A new hybrid organic-inorganic chain: [(Phen)Cu-μ-(κ2 O:O′-VP2O10H3)2-Cu(phen)] n

Diego Venegas-Yazigi; Andres Vega; Karen Valdes De La Barra; Marianela Saldias; Eric Le Fur

doi:10.1107/S0108270112026005

A new hybrid organic-inorganic chain: [(Phen)Cu-μ-(κ² O:O′-VP₂O₁₀H₃)₂-Cu(phen)] _n

Diego Venegas-Yazigi, Andres Vega, Karen Valdes De La Barra, Marianela Saldias, Eric Le Fur

Facultad Ciencias Exactas

Resultado de la investigación: Contribución a una revista › Artículo › revisión exhaustiva

1 Cita (Scopus)

Resumen

The structure of the title compound, poly[(dihydrogen-phosphato-κO) (μ₃-hydrogenphosphato)di-μ-xido-(1,10-phenanthroline)copper(II) vanadium(V)], [CuV(HPO₄)(H₂PO₄)O ₂(C₁₂H₈N₂)]_n , is defined by [(phen)Cu-μ-(κ² O:O′-VP₂O ₁₀H₃)₂-Cu(phen)] units (phen is 1,10-phenanthroline), which are connected to neighbouring units through vanadyl bridges. Neighbouring chains have no covalent bonds between them, although they inter-digitate through the phen groups via π-π inter-actions.

Idioma original	Inglés
Páginas (desde-hasta)	m200-m202
Publicación	Acta Crystallographica Section C: Crystal Structure Communications
Volumen	68
N.º	7
DOI	https://doi.org/10.1107/S0108270112026005
Estado	Publicada - jul. 2012

Áreas temáticas de ASJC Scopus

Bioquímica, genética y biología molecular (todo)

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10.1107/S0108270112026005

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title = "A new hybrid organic-inorganic chain: [(Phen)Cu-μ-(κ2 O:O′-VP2O10H3)2-Cu(phen)] n",

abstract = "The structure of the title compound, poly[(dihydrogen-phosphato-κO) (μ3-hydrogenphosphato)di-μ-xido-(1,10-phenanthroline)copper(II) vanadium(V)], [CuV(HPO4)(H2PO4)O 2(C12H8N2)]n , is defined by [(phen)Cu-μ-(κ2 O:O′-VP2O 10H3)2-Cu(phen)] units (phen is 1,10-phenanthroline), which are connected to neighbouring units through vanadyl bridges. Neighbouring chains have no covalent bonds between them, although they inter-digitate through the phen groups via π-π inter-actions.",

author = "Diego Venegas-Yazigi and Andres Vega and {Valdes De La Barra}, Karen and Marianela Saldias and {Le Fur}, Eric",

year = "2012",

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AU - Valdes De La Barra, Karen

AU - Saldias, Marianela

AU - Le Fur, Eric

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AB - The structure of the title compound, poly[(dihydrogen-phosphato-κO) (μ3-hydrogenphosphato)di-μ-xido-(1,10-phenanthroline)copper(II) vanadium(V)], [CuV(HPO4)(H2PO4)O 2(C12H8N2)]n , is defined by [(phen)Cu-μ-(κ2 O:O′-VP2O 10H3)2-Cu(phen)] units (phen is 1,10-phenanthroline), which are connected to neighbouring units through vanadyl bridges. Neighbouring chains have no covalent bonds between them, although they inter-digitate through the phen groups via π-π inter-actions.

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