A novel copper cobalt inorganometallic cluster. Synthesis, structure and bonding analysis of Cu32-(CCHCo2 (CO)6)}3

Andrés Vega, Víctor Calvo, Evgenia Spodine, Antonio Zárate, Víctor Fuenzalida, Jean Yves Saillard

Resultado de la investigación: Article

19 Citas (Scopus)

Resumen

The reaction of the organometallic carboxylic acid HOOCCCHCo2(CO)6 with copper(II) methoxide leads to a new inorganometallic cluster; Cu32-(CCHCo2 (CO)6)}3. This cluster has a triangular core of copper(I) centers surrounded by three CCHCo2(CO)6 fragments. The structure of the cluster has short Cu-Cu and Cu-Co distances (average 2.500 and 2.540 Å, respectively). DFT calculations provide a rationalization of the peculiar bonding in this cluster.

Idioma originalEnglish
Páginas (desde-hasta)3389-3395
Número de páginas7
PublicaciónInorganic Chemistry
Volumen41
N.º13
DOI
EstadoPublished - 1 jul 2002

Huella dactilar

Cobalt
Copper
cobalt
copper
Organometallics
synthesis
Carboxylic Acids
Discrete Fourier transforms
carboxylic acids
fragments

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

Citar esto

Vega, Andrés ; Calvo, Víctor ; Spodine, Evgenia ; Zárate, Antonio ; Fuenzalida, Víctor ; Saillard, Jean Yves. / A novel copper cobalt inorganometallic cluster. Synthesis, structure and bonding analysis of Cu32-(CCHCo2 (CO)6)}3 En: Inorganic Chemistry. 2002 ; Vol. 41, N.º 13. pp. 3389-3395.
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abstract = "The reaction of the organometallic carboxylic acid HOOCCCHCo2(CO)6 with copper(II) methoxide leads to a new inorganometallic cluster; Cu3{μ2-(CCHCo2 (CO)6)}3. This cluster has a triangular core of copper(I) centers surrounded by three CCHCo2(CO)6 fragments. The structure of the cluster has short Cu-Cu and Cu-Co distances (average 2.500 and 2.540 {\AA}, respectively). DFT calculations provide a rationalization of the peculiar bonding in this cluster.",
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A novel copper cobalt inorganometallic cluster. Synthesis, structure and bonding analysis of Cu32-(CCHCo2 (CO)6)}3 . / Vega, Andrés; Calvo, Víctor; Spodine, Evgenia; Zárate, Antonio; Fuenzalida, Víctor; Saillard, Jean Yves.

En: Inorganic Chemistry, Vol. 41, N.º 13, 01.07.2002, p. 3389-3395.

Resultado de la investigación: Article

TY - JOUR

T1 - A novel copper cobalt inorganometallic cluster. Synthesis, structure and bonding analysis of Cu3{μ2-(CCHCo2 (CO)6)}3

AU - Vega, Andrés

AU - Calvo, Víctor

AU - Spodine, Evgenia

AU - Zárate, Antonio

AU - Fuenzalida, Víctor

AU - Saillard, Jean Yves

PY - 2002/7/1

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AB - The reaction of the organometallic carboxylic acid HOOCCCHCo2(CO)6 with copper(II) methoxide leads to a new inorganometallic cluster; Cu3{μ2-(CCHCo2 (CO)6)}3. This cluster has a triangular core of copper(I) centers surrounded by three CCHCo2(CO)6 fragments. The structure of the cluster has short Cu-Cu and Cu-Co distances (average 2.500 and 2.540 Å, respectively). DFT calculations provide a rationalization of the peculiar bonding in this cluster.

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