A dinuclear copper(II) complex involving monoatomic O-carboxylate bridging and Cu-S(thioether) bonds: [Cu(tda)(phen)]2 · H2tda (tda=thiodiacetate, phen=phenanthroline)

Ricardo Baggio, Maria T. Garland, Jorge Manzur, Octavio Peña, Mireille Perec, Evgenia Spodine, Andrés Vega

Resultado de la investigación: Article

34 Citas (Scopus)

Resumen

The dinuclear copper(II) complex [Cu(tda)(phen)]2 · H2tda (tda=thiodiacetate; phen=1,10-phenanthroline) has been prepared and characterized by single crystal X-ray diffraction. The dimer shows a strictly planar CuO2Cu ring involving monoatomic O-carboxylates in the bridging mode with each copper weakly bonded to a thioether in a distorted octahedral N2O3S environment. Variable temperature susceptibility measurements reveal the existence of weak ferromagnetic interactions within the dimer, mediated by the oxygen atoms of the bridge.

Idioma originalEnglish
Páginas (desde-hasta)74-79
Número de páginas6
PublicaciónInorganica Chimica Acta
Volumen286
N.º1
DOI
EstadoPublished - 2 mar 1999

Huella dactilar

Phenanthrolines
Sulfides
Dimers
carboxylates
Copper
dimers
copper
oxygen atoms
Single crystals
Oxygen
magnetic permeability
X ray diffraction
Atoms
rings
single crystals
diffraction
x rays
interactions
Temperature
temperature

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

Citar esto

Baggio, Ricardo ; Garland, Maria T. ; Manzur, Jorge ; Peña, Octavio ; Perec, Mireille ; Spodine, Evgenia ; Vega, Andrés. / A dinuclear copper(II) complex involving monoatomic O-carboxylate bridging and Cu-S(thioether) bonds : [Cu(tda)(phen)]2 · H2tda (tda=thiodiacetate, phen=phenanthroline). En: Inorganica Chimica Acta. 1999 ; Vol. 286, N.º 1. pp. 74-79.
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abstract = "The dinuclear copper(II) complex [Cu(tda)(phen)]2 · H2tda (tda=thiodiacetate; phen=1,10-phenanthroline) has been prepared and characterized by single crystal X-ray diffraction. The dimer shows a strictly planar CuO2Cu ring involving monoatomic O-carboxylates in the bridging mode with each copper weakly bonded to a thioether in a distorted octahedral N2O3S environment. Variable temperature susceptibility measurements reveal the existence of weak ferromagnetic interactions within the dimer, mediated by the oxygen atoms of the bridge.",
keywords = "Carboxylate complexes, Copper complexes, Crystal structures, Dinuclear complexes, Thioether complexes",
author = "Ricardo Baggio and Garland, {Maria T.} and Jorge Manzur and Octavio Pe{\~n}a and Mireille Perec and Evgenia Spodine and Andr{\'e}s Vega",
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Baggio, R, Garland, MT, Manzur, J, Peña, O, Perec, M, Spodine, E & Vega, A 1999, 'A dinuclear copper(II) complex involving monoatomic O-carboxylate bridging and Cu-S(thioether) bonds: [Cu(tda)(phen)]2 · H2tda (tda=thiodiacetate, phen=phenanthroline)', Inorganica Chimica Acta, vol. 286, n.º 1, pp. 74-79. https://doi.org/10.1016/S0020-1693(98)00374-0

A dinuclear copper(II) complex involving monoatomic O-carboxylate bridging and Cu-S(thioether) bonds : [Cu(tda)(phen)]2 · H2tda (tda=thiodiacetate, phen=phenanthroline). / Baggio, Ricardo; Garland, Maria T.; Manzur, Jorge; Peña, Octavio; Perec, Mireille; Spodine, Evgenia; Vega, Andrés.

En: Inorganica Chimica Acta, Vol. 286, N.º 1, 02.03.1999, p. 74-79.

Resultado de la investigación: Article

TY - JOUR

T1 - A dinuclear copper(II) complex involving monoatomic O-carboxylate bridging and Cu-S(thioether) bonds

T2 - [Cu(tda)(phen)]2 · H2tda (tda=thiodiacetate, phen=phenanthroline)

AU - Baggio, Ricardo

AU - Garland, Maria T.

AU - Manzur, Jorge

AU - Peña, Octavio

AU - Perec, Mireille

AU - Spodine, Evgenia

AU - Vega, Andrés

PY - 1999/3/2

Y1 - 1999/3/2

N2 - The dinuclear copper(II) complex [Cu(tda)(phen)]2 · H2tda (tda=thiodiacetate; phen=1,10-phenanthroline) has been prepared and characterized by single crystal X-ray diffraction. The dimer shows a strictly planar CuO2Cu ring involving monoatomic O-carboxylates in the bridging mode with each copper weakly bonded to a thioether in a distorted octahedral N2O3S environment. Variable temperature susceptibility measurements reveal the existence of weak ferromagnetic interactions within the dimer, mediated by the oxygen atoms of the bridge.

AB - The dinuclear copper(II) complex [Cu(tda)(phen)]2 · H2tda (tda=thiodiacetate; phen=1,10-phenanthroline) has been prepared and characterized by single crystal X-ray diffraction. The dimer shows a strictly planar CuO2Cu ring involving monoatomic O-carboxylates in the bridging mode with each copper weakly bonded to a thioether in a distorted octahedral N2O3S environment. Variable temperature susceptibility measurements reveal the existence of weak ferromagnetic interactions within the dimer, mediated by the oxygen atoms of the bridge.

KW - Carboxylate complexes

KW - Copper complexes

KW - Crystal structures

KW - Dinuclear complexes

KW - Thioether complexes

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U2 - 10.1016/S0020-1693(98)00374-0

DO - 10.1016/S0020-1693(98)00374-0

M3 - Article

AN - SCOPUS:0013408848

VL - 286

SP - 74

EP - 79

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

SN - 0020-1693

IS - 1

ER -

Baggio R, Garland MT, Manzur J, Peña O, Perec M, Spodine E y otros. A dinuclear copper(II) complex involving monoatomic O-carboxylate bridging and Cu-S(thioether) bonds: [Cu(tda)(phen)]2 · H2tda (tda=thiodiacetate, phen=phenanthroline). Inorganica Chimica Acta. 1999 mar 2;286(1):74-79. https://doi.org/10.1016/S0020-1693(98)00374-0

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