(2,2′-biquinoline-κ2 N,N′)bis-(nitrato- κ2 O,O′)copper(II)

Yanko Moreno; Yimmy Salgado; María Teresa Garland; Ricardo Baggio

doi:10.1107/S0108270107046513

(2,2′-biquinoline-κ² N,N′)bis-(nitrato- κ² O,O′)copper(II)

Yanko Moreno, Yimmy Salgado, María Teresa Garland, Ricardo Baggio

Facultad Ciencias Exactas

Resultado de la investigación: Contribución a una revista › Artículo › revisión exhaustiva

3 Citas (Scopus)

Resumen

In the title monomer, [Cu(NO3)2(C18H12N2)], the six-coordinated Cu ^II atom lies on a twofold axis which bisects one of the ligands (a chelating biquinoline) and duplicates the remaining ligand, a chelating nitrate. The latter binds in a very asymmetric way, consistent with a Jahn-Teller distortion in the coordination polyhedron which, due to the triple chelation, is extremely distorted and difficult to describe in terms of any regular model.

Idioma original	Inglés
Páginas (desde-hasta)	m487-m489
Publicación	Acta Crystallographica Section C: Crystal Structure Communications
Volumen	63
N.º	11
DOI	https://doi.org/10.1107/S0108270107046513
Estado	Publicada - 13 oct 2007

Áreas temáticas de ASJC Scopus

Bioquímica, genética y biología molecular (todo)

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10.1107/S0108270107046513

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abstract = "In the title monomer, [Cu(NO3)2(C18H12N2)], the six-coordinated Cu II atom lies on a twofold axis which bisects one of the ligands (a chelating biquinoline) and duplicates the remaining ligand, a chelating nitrate. The latter binds in a very asymmetric way, consistent with a Jahn-Teller distortion in the coordination polyhedron which, due to the triple chelation, is extremely distorted and difficult to describe in terms of any regular model.",

author = "Yanko Moreno and Yimmy Salgado and Garland, {Mar{\'i}a Teresa} and Ricardo Baggio",

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T1 - (2,2′-biquinoline-κ2 N,N′)bis-(nitrato- κ2 O,O′)copper(II)

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AU - Salgado, Yimmy

AU - Garland, María Teresa

AU - Baggio, Ricardo

PY - 2007/10/13

Y1 - 2007/10/13

N2 - In the title monomer, [Cu(NO3)2(C18H12N2)], the six-coordinated Cu II atom lies on a twofold axis which bisects one of the ligands (a chelating biquinoline) and duplicates the remaining ligand, a chelating nitrate. The latter binds in a very asymmetric way, consistent with a Jahn-Teller distortion in the coordination polyhedron which, due to the triple chelation, is extremely distorted and difficult to describe in terms of any regular model.

AB - In the title monomer, [Cu(NO3)2(C18H12N2)], the six-coordinated Cu II atom lies on a twofold axis which bisects one of the ligands (a chelating biquinoline) and duplicates the remaining ligand, a chelating nitrate. The latter binds in a very asymmetric way, consistent with a Jahn-Teller distortion in the coordination polyhedron which, due to the triple chelation, is extremely distorted and difficult to describe in terms of any regular model.

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JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

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