Triaryl-1,3,5-triazinane-2,4,6-triones functionalized with electron-rich Fe(ii) and Ru(ii) acetylide complexes: New organometallic octupoles with large hyperpolarizabilities

Alexander Trujillo, Romain Veillard, Gilles Argouarch, Thierry Roisnel, Anu Singh, Isabelle Ledoux, Frédéric Paul

Research output: Contribution to journalArticlepeer-review

13 Citations (Scopus)

Abstract

The synthesis and study of a series of trinuclear organometallic triaryl-1,3,5-triazinane-2,4,6-triones functionalized by d 6- transition metal acetylides complexes at their periphery are reported. Remarkably large hyperpolarizabilities, far superior to those of related purely organic derivatives, are measured by hyper-Rayleigh scattering (HRS) for these new octupolar chromophores.

Original languageEnglish
Pages (from-to)7454-7456
Number of pages3
JournalDalton Transactions
Volume41
Issue number25
DOIs
Publication statusPublished - 7 Jul 2012

ASJC Scopus subject areas

  • Inorganic Chemistry

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