TY - JOUR
T1 - (2,2′-biquinoline-κ2 N,N′)bis-(nitrato- κ2 O,O′)copper(II)
AU - Moreno, Yanko
AU - Salgado, Yimmy
AU - Garland, María Teresa
AU - Baggio, Ricardo
PY - 2007/10/13
Y1 - 2007/10/13
N2 - In the title monomer, [Cu(NO3)2(C18H12N2)], the six-coordinated Cu II atom lies on a twofold axis which bisects one of the ligands (a chelating biquinoline) and duplicates the remaining ligand, a chelating nitrate. The latter binds in a very asymmetric way, consistent with a Jahn-Teller distortion in the coordination polyhedron which, due to the triple chelation, is extremely distorted and difficult to describe in terms of any regular model.
AB - In the title monomer, [Cu(NO3)2(C18H12N2)], the six-coordinated Cu II atom lies on a twofold axis which bisects one of the ligands (a chelating biquinoline) and duplicates the remaining ligand, a chelating nitrate. The latter binds in a very asymmetric way, consistent with a Jahn-Teller distortion in the coordination polyhedron which, due to the triple chelation, is extremely distorted and difficult to describe in terms of any regular model.
UR - http://www.scopus.com/inward/record.url?scp=35948983004&partnerID=8YFLogxK
U2 - 10.1107/S0108270107046513
DO - 10.1107/S0108270107046513
M3 - Article
C2 - 17989459
AN - SCOPUS:35948983004
VL - 63
SP - m487-m489
JO - Acta Crystallographica Section C: Crystal Structure Communications
JF - Acta Crystallographica Section C: Crystal Structure Communications
SN - 0108-2701
IS - 11
ER -