Synthesis, structure and oxidation studies of a dinuclear copper(I)-copper(II) complex: [Cu2(bdpdz)2](ClO4)3

J. Manzur; A. M. García; A. Vega; E. Spodine

doi:10.1016/S0277-5387(99)00136-9

Synthesis, structure and oxidation studies of a dinuclear copper(I)-copper(II) complex: [Cu₂(bdpdz)₂](ClO₄)₃

J. Manzur, A. M. García, A. Vega, E. Spodine

Exact Sciences School

Research output: Contribution to journal › Article › peer-review

16 Citations (Scopus)

Abstract

A dinuclear copper complex containing the ligand 3,6-bis(di-2-pyridylmethyl) pyridazine, bdpdz, [Cu₂(bdpdz)₂](ClO₄)₃, was prepared and its structure determined by X-ray analysis. The compound consists of a dinuclear mixed valence copper(I)-copper(II) entity with localised valences, co-ordinated to two bridging ligand molecules. The geometry around the copper(I) centre is distorted tetrahedral, while that of the copper(II) centre is tetragonally distorted octahedral. Oxidation studies reveal that the compound does not exhibit phenolase activity.

Original language	English
Pages (from-to)	2399-2404
Number of pages	6
Journal	Polyhedron
Volume	18
Issue number	18
DOIs	https://doi.org/10.1016/S0277-5387(99)00136-9
Publication status	Published - 30 Jul 1999

Keywords

Binucleating ligand
Copper complexes
Mixed valence
Oxidation
Structure

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

Access to Document

10.1016/S0277-5387(99)00136-9

Cite this

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title = "Synthesis, structure and oxidation studies of a dinuclear copper(I)-copper(II) complex: [Cu2(bdpdz)2](ClO4)3",

abstract = "A dinuclear copper complex containing the ligand 3,6-bis(di-2-pyridylmethyl) pyridazine, bdpdz, [Cu2(bdpdz)2](ClO4)3, was prepared and its structure determined by X-ray analysis. The compound consists of a dinuclear mixed valence copper(I)-copper(II) entity with localised valences, co-ordinated to two bridging ligand molecules. The geometry around the copper(I) centre is distorted tetrahedral, while that of the copper(II) centre is tetragonally distorted octahedral. Oxidation studies reveal that the compound does not exhibit phenolase activity.",

keywords = "Binucleating ligand, Copper complexes, Mixed valence, Oxidation, Structure",

author = "J. Manzur and Garc{\'i}a, {A. M.} and A. Vega and E. Spodine",

note = "Funding Information: The support of this research by the Departamento de Investigaci{\'o}n y Desarrollo de la Universidad de Chile (project E012/97) is gratefully acknowledged. A. V. acknowledges the Consejo Nacional de Ciencia y Tecnolog{\'ı}a (CONICYT) for a graduate scholarship.",

year = "1999",

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doi = "10.1016/S0277-5387(99)00136-9",

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TY - JOUR

T1 - Synthesis, structure and oxidation studies of a dinuclear copper(I)-copper(II) complex

T2 - [Cu2(bdpdz)2](ClO4)3

AU - Manzur, J.

AU - García, A. M.

AU - Vega, A.

AU - Spodine, E.

N1 - Funding Information: The support of this research by the Departamento de Investigación y Desarrollo de la Universidad de Chile (project E012/97) is gratefully acknowledged. A. V. acknowledges the Consejo Nacional de Ciencia y Tecnologı́a (CONICYT) for a graduate scholarship.

PY - 1999/7/30

Y1 - 1999/7/30

N2 - A dinuclear copper complex containing the ligand 3,6-bis(di-2-pyridylmethyl) pyridazine, bdpdz, [Cu2(bdpdz)2](ClO4)3, was prepared and its structure determined by X-ray analysis. The compound consists of a dinuclear mixed valence copper(I)-copper(II) entity with localised valences, co-ordinated to two bridging ligand molecules. The geometry around the copper(I) centre is distorted tetrahedral, while that of the copper(II) centre is tetragonally distorted octahedral. Oxidation studies reveal that the compound does not exhibit phenolase activity.

AB - A dinuclear copper complex containing the ligand 3,6-bis(di-2-pyridylmethyl) pyridazine, bdpdz, [Cu2(bdpdz)2](ClO4)3, was prepared and its structure determined by X-ray analysis. The compound consists of a dinuclear mixed valence copper(I)-copper(II) entity with localised valences, co-ordinated to two bridging ligand molecules. The geometry around the copper(I) centre is distorted tetrahedral, while that of the copper(II) centre is tetragonally distorted octahedral. Oxidation studies reveal that the compound does not exhibit phenolase activity.

KW - Binucleating ligand

KW - Copper complexes

KW - Mixed valence

KW - Oxidation

KW - Structure

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DO - 10.1016/S0277-5387(99)00136-9

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VL - 18

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EP - 2404

JO - Polyhedron

JF - Polyhedron

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ER -