TY - JOUR
T1 - (2S,RS)-6-phenyl-1-(p-tolylsulfinyl)-hexa-3(E),5(E)-dien-2-ol
AU - Donoso-Tauda, Oscar
AU - Escobar, Carlos A.
AU - Araya-Maturana, Ramiro
AU - Vega, Andres
N1 - Copyright:
Copyright 2009 Elsevier B.V., All rights reserved.
PY - 2006/10
Y1 - 2006/10
N2 - The molecule of the title compound, C19H20O 2S, corresponds to a chiral sulfinyldienol with two stereogenic centres, viz. the C atom susbtituted by the hydroxy group and the sulflnyl S atom. The molecule displays a V-shape in the solid state. The dihedral angle defined by the least-squares planes of the aromatic rings is 72.9 (1)°. The packing pattern exhibits the following intermolecular hydrogen bonds: one O-H⋯O [H⋯O = 1.98 Å, O⋯O = 2.785 (4) Å and O-H⋯O = 166°] and two C-H⋯O [H⋯O = 2.58 and 2.60 Å, C⋯O = 3.527(5) and 3.347 (5) Å, and C-H⋯O = 164 and 134°]. These define a chain along b.
AB - The molecule of the title compound, C19H20O 2S, corresponds to a chiral sulfinyldienol with two stereogenic centres, viz. the C atom susbtituted by the hydroxy group and the sulflnyl S atom. The molecule displays a V-shape in the solid state. The dihedral angle defined by the least-squares planes of the aromatic rings is 72.9 (1)°. The packing pattern exhibits the following intermolecular hydrogen bonds: one O-H⋯O [H⋯O = 1.98 Å, O⋯O = 2.785 (4) Å and O-H⋯O = 166°] and two C-H⋯O [H⋯O = 2.58 and 2.60 Å, C⋯O = 3.527(5) and 3.347 (5) Å, and C-H⋯O = 164 and 134°]. These define a chain along b.
UR - http://www.scopus.com/inward/record.url?scp=33749468906&partnerID=8YFLogxK
U2 - 10.1107/S0108270106036171
DO - 10.1107/S0108270106036171
M3 - Article
C2 - 17008755
AN - SCOPUS:33749468906
VL - 62
SP - o631-o632
JO - Acta Crystallographica Section C: Crystal Structure Communications
JF - Acta Crystallographica Section C: Crystal Structure Communications
SN - 0108-2701
IS - 10
ER -