A new heterobimetallic manganese-rhodium carbonyl complex derived from partially alkylated s-indacene

César Morales-Verdejo, Luciano Oehninger, Iván Martínez-Díaz, Desmond Mac-Leod Carey, Ramiro Arratia-Pérez, Ivonne Chávez, Juan Manuel Manríquez

Resultado de la investigación: Article

9 Citas (Scopus)

Resumen

This work describes the synthesis and characterization by means of 1H, 13C NMR and FT-IR spectroscopies of new heterobinuclear carbonylated complex derived from partially alkylated s-indacene. The heterobimetallic complex [(CO) 3Mn(2,6-diethyl-4,8- dimethyl-s-indaceneiide)Rh(COD)] 1 was synthesized from the monometallic specie [(CO) 3Mn(2,6-diethyl-4,8-dimethyl-1-hydroindacenide)] and [Rh(μ-Cl)(COD)] 2. Secondly, its respective carbonylated complex [(CO) 3Mn(2,6-diethyl-4,8-dimethyl-s-indaceneiide)Rh(CO) 2] 2 was obtained by under an atmosphere of carbon monoxide in hexanes. Theoretical calculations of these two compounds were carried out to gain further understanding of these novel molecular systems.

Idioma originalEnglish
Páginas (desde-hasta)132-139
Número de páginas8
PublicaciónInorganica Chimica Acta
Volumen394
DOI
EstadoPublished - 1 ene 2013

Huella dactilar

Rhodium
crack opening displacement
Hexanes
Carbon Monoxide
Manganese
Hexane
rhodium
Carbon monoxide
manganese
Infrared spectroscopy
Nuclear magnetic resonance
carbon monoxide
atmospheres
nuclear magnetic resonance
synthesis
spectroscopy

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

Citar esto

Morales-Verdejo, C., Oehninger, L., Martínez-Díaz, I., Mac-Leod Carey, D., Arratia-Pérez, R., Chávez, I., & Manríquez, J. M. (2013). A new heterobimetallic manganese-rhodium carbonyl complex derived from partially alkylated s-indacene. Inorganica Chimica Acta, 394, 132-139. https://doi.org/10.1016/j.ica.2012.08.010
Morales-Verdejo, César ; Oehninger, Luciano ; Martínez-Díaz, Iván ; Mac-Leod Carey, Desmond ; Arratia-Pérez, Ramiro ; Chávez, Ivonne ; Manríquez, Juan Manuel. / A new heterobimetallic manganese-rhodium carbonyl complex derived from partially alkylated s-indacene. En: Inorganica Chimica Acta. 2013 ; Vol. 394. pp. 132-139.
@article{f52f50c4263d48ae815400c3a51c87e9,
title = "A new heterobimetallic manganese-rhodium carbonyl complex derived from partially alkylated s-indacene",
abstract = "This work describes the synthesis and characterization by means of 1H, 13C NMR and FT-IR spectroscopies of new heterobinuclear carbonylated complex derived from partially alkylated s-indacene. The heterobimetallic complex [(CO) 3Mn(2,6-diethyl-4,8- dimethyl-s-indaceneiide)Rh(COD)] 1 was synthesized from the monometallic specie [(CO) 3Mn(2,6-diethyl-4,8-dimethyl-1-hydroindacenide)] and [Rh(μ-Cl)(COD)] 2. Secondly, its respective carbonylated complex [(CO) 3Mn(2,6-diethyl-4,8-dimethyl-s-indaceneiide)Rh(CO) 2] 2 was obtained by under an atmosphere of carbon monoxide in hexanes. Theoretical calculations of these two compounds were carried out to gain further understanding of these novel molecular systems.",
keywords = "DFT, Heterobimetallic complexes, Organometallic",
author = "C{\'e}sar Morales-Verdejo and Luciano Oehninger and Iv{\'a}n Mart{\'i}nez-D{\'i}az and {Mac-Leod Carey}, Desmond and Ramiro Arratia-P{\'e}rez and Ivonne Ch{\'a}vez and Manr{\'i}quez, {Juan Manuel}",
year = "2013",
month = "1",
day = "1",
doi = "10.1016/j.ica.2012.08.010",
language = "English",
volume = "394",
pages = "132--139",
journal = "Inorganica Chimica Acta",
issn = "0020-1693",
publisher = "Elsevier BV",

}

Morales-Verdejo, C, Oehninger, L, Martínez-Díaz, I, Mac-Leod Carey, D, Arratia-Pérez, R, Chávez, I & Manríquez, JM 2013, 'A new heterobimetallic manganese-rhodium carbonyl complex derived from partially alkylated s-indacene', Inorganica Chimica Acta, vol. 394, pp. 132-139. https://doi.org/10.1016/j.ica.2012.08.010

A new heterobimetallic manganese-rhodium carbonyl complex derived from partially alkylated s-indacene. / Morales-Verdejo, César; Oehninger, Luciano; Martínez-Díaz, Iván; Mac-Leod Carey, Desmond; Arratia-Pérez, Ramiro; Chávez, Ivonne; Manríquez, Juan Manuel.

En: Inorganica Chimica Acta, Vol. 394, 01.01.2013, p. 132-139.

Resultado de la investigación: Article

TY - JOUR

T1 - A new heterobimetallic manganese-rhodium carbonyl complex derived from partially alkylated s-indacene

AU - Morales-Verdejo, César

AU - Oehninger, Luciano

AU - Martínez-Díaz, Iván

AU - Mac-Leod Carey, Desmond

AU - Arratia-Pérez, Ramiro

AU - Chávez, Ivonne

AU - Manríquez, Juan Manuel

PY - 2013/1/1

Y1 - 2013/1/1

N2 - This work describes the synthesis and characterization by means of 1H, 13C NMR and FT-IR spectroscopies of new heterobinuclear carbonylated complex derived from partially alkylated s-indacene. The heterobimetallic complex [(CO) 3Mn(2,6-diethyl-4,8- dimethyl-s-indaceneiide)Rh(COD)] 1 was synthesized from the monometallic specie [(CO) 3Mn(2,6-diethyl-4,8-dimethyl-1-hydroindacenide)] and [Rh(μ-Cl)(COD)] 2. Secondly, its respective carbonylated complex [(CO) 3Mn(2,6-diethyl-4,8-dimethyl-s-indaceneiide)Rh(CO) 2] 2 was obtained by under an atmosphere of carbon monoxide in hexanes. Theoretical calculations of these two compounds were carried out to gain further understanding of these novel molecular systems.

AB - This work describes the synthesis and characterization by means of 1H, 13C NMR and FT-IR spectroscopies of new heterobinuclear carbonylated complex derived from partially alkylated s-indacene. The heterobimetallic complex [(CO) 3Mn(2,6-diethyl-4,8- dimethyl-s-indaceneiide)Rh(COD)] 1 was synthesized from the monometallic specie [(CO) 3Mn(2,6-diethyl-4,8-dimethyl-1-hydroindacenide)] and [Rh(μ-Cl)(COD)] 2. Secondly, its respective carbonylated complex [(CO) 3Mn(2,6-diethyl-4,8-dimethyl-s-indaceneiide)Rh(CO) 2] 2 was obtained by under an atmosphere of carbon monoxide in hexanes. Theoretical calculations of these two compounds were carried out to gain further understanding of these novel molecular systems.

KW - DFT

KW - Heterobimetallic complexes

KW - Organometallic

UR - http://www.scopus.com/inward/record.url?scp=84866696986&partnerID=8YFLogxK

U2 - 10.1016/j.ica.2012.08.010

DO - 10.1016/j.ica.2012.08.010

M3 - Article

AN - SCOPUS:84866696986

VL - 394

SP - 132

EP - 139

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

SN - 0020-1693

ER -