TY - JOUR
T1 - A new hybrid organic-inorganic chain
T2 - [(Phen)Cu-μ-(κ2 O:O′-VP2O10H3)2-Cu(phen)] n
AU - Venegas-Yazigi, Diego
AU - Vega, Andres
AU - Valdes De La Barra, Karen
AU - Saldias, Marianela
AU - Le Fur, Eric
N1 - Copyright:
Copyright 2013 Elsevier B.V., All rights reserved.
PY - 2012/7
Y1 - 2012/7
N2 - The structure of the title compound, poly[(dihydrogen-phosphato-κO) (μ3-hydrogenphosphato)di-μ-xido-(1,10-phenanthroline)copper(II) vanadium(V)], [CuV(HPO4)(H2PO4)O 2(C12H8N2)]n , is defined by [(phen)Cu-μ-(κ2 O:O′-VP2O 10H3)2-Cu(phen)] units (phen is 1,10-phenanthroline), which are connected to neighbouring units through vanadyl bridges. Neighbouring chains have no covalent bonds between them, although they inter-digitate through the phen groups via π-π inter-actions.
AB - The structure of the title compound, poly[(dihydrogen-phosphato-κO) (μ3-hydrogenphosphato)di-μ-xido-(1,10-phenanthroline)copper(II) vanadium(V)], [CuV(HPO4)(H2PO4)O 2(C12H8N2)]n , is defined by [(phen)Cu-μ-(κ2 O:O′-VP2O 10H3)2-Cu(phen)] units (phen is 1,10-phenanthroline), which are connected to neighbouring units through vanadyl bridges. Neighbouring chains have no covalent bonds between them, although they inter-digitate through the phen groups via π-π inter-actions.
UR - http://www.scopus.com/inward/record.url?scp=84863512225&partnerID=8YFLogxK
U2 - 10.1107/S0108270112026005
DO - 10.1107/S0108270112026005
M3 - Article
C2 - 22763689
AN - SCOPUS:84863512225
VL - 68
SP - m200-m202
JO - Acta Crystallographica Section C: Crystal Structure Communications
JF - Acta Crystallographica Section C: Crystal Structure Communications
SN - 0108-2701
IS - 7
ER -