A novel biomimetic synthesis of 5-oxogermacranolides. A conformational study

Victor Kesternich, Leonel Vera, Rolando Martinez

Resultado de la investigación: Article

Resumen

The biomimetic synthesis of a 5-oxogermacranolide from eudesmanolide skeleton is reported as a preliminary study for the first time. The synthesis of two 5-oxogermacranolides from two cis-fused eudesmanolides, gallicadiol and isogallicadiol, was carried out following a new route via a fragmentation reaction of known stereoselectivity. The conformational study of the products was done.

Idioma originalEnglish
PublicaciónBoletin de la Sociedad Chilena de Quimica
Volumen44
N.º2
EstadoPublished - 1 dic 1999

Huella dactilar

Biomimetics
Stereoselectivity
gallicadiol
eudesmanolide

ASJC Scopus subject areas

  • Chemistry(all)

Citar esto

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abstract = "The biomimetic synthesis of a 5-oxogermacranolide from eudesmanolide skeleton is reported as a preliminary study for the first time. The synthesis of two 5-oxogermacranolides from two cis-fused eudesmanolides, gallicadiol and isogallicadiol, was carried out following a new route via a fragmentation reaction of known stereoselectivity. The conformational study of the products was done.",
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A novel biomimetic synthesis of 5-oxogermacranolides. A conformational study. / Kesternich, Victor; Vera, Leonel; Martinez, Rolando.

En: Boletin de la Sociedad Chilena de Quimica, Vol. 44, N.º 2, 01.12.1999.

Resultado de la investigación: Article

TY - JOUR

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AU - Vera, Leonel

AU - Martinez, Rolando

PY - 1999/12/1

Y1 - 1999/12/1

N2 - The biomimetic synthesis of a 5-oxogermacranolide from eudesmanolide skeleton is reported as a preliminary study for the first time. The synthesis of two 5-oxogermacranolides from two cis-fused eudesmanolides, gallicadiol and isogallicadiol, was carried out following a new route via a fragmentation reaction of known stereoselectivity. The conformational study of the products was done.

AB - The biomimetic synthesis of a 5-oxogermacranolide from eudesmanolide skeleton is reported as a preliminary study for the first time. The synthesis of two 5-oxogermacranolides from two cis-fused eudesmanolides, gallicadiol and isogallicadiol, was carried out following a new route via a fragmentation reaction of known stereoselectivity. The conformational study of the products was done.

KW - Biomimetic synthesis

KW - Germacranolides

KW - Sesquiterpene lactones

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JF - Journal of the Chilean Chemical Society

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