A new heterobimetallic manganese-rhodium carbonyl complex derived from partially alkylated s-indacene

César Morales-Verdejo, Luciano Oehninger, Iván Martínez-Díaz, Desmond Mac-Leod Carey, Ramiro Arratia-Pérez, Ivonne Chávez, Juan Manuel Manríquez

Resultado de la investigación: Contribución a una revistaArtículorevisión exhaustiva

10 Citas (Scopus)

Resumen

This work describes the synthesis and characterization by means of 1H, 13C NMR and FT-IR spectroscopies of new heterobinuclear carbonylated complex derived from partially alkylated s-indacene. The heterobimetallic complex [(CO)3Mn(2,6-diethyl-4,8- dimethyl-s-indaceneiide)Rh(COD)] 1 was synthesized from the monometallic specie [(CO)3Mn(2,6-diethyl-4,8-dimethyl-1-hydroindacenide)] and [Rh(μ-Cl)(COD)]2. Secondly, its respective carbonylated complex [(CO)3Mn(2,6-diethyl-4,8-dimethyl-s-indaceneiide)Rh(CO)2] 2 was obtained by under an atmosphere of carbon monoxide in hexanes. Theoretical calculations of these two compounds were carried out to gain further understanding of these novel molecular systems.

Idioma originalInglés
Páginas (desde-hasta)132-139
Número de páginas8
PublicaciónInorganica Chimica Acta
Volumen394
DOI
EstadoPublicada - 1 ene 2013

Áreas temáticas de ASJC Scopus

  • Química física y teórica
  • Química inorgánica
  • Química de los materiales

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