(2,2′-biquinoline-κ2 N,N′)bis-(nitrato- κ2 O,O′)copper(II)

Yanko Moreno; Yimmy Salgado; María Teresa Garland; Ricardo Baggio

doi:10.1107/S0108270107046513

(2,2′-biquinoline-κ² N,N′)bis-(nitrato- κ² O,O′)copper(II)

Yanko Moreno, Yimmy Salgado, María Teresa Garland, Ricardo Baggio

Facultad Ciencias Exactas

Resultado de la investigación: Contribución a una revista › Artículo › revisión exhaustiva

3 Citas (Scopus)

Resumen

In the title monomer, [Cu(NO3)2(C18H12N2)], the six-coordinated Cu ^II atom lies on a twofold axis which bisects one of the ligands (a chelating biquinoline) and duplicates the remaining ligand, a chelating nitrate. The latter binds in a very asymmetric way, consistent with a Jahn-Teller distortion in the coordination polyhedron which, due to the triple chelation, is extremely distorted and difficult to describe in terms of any regular model.

Idioma original	Inglés
Páginas (desde-hasta)	m487-m489
Publicación	Acta Crystallographica Section C: Crystal Structure Communications
Volumen	63
N.º	11
DOI	https://doi.org/10.1107/S0108270107046513
Estado	Publicada - 13 oct. 2007

Áreas temáticas de ASJC Scopus

Bioquímica, genética y biología molecular (todo)

Acceder al documento

10.1107/S0108270107046513

Otros archivos y enlaces

Enlace a la publicación en Scopus

Citar esto

@article{d625df5eb4144425b69e096c31dc0922,

title = "(2,2′-biquinoline-κ2 N,N′)bis-(nitrato- κ2 O,O′)copper(II)",

abstract = "In the title monomer, [Cu(NO3)2(C18H12N2)], the six-coordinated Cu II atom lies on a twofold axis which bisects one of the ligands (a chelating biquinoline) and duplicates the remaining ligand, a chelating nitrate. The latter binds in a very asymmetric way, consistent with a Jahn-Teller distortion in the coordination polyhedron which, due to the triple chelation, is extremely distorted and difficult to describe in terms of any regular model.",

author = "Yanko Moreno and Yimmy Salgado and Garland, {Mar{\'i}a Teresa} and Ricardo Baggio",

year = "2007",

month = oct,

day = "13",

doi = "10.1107/S0108270107046513",

language = "English",

volume = "63",

pages = "m487--m489",

journal = "Acta Crystallographica Section C: Crystal Structure Communications",

issn = "0108-2701",

publisher = "International Union of Crystallography",

number = "11",

}

TY - JOUR

T1 - (2,2′-biquinoline-κ2 N,N′)bis-(nitrato- κ2 O,O′)copper(II)

AU - Moreno, Yanko

AU - Salgado, Yimmy

AU - Garland, María Teresa

AU - Baggio, Ricardo

PY - 2007/10/13

Y1 - 2007/10/13

N2 - In the title monomer, [Cu(NO3)2(C18H12N2)], the six-coordinated Cu II atom lies on a twofold axis which bisects one of the ligands (a chelating biquinoline) and duplicates the remaining ligand, a chelating nitrate. The latter binds in a very asymmetric way, consistent with a Jahn-Teller distortion in the coordination polyhedron which, due to the triple chelation, is extremely distorted and difficult to describe in terms of any regular model.

AB - In the title monomer, [Cu(NO3)2(C18H12N2)], the six-coordinated Cu II atom lies on a twofold axis which bisects one of the ligands (a chelating biquinoline) and duplicates the remaining ligand, a chelating nitrate. The latter binds in a very asymmetric way, consistent with a Jahn-Teller distortion in the coordination polyhedron which, due to the triple chelation, is extremely distorted and difficult to describe in terms of any regular model.

UR - http://www.scopus.com/inward/record.url?scp=35948983004&partnerID=8YFLogxK

U2 - 10.1107/S0108270107046513

DO - 10.1107/S0108270107046513

M3 - Article

C2 - 17989459

AN - SCOPUS:35948983004

VL - 63

SP - m487-m489

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

SN - 0108-2701

IS - 11

ER -