Synthesis, characterization and thermal properties of iron material including carbodiimide and S-indacene structures

Mohamed Dahrouch, Enzo Díaz, Andrés Iturra, Maria Parra, Nicolás Gatica, Yanko Moreno, Ivonne Chávez, Juan Manuel Manríquez

Research output: Contribution to journalArticlepeer-review

Abstract

Iron carbodiimide materials have been prepared using transmetallation reaction from dilithium carbodiimide. The products were characterized by elemental analysis and infrared spectroscopy presenting the characteristic absorption of carbodiimide group (-NCN-). The partial oxidation of iron carbodiimide materials based on s-indacene ligand has shown a clear electronic delocalization observed by IR spectroscopy. The thermal degradation of these materials studied by thermogravimetric analyses (TGA), starts around 180-200°C.

Original languageEnglish
Pages (from-to)587-590
Number of pages4
JournalJournal of the Chilean Chemical Society
Volume56
Issue number1
DOIs
Publication statusPublished - 2011

ASJC Scopus subject areas

  • Chemistry(all)

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