The first ReI organometallic complex with an organoimido-polyoxometalate ligand

Patricio Hermosilla-Ibáñez, Kerry Wrighton-Araneda, Gaspar Prado, Verónica Paredes-García, Nancy Pizarro, Andrés Vega, Diego Venegas-Yazigi

Research output: Contribution to journalArticlepeer-review

5 Citations (Scopus)

Abstract

The spectroscopic, electrochemical and photophysical properties of the first ReI organometallic organoimido-polyoxometalate complex [n-Bu4N][Mo6O18NC6H4-CH2-N3C2H2-Re-phen(CO)3] compared with all fragments are reported. The UV-Vis spectra are analysed using experimental and theoretical tools. In contrast to the reported studies in the literature, our results show that a new more intense band is present in the spectra of the hybrid ligand obscuring the intra-polyanion charge transfer. The electrochemical results show that the strong acceptor character of the polyoxometalate fragment is quenched by the condensation of the phenyl-triazole molecule.

Original languageEnglish
Pages (from-to)8611-8620
Number of pages10
JournalDalton Transactions
Volume46
Issue number26
DOIs
Publication statusPublished - 2017

ASJC Scopus subject areas

  • Inorganic Chemistry

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