Resumen
The dinuclear copper(II) complex [Cu(tda)(phen)]2 · H2tda (tda=thiodiacetate; phen=1,10-phenanthroline) has been prepared and characterized by single crystal X-ray diffraction. The dimer shows a strictly planar CuO2Cu ring involving monoatomic O-carboxylates in the bridging mode with each copper weakly bonded to a thioether in a distorted octahedral N2O3S environment. Variable temperature susceptibility measurements reveal the existence of weak ferromagnetic interactions within the dimer, mediated by the oxygen atoms of the bridge.
Idioma original | Inglés |
---|---|
Páginas (desde-hasta) | 74-79 |
Número de páginas | 6 |
Publicación | Inorganica Chimica Acta |
Volumen | 286 |
N.º | 1 |
DOI | |
Estado | Publicada - 2 mar. 1999 |
Áreas temáticas de ASJC Scopus
- Química física y teórica
- Química inorgánica
- Química de los materiales