Synthesis, characterization of a new carbonylated zirconium metallocene using a dichloro-zirconocene derived from partially alkylated s-indacene

J. F. Araneda, S. Salinas, D. Mac-Leod-Carey, A. Muñoz-Castro, R. Arratia-Perez, C. Adams, I. Chávez, J. M. Manríquez

Research output: Contribution to journalArticlepeer-review

3 Citations (Scopus)

Abstract

This work describes the synthesis and characterization of new organometallic species, an unprecedented mononuclear zirconium complex bearing a tetraalkylated s-indacene ligand, and secondly, its respective dicarbonyl complex obtained by reduction with Mg/HgCl2. Theoretical calculations of these two compounds were carried out to gain further understanding of these novel molecular systems.

Original languageEnglish
Pages (from-to)269-273
Number of pages5
JournalJournal of the Chilean Chemical Society
Volume54
Issue number3
DOIs
Publication statusPublished - 2009

Keywords

  • DFT
  • S-indaceno
  • Zirconium dicarbonyl
  • Zirconocene

ASJC Scopus subject areas

  • General Chemistry

Fingerprint

Dive into the research topics of 'Synthesis, characterization of a new carbonylated zirconium metallocene using a dichloro-zirconocene derived from partially alkylated s-indacene'. Together they form a unique fingerprint.

Cite this