011, 'Adsorption essays of palladium in modified silica gel with thiouronium groups: Experimental and theorical studies', Journal of the Chilean Chemical Society, vol. 56, n.º 2, pp. 692-696.

Adsorption essays of palladium in modified silica gel with thiouronium groups : Experimental and theorical studies. / Alexander, Carreño G.; Eduardo, Schott V.; Ximena, Zárate B.; Arratia-Perez, Ramiro; Juan, Carlos Vega De K.; Miguel, Mardones L.; Juan, M. Manríquez M.; Ivonne, Chávez M.

En: Journal of the Chilean Chemical Society, Vol. 56, N.º 2, 14.09.2011, p. 692-696.

Resultado de la investigación: Article

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T1 - Adsorption essays of palladium in modified silica gel with thiouronium groups

T2 - Experimental and theorical studies

AU - Alexander, Carreño G.

AU - Eduardo, Schott V.

AU - Ximena, Zárate B.

AU - Arratia-Perez, Ramiro

AU - Juan, Carlos Vega De K.

AU - Miguel, Mardones L.

AU - Juan, M. Manríquez M.

AU - Ivonne, Chávez M.

PY - 2011/9/14

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AB - The silylant 3-cloropropyltriethoxysilyl was anchored over silica gel in anhydrous conditions in order to react with thiourea to obtain modified silica gel with thiouronium. The aim to obtain an inorganic support that is able to hijack metals from the VIII group such as palladium. The product was characterized by SBET and FTIR infrared spectroscopy. For the determination of the structure in the modified silica gel NMR spectra of silicon and carbon were preformed in solid state. The coordination form of the modified silica gel to the metal was studied computationally in the context of the DFT theory, using the ADF code. This was a collaborative work with "Fundación Chile" for the recuperation of precious metals from the mining industry.

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KW - Functionalization

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